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We simulate model systems of charged spherical particles in their counterion solution and measure the thermodynamic pressure and the pair distribution function from which we derive effective potentials of mean force. For a system with only…

Soft Condensed Matter · Physics 2007-05-23 Niels Gronbech-Jensen , Keith M Beardmore , Philip Pincus

We study the mutual interactions of simple, parallel polymers and nanotubes, and develop a scheme to include the van der Waals interactions in the framework of density functional theory (DFT) for these molecules at intermediate to…

Soft Condensed Matter · Physics 2007-05-23 Jesper Kleis , Per Hyldgaard , Elsebeth Schroder

The numerically exact evaluation of the van der Waals interaction, also known as Casimir interaction when including retardation effects, constitutes a challenging task. We present a new approach based on the plane-wave basis and demonstrate…

Soft Condensed Matter · Physics 2020-07-13 Benjamin Spreng , Paulo A. Maia Neto , Gert-Ludwig Ingold

London-van der Waals dispersion forces are a fundamental component of condensed matter systems, biological processes, and self-assembly. In this letter we propose a method to calculate the C6 coefficients that characterize dispersion forces…

Chemical Physics · Physics 2019-02-06 Micael J. T. Oliveira , Ksenia Komarova , Francoise Remacle , Matthieu J. Verstraete

We consider the van der Waals interaction between two ground-state atoms embedded in adjacent semi-infinite magnetodielectric media, with emphasis on medium effects on it. We demonstrate that, in this case, at small atom-atom distances the…

Quantum Physics · Physics 2009-11-13 M. S. Tomas

We investigate the influence of the appearance of excitonic states on van der Waals interactions among two Rydberg atoms. The atoms are assumed to be in different Rydberg states, e.g., in the $|ns\rangle$ and $|np\rangle$ states. The…

Atomic Physics · Physics 2015-08-12 Hashem Zoubi

We develop a nonequilibrium Green's function theory for dispersion interactions between two nanostructures, each an open quantum system driven into a nonequilibrium steady state by an applied bias voltage. Starting from the two-particle…

Mesoscale and Nanoscale Physics · Physics 2026-05-05 Christine M. E. Little , Daniel S. Kosov

We study theoretically the van der Waals interaction between two atoms out of equilibrium with isotropic electromagnetic field. We demonstrate that at large interatomic separations, the van der Waals forces are resonant, spatially…

Quantum Physics · Physics 2018-05-09 Yury Sherkunov

We discuss laser dressed dipolar and Van der Waals interactions between atoms and polar molecules, so that a cold atomic gas with laser admixed Rydberg levels acts as a designed reservoir for both elastic and inelastic collisional…

Atomic Physics · Physics 2012-05-15 Bo Zhao , Alexander Glätzle , Guido Pupillo , Peter Zoller

A new scheme for the computation of dispersive interactions from first principles is presented. This cost-effective approach relies on a Wannier function representation compatible with density function theory descriptions. This is an…

Materials Science · Physics 2025-02-04 Diem Thi-Xuan Dang , Dai-Nam Le , Lilia M. Woods

The long-range interactions of two atoms, of an atom and a dielectric wall, of an atom and a perfectly conducting wall, and of an atom between two perfectly conducting walls are calculated, including the effects of retardation, for Li using…

Atomic Physics · Physics 2008-02-03 Zong-Chao Yan , A. Dalgarno , J. F. Babb

In a frame of quasi-crystal approximation the dispersion equations are obtained for the wave vector of a coherent electromagnetic wave propagating in a media which contains a random set of parallel dielectric cylinders with possible…

Optics · Physics 2007-05-23 Nadejda L. Cherkas

We describe the resonant interaction of an atom with a strongly focused light beam by expanding the field in multipole waves. For a classical field, or when the field is described by a coherent state, we find that both intensity pattern and…

Quantum Physics · Physics 2009-11-10 S. J. van Enk

Electron correlations in molecules can be divided in short range dynamical correlations, long range Van der Waals type interactions and near degeneracy static correlations. In this work we analyze for a one-dimensional model of a…

Chemical Physics · Physics 2014-05-13 K. J. H. Giesbertz , R. van Leeuwen

When an atom in vacuum is near a surface of a dielectric the energy of a fluctuating electromagnetic field depends on a distance between them resulting, as known, in the force called van der Waals one. Besides this fluctuation phenomenon…

Quantum Physics · Physics 2015-05-27 B. Ivlev

Highly polarizable metastable He* ($\mathrm{2^3S}$) and Ne* ($\mathrm{2^3P}$) atoms have been diffracted from a 100 nm period silicon nitride transmission grating and the van der Waals coefficients $C_3$ for the interaction of the excited…

We obtained new nonrelativistic expression for the dynamical van der Waals atom -surface interaction energy of very convenient form for different applications. It is shown that classical result (Ferrell and Ritchie, 1980) holds only for a…

Other Condensed Matter · Physics 2011-08-10 G. V. Dedkov , A. A. Kyasov

We describe a novel type of interaction between open-shell polar molecules at sub-millikelvin temperatures. This hyperfine van der Waals interaction occurs between two molecules in two rotational states that differ by one quantum. Normally,…

Atomic Physics · Physics 2025-09-23 Etienne F. Walraven , Tijs Karman

For the first time, using nonrelativistic approach we have calculated the attraction force, friction torque and the rate of radiation heat exchange in the system of two sprerical rotating particles located at a distance between one another.

Mesoscale and Nanoscale Physics · Physics 2012-09-24 A. A. Kyasov , G. V. Dedkov

The dispersion energy between extended molecular chains (or equivalently infinite wires) with non-zero band gaps is generally assumed to be expressible as a pair-wise sum of atom-atom terms which decay as $R^{-6}$. Using a model system of…

Mesoscale and Nanoscale Physics · Physics 2012-12-17 Alston J. Misquitta , James Spencer , Anthony J. Stone , Ali Alavi