Related papers: Atmospheric Sulfur Photochemistry on Hot Jupiters
The high cosmic abundance and the intermediate volatility and chemical properties of sulfur allow the use of sulfur-bearing species as a tracer of the chemical processes in the atmospheres of hot Jupiter exoplanets. Nevertheless, despite…
We present and validate a new network of atmospheric thermo-chemical and photo-chemical sulfur reactions. We use a 1-D chemical kinetics model to investigate these reactions as part of a broader HCNO chemical network in a series of hot and…
We use a 1D thermochemical and photochemical kinetics model to predict the disequilibrium stratospheric chemistries of warm and hot Jupiters (800 < T < 1200 K). Thermal chemistry and vertical mixing are generally more important than…
For solar-system objects, ultraviolet spectroscopy has been critical in identifying sources for stratospheric heating and measuring the abundances of a variety of hydrocarbon and sulfur-bearing species, produced via photochemical…
Molecular species in planetary atmospheres provide key insights into their atmospheric processes and formation conditions. In recent years, high-resolution Doppler spectroscopy in the near-infrared has allowed detections of H$_2$O and CO in…
HD 209458b is the prototypical hot Jupiter and one of the best targets available for precise atmosphere characterisation. Now that spectra from both Hubble Space Telescope (HST) and James Webb Space Telescope (JWST) are available, we can…
Ultra-hot Jupiters (UHJs) have recently been the focus of several atmospheric studies due to their extreme properties. While molecular hydrogen (H$_2$) plays a key role in UHJ atmospheres, it has not been directly detected on an exoplanet.…
The first JWST observations of hot Jupiters showed an unexpected detection of SO2 in their hydrogen-rich atmospheres. We investigate how much sulphur can be expected in the atmospheres of rocky exoplanets and which sulphur molecules can be…
We use a 1D model to address photochemistry and possible haze formation in the irradiated warm Jupiter, 51 Eridani b. The intended focus was to be carbon, but sulfur photochemistry turns out to be important. The case for organic…
Ultraviolet (UV) absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in…
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly…
UV absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar…
The atmospheric chemical composition of a hot Jupiter can lead to insights into where in its natal protoplanetary disk it formed and its subsequent migration pathway. We use a 1-D chemical kinetics code to compute a suite of models across a…
The opacity of alkali atoms, most importantly of Na and K, plays a crucial role in the atmospheres of brown dwarfs and exoplanets. We present a comprehensive study of NaH2 collisional profiles at temperatures from 500 to 3000 K, the…
Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by…
The chemistry along the mass loss of Hot Jupiters is generally considered to be simple, consisting mainly of atoms, prevented from forming more complex species by the intense radiation field from their host stars. In order to probe the…
The UVS instrument on the Juno mission records far-ultraviolet reflected sunlight from Jupiter. These spectra are sensitive to the abundances of chemical species in the upper atmosphere and to the distribution of the stratospheric haze…
JWST has revealed sulfur chemistry in giant exoplanet atmospheres, where molecules such as SO2 trace photochemistry, metallicity, and formation and migration. To ascertain the conditions that determine whether (or how much) SO2, H2S, and…
The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet…
We present a computationally efficient 1-D seasonal radiative model, with convective adjustment, of Jupiter's atmosphere. Our model takes into account radiative forcings from the main hydrocarbons (methane, ethane, acetylene), ammonia,…