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We introduce a density-functional formalism based on the Parsons-Lee and the generalized van der Waals theories in order to describe the thermodynamics of anisotropic particle systems with steric interactions. For ellipsoids of revolution,…

Soft Condensed Matter · Physics 2018-12-31 Eduardo dos S. Nascimento

Over the years, several schemes have been proposed to describe multireference systems with Kohn-Sham Density Functional Theory. Problematic is the combination of two aspects: the Kohn-Sham reference wavefunction is usually taken to be a…

Strongly Correlated Electrons · Physics 2019-08-01 Pablo Ramos , Michele Pavanello

The Fermi liquid theory may provide a good description of the thermodynamic properties of an interacting particle system when the interaction between the particles contributes to the total energy of the system with a quantity which may…

Quantum Gases · Physics 2012-07-19 Dragos-Victor Anghel

A single mechanism, endemic to the standard model of physics, is proposed to explain wavefunction collapse, classical motion, dissipation, equilibration, and the transition from pure quantum mechanics through open system decoherence to the…

General Physics · Physics 2024-09-23 J. H. Brownell

We investigate dynamical properties of a one-component Fermi gas with dipole-dipole interaction between particles. Using a variational function based on the Thomas-Fermi density distribution in phase space representation, the total energy…

Other Condensed Matter · Physics 2011-04-12 T Sogo , L He , T Miyakawa , S Yi , H Lu , H Pu

The Runge-Gross [E. Runge, and E. K. U. Gross, Phys. Rev. Lett., 52, 997 (1984)] action functional of time-dependent density-functional theory leads to a well-known causality paradox, i.e., a perturbation of the electronic density in the…

Chemical Physics · Physics 2015-06-15 Martin A. Mosquera

Time-resolved photoemission spectroscopy provides a unique and direct way to explore the real-time nonequilibrium dynamics of electrons and holes. The formal theory of the spectral function evolution requires inclusion of electronic…

Materials Science · Physics 2025-05-09 Thomas Blommel , Enrico Perfetto , Gianluca Stefanucci , Vojtěch Vlček

We demonstrate that the zero-temperature conductance of the Anderson model can be calculated within the Landauer formalism combined with static density functional theory (DFT). The proposed approximate functional is based on…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 G. Stefanucci , S. Kurth

The thermodynamics and covariant kinetic theory have been elaborately investigated in a non-extensive environment considering the non-extensive generalization of Bose-Einstein (BE) and Fermi-Dirac (FD) statistics. Starting with Tsallis'…

Nuclear Theory · Physics 2018-02-08 Sukanya Mitra

Simple application of the Einstein model combined with the elastic description of solid state is developed. The frequency of quantum oscillators has been assumed as volume dependent and, furthermore, elastic energy terms of static character…

Statistical Mechanics · Physics 2013-04-09 Tadeusz Balcerzak , Karol Szałowski , Michal Jaščur

Classical density functional theory (DFT) provides an exact variational framework for determining the equilibrium properties of inhomogeneous fluids. We report a generalization of DFT to treat the non-equilibrium dynamics of classical…

Soft Condensed Matter · Physics 2013-09-06 Matthias Schmidt , Joseph M. Brader

The nonequilibrium dynamics of a binary Lennard-Jones mixture in a simple shear flow is investigated by means of molecular dynamics simulations. The range of temperature investigated covers both the liquid, supercooled and glassy states,…

Soft Condensed Matter · Physics 2009-11-07 Ludovic Berthier , Jean-Louis Barrat

The real-time electronic dynamics on material surfaces is critically important to a variety of applications. However, their simulations have remained challenging for conventional methods such as the time-dependent density-functional theory…

Chemical Physics · Physics 2015-06-16 Rulin Wang , Dong Hou , Xiao Zheng

The fundamental insight into Brownian motion by Einstein is that all substances exhibit continual fluctuations due to thermal agitation balancing with the frictional resistance. However, even at thermal equilibrium, biological activity can…

Soft Condensed Matter · Physics 2014-02-19 Soya Shinkai , Yuichi Togashi

We present new nonlinear differential equations for spacetime correlation functions of Fermi gas in one spatial dimension. The correlation functions we consider describe non-stationary processes out of equilibrium. The equations we obtain…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 E. Bettelheim , A. G. Abanov , P. Wiegmann

We give a variational formulation of classical statistical mechanics where the one-body density and the local entropy distribution constitute the trial fields. Using Levy's constrained search method it is shown that the grand potential is a…

Soft Condensed Matter · Physics 2015-05-30 Matthias Schmidt

The self consistent version of the density functional theory is presented, which allows to calculate the ground state and dynamic properties of finite multi-electron systems. An exact functional equation for the effective interaction, from…

Materials Science · Physics 2017-08-23 M. Ya. Amusia , A. Z. Msezane , V. R. Shaginyan

A rigorous derivation of the density functional in the Hohenberg-Kohn theory is presented. With no assumption regarding the magnitude of the electric coupling constant $e^2$ (or correlation), this work provides a firm basis for…

Other Condensed Matter · Physics 2010-09-20 Yi-Kuo Yu

We present a new class of non-adiabatic approximations in time-dependent density functional theory derived from an exact expression for the time-dependent exchange-correlation potential. The approximations reproduce dynamical step and peak…

Chemical Physics · Physics 2018-12-21 Lionel Lacombe , Neepa T. Maitra

The molecular density functional theory of fluids provides an exact theory for computing solvation free energies in implicit solvents. One of the reasons it has not received nearly as much attention as quantum density functional theory for…

Statistical Mechanics · Physics 2019-02-04 David M. Rogers