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We perform a phenomenological analysis of the problem of the electronic doping of a graphene sheet by deposited transition metal atoms, which aggregate in clusters. The sample is placed in a capacitor device such that the electronic doping…

Strongly Correlated Electrons · Physics 2015-03-19 Jaime E. Santos , Nuno M. R. Peres , Joao M. B. Lopes dos Santos , Antonio H. Castro Neto

We study the effects of metallic doping on the electronic properties of graphene using density functional theory in the local density approximation in the presence of a local charging energy (LDA+U). The electronic properties are sensitive…

Materials Science · Physics 2009-11-13 B. Uchoa , C. -Y. Lin , A. H. Castro Neto

Atomic-scale fabrication is an outstanding challenge and overarching goal for the nanoscience community. The practical implementation of moving and fixing atoms to a structure is non-trivial considering that one must spatially address the…

We have performed scanning gate microscopy (SGM) on graphene field effect transistors (GFET), using a biased metallic nanowire coated with a dielectric layer as a contact mode tip and local top gate. Electrical transport through graphene at…

The temperature dependence of electric transport properties of single-layer and few-layer graphene at large charge doping is of great interest both for the study of the scattering processes dominating the conductivity at different…

Mesoscale and Nanoscale Physics · Physics 2016-09-02 R. S. Gonnelli , F. Paolucci , E. Piatti , Kanudha Sharda , A. Sola , M. Tortello , Jijeesh R. Nair , C. Gerbaldi , M. Bruna , S. Borini

By employing x-ray photoelectron spectroscopy (XPS), we have been able to establish the occurrence of charge-transfer doping in few-layer graphene covered with electron acceptor (TCNE) and donor (TTF) molecules. We have performed…

Materials Science · Physics 2015-06-04 D. Choudhury , B. Das , D. D. Sarma , C. N. R. Rao

We distinguish three mechanisms of doping graphene. Density functional theory is used to show that electronegative molecule like F4-TCNQ and electropositive metals like K dope graphene p- and n-type respectively. These dopants are expected…

Materials Science · Physics 2015-05-18 H. Pinto , R. Jones , J. P. Goss , P. R. Briddon

Doping of the graphene lattice with transition metal atoms resulting in high magnetic anisotropy energy (MAE) is an important goal of materials research owing to its potential application in spintronics. In this article, by using…

We demonstrate electrochemical top gating of graphene by using a solid polymer electrolyte. This allows to reach much higher electron and hole doping than standard back gating. In-situ Raman measurements monitor the doping. The G peak…

The effects of surface chemical doping on spin transport in graphene are investigated by performing non-local measurements in ultrahigh vacuum while depositing gold adsorbates. We demonstrate manipulation of the gate-dependent non-local…

Mesoscale and Nanoscale Physics · Physics 2010-05-13 K. Pi , Wei Han , K. M. McCreary , A. G. Swartz , Yan Li , R. K. Kawakami

The thermodynamic, kinetic and magnetic properties of the hydrogen monomer on doped graphene layers were studied by ab initio simulations. Electron doping was found to heighten the diffusion potential barrier, while hole doping lowers it.…

Materials Science · Physics 2011-08-17 Liang Feng Huang , Mei Yan Ni , Guo Ren Zhang , Wang Huai Zhou , Yong Gang Li , Xiao Hong Zheng , Zhi Zeng

Chemically doped graphene could support plasmon excitations up to telecommunication or even visible frequencies. Apart from that, the presence of dopant may influence electron scattering mechanisms in graphene and thus impact the plasmon…

Materials Science · Physics 2017-10-06 Dino Novko

The electrical properties of graphene are known to be modified by chemical species that interact with it. We investigate the effect of doping of graphene-based devices by toluene (C6H5CH3). We show that this effect has a complicated…

Materials Science · Physics 2010-10-25 A. A. Kaverzin , S. M. Strawbridge , A. S. Price , F. Withers , A. K. Savchenko , D. W. Horsell

A significant advance toward achieving practical applications of graphene as a two-dimensional material in nanoelectronics would be provided by successful synthesis of both n-type and p-type doped graphene. However reliable doping and a…

Mesoscale and Nanoscale Physics · Physics 2013-10-24 Yu-Fen Lu , Shun-Tsung Lo , Jheng-Cyuan Lin , Wenjing Zhang , Jing-Yu Lu , Fan-Hung Liu , Chuan-Ming Tseng , Yi-Hsien Lee , Chi-Te Liang , Lain-Jong Li

The pressure evolution of the Raman spectrum of graphene grown by chemical vapour deposition on polycrystalline copper is investigated with the use of a polar and a non-polar pressure transmitting medium (PTM). The G and 2D Raman bands…

Mesoscale and Nanoscale Physics · Physics 2013-05-01 K. Filintoglou , N. Papadopoulos , J. Arvanitidis , D. Christofilos , O. Frank , M. Kalbac , J. Parthenios , G. Kalosakas , C. Galiotis , K. Papagelis

Transition metal phthalocyanines (TMPc's) are under intense scrutiny in the field of spintronics, as they may be promising storage devices. The simplicity and cheapness of such molecules increase their commercial potential. There is an…

Materials Science · Physics 2022-10-04 Aleksei Koshevarnikov , Jacek A. Majewski

The thermal conductivity of doped graphene flake of finite size is investigated with emphasis on the influence of mass of substituting atoms on this property. It is shown that the graphene doping by small concentrations of relatively heavy…

Mesoscale and Nanoscale Physics · Physics 2012-09-26 Vadym Adamyan , Vladimir Zavalniuk

In this paper we describe a graphene p-n junction created by chemical doping. We find that chemical doping does not reduce mobility in contrast to top-gating. The preparation technique has been developed from systematic studies about…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Timm Lohmann , Klaus v. Klitzing , Jurgen H. Smet

Controlling the metal-insulator transition in graphene-based material is a crucial topic as it directly impacts its potential applications. Inspired by recent experiments, we study the effects of doping and bond disorder on metal-insulator…

Strongly Correlated Electrons · Physics 2024-01-24 Kaiyi Guo , Ying Liang , Tianxing Ma

In monolayer graphene, substitutional doping during growth can be used to alter its electronic properties. We used scanning tunneling microscopy (STM), Raman spectroscopy, x-ray spectroscopy, and first principles calculations to…

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