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We investigate the effect of polymer length dispersity on the properties of self-assembled micelles in solution by self-consistent field calculations. Polydispersity stabilizes micelles by raising the free energy barriers of micelle…

Soft Condensed Matter · Physics 2019-02-13 Sriteja Mantha , Shuanhu Qi , Matthias Barz , Friederike Schmid

We report on the electrostatic complexation between polyelectrolyte-neutral copolymers and oppositely charged 6 nm-crystalline nanoparticles. For two different dispersions of oxide nanoparticles, the electrostatic complexation gives rise to…

Soft Condensed Matter · Physics 2007-09-10 J. -F. Berret , A. Sehgal , M. Morvan , O. Sandre , A. Vacher , M. Airiau

Thanks to the spontaneous interaction between noble metals and biological scaffolds, nanomaterials with unique features can be achieved following relatively straightforward and cost-efficient synthetic procedures. Here, plasmonic silver…

We report the synthesis of complex salts made from the cationic surfactant dodecyltrimethyl-ammonium and diblock copolymers poly(acrylic acid)-block-poly(acrylamide) of different molecular weights. In water, the complex salts self-assemble…

Materials Science · Physics 2013-10-29 Leticia Vitorazi , Jean-Francois Berret , Watson Loh

The ability to engineer localized surface plasmon resonances at large scale usually relies on precise nanoscale patterning. Here, we demonstrate that mid-infrared plasmonic responses can instead emerge in unpatterned polysilicon films…

Magnetic composite materials i.e. elastomers, polymer gels, or polymer solutions with embedded magnetic nanoparticles are useful for many technical and bio-medical applications. However, the microscopic details of the coupling mechanisms…

Soft Condensed Matter · Physics 2020-10-30 Patrick Kreissl , Christian Holm , Rudolf Weeber

By using nanosecond laser pulses at 532-nm wavelength, we have intensively studied the optical limiting and nonlinear optical properties of some new composites which consist of mono-functional…

Materials Science · Physics 2015-06-25 Hendry Izaac Elim , Jianying Ouyang , Suat Hong Goh , Wei Ji

Herein, we report an easy, straight forward, and versatile approach to build 0D/2D hybrid nanoparticle/graphene architectures by means of non-covalent chemistry and a modified Layer-by-Layer assembly. Three water soluble perylene diimides…

The study of nanostructured artificial media for optics has expanded rapidly over the last few decades, coupled with improvements of fabrication technology that have enabled investigation of previously unrealisable optical scattering…

Optics · Physics 2017-09-27 Ben Hopkins

We review the basic physics behind light interaction with plasmonic nanoparticles. The theoretical foundations of light scattering on one metallic particle (a plasmonic monomer) and two interacting particles (a plasmonic dimer) are…

Optics · Physics 2012-08-22 Dmitry N. Chigrin , Christian Kremers , Sergei V. Zhukovsky

We computed the self-organisation process of a monodisperse collection of spherical micrometric particles trapped in a two-dimensional (2D) thin liquid film isothermally dried on a chemically inert substrate. The substrate is either flat or…

Soft Condensed Matter · Physics 2009-11-11 F. Lallet , N. Olivi-Tran

In frameworks of the scaling theory of phase transitions and critical phenomena the quantitative dependence of macroscopic properties on nanostructural parameters in a polymeric material is revealed. The draw ratios at neck and at break are…

Soft Condensed Matter · Physics 2012-10-30 Andrei N. Yakunin

A new method of polymer characterization, based on permeation studies using nanoscale pores, was recently proposed by Brochard and de Gennes. In the present paper, we study how this method, initially developped for star polymers can be…

Soft Condensed Matter · Physics 2007-05-23 Cyprien Gay , Elie Raphael

The self-assembly of submerged cold-plasma-treated polyethylene beads is reported. The plasma-treated immersed millimetrically-sized polyethylene beads formed well-ordered 2D quasi-crystalline structures. The submerged floating of light…

Organic-inorganic nanohybrids have been synthesized by in-situ coating of self-assembled, nanotubular J-aggregates with helically wound silica ribbons. The J-aggregates retain their outstanding optical properties in the nanohybrids, but…

Chemical Physics · Physics 2015-02-03 Yan Qiao , Frank Polzer , Holm Kirmse , Stefan Kirstein , Jürgen P. Rabe

We present results of electrochemical deposition of superconducting Pb in the pores of templates prepared by self-assembly from colloidal suspensions of polystyrene latex spheres. This technique enables us to create highly ordered…

Superconductivity · Physics 2009-11-10 A. A. Zhukov , E. T. Filby , M. A. Ghanem , P. N. Bartlett , P. A. J. de Groot

Polymers with the same chemical composition can provide different properties by reducing the dimension or simply by altering their nanostructure. Recent literature works report hundreds of examples of advances methods in the fabrication of…

Materials Science · Physics 2017-06-27 Carmen Mijangos , Rebeca Hernández , Jaime Martin

Recent progress in colloidal science has led to elaborate self-assembled structures whose complexity raises hopes for elaborating new materials. However, the throughputs are extremely low and consequently, the chance to produce materials of…

Soft Condensed Matter · Physics 2014-09-16 Bingqing Shen , Joshua Ricouvier , Mathilde Reyssat , Florent Malloggi , Patrick Tabeling

The synthesis of polymer-like amorphous carbon (a-C:H) thin-films by microwave excited collisional hydrocarbon plasma process is reported. Stable and highly aromatic a-C:H were obtained containing significant inclusions of poly(p-phenylene…

Materials Science · Physics 2015-05-18 M. Rybachuk* , A. Hertwig , M. Weise , M. Sahre , M. Männ , U. Beck , J. M. Bell

Binary random compacts with different proportions of small (volume V) and large (volume 2V) bare maghemite nanoparticles (NPs) are used to investigate the effect of controllably broadening the particle size distribution on the magnetic…