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Electronic band structures in hydrogenated graphene are theoretically investigated by means of first-principle calculations and an effective tight-binding model. It is shown that regularly designed hydrogenation to graphene gives rise to a…

Mesoscale and Nanoscale Physics · Physics 2024-08-05 Yong-Cheng Jiang , Toshikaze Kariyado , Xiao Hu

Hydrogenation has proven to be an effective tool to open the bandgap of graphene. In the present density functional study we demonstrate that single-side-hydrogenated graphene is a semiconductor with an indirect bandgap of 1.89 eV, in…

Materials Science · Physics 2011-03-01 Bhalchandra S. Pujari , Sergey Gusarov , Michael Brett , Andriy Kovalenko

We present a detailed numerical study of the electronic properties of single-layer graphene with resonant ("hydrogen") impurities and vacancies within a framework of noninteracting tight-binding model on a honeycomb lattice. The algorithms…

Mesoscale and Nanoscale Physics · Physics 2010-09-29 Shengjun Yuan , Hans De Raedt , Mikhail I. Katsnelson

We have systematically investigated the effect of oxidation on the structural and electronic properties of graphene based on first-principles calculations. Energetically favorable atomic configurations and building blocks are identified,…

Mesoscale and Nanoscale Physics · Physics 2009-08-24 Jia-An Yan , Lede Xian , M. Y. Chou

While graphene is a semi-metal, a recently synthesized hydrogenated graphene called graphane, is an insulator. We have probed the transformation of graphene upon hydrogenation to graphane within the framework of density functional theory.…

Mesoscale and Nanoscale Physics · Physics 2012-10-05 Prachi Chandrachud , Bhalchandra S Pujari , Soumyajyoti Haldar , Biplab Sanyal , D G Kanhere

There exist three conformers of hydrogenated graphene, referred to as chair-, boat-, or washboard-graphane. These systems have a perfect two-dimensional periodicity mapped onto the graphene scaffold, but they are characterized by a $sp^3$…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Emiliano Cadelano , Pier Luca Palla , Stefano Giordano , Luciano Colombo

We provide a thorough study of a carbon divacancy, a fundamental but almost unexplored point defect in graphene. Low temperature scanning tunneling microscopy (STM) imaging of irradiated graphene on different substrates enabled us to…

Angle-resolved two-photon photoemission and high-resolution electron energy loss spectroscopy are employed to derive the electronic structure of a sub-nanometer tomically precise quasi-one-dimensional graphene nanoribbon (GNR) on Au(111).…

Materials Science · Physics 2012-11-26 C. Bronner , F. Leyssner , S. Stremlau , M. Utecht , P. Saalfrank , T. Klamroth , P. Tegeder

The electronic structure and structural evolution of hydrogenated graphene are investigated by Raman spectroscopy with multiple excitations. The excitation energy dependent saturation effect on the ratio of integrated intensities of D and G…

Materials Science · Physics 2010-12-06 Zhiqiang Luo , Ting Yu , Zhenhua Ni , Sanhua Lim , Jingzhi Shang , Hailong Hu , Lei Liu , Zexiang Shen , Jianyi Lin

The electronic properties of a material depend on the spatial freedom of the electron wavefunction. A well-known example is graphite, which is a conventional gapless semiconductor, while a single layer of it, graphene, exhibits extremely…

Mesoscale and Nanoscale Physics · Physics 2026-01-28 Mohammadamir Bazrafshan , Thomas. D. Kühne

We propose a new allotrope of graphane, named as tricycle graphane,with a 4up/2down UUUDUD hydrogenation in each hexagonal carbon ring,which is different from previously proposed allotropes with UUDUUD(boat-1) and UUUUDD (boat-2) types of…

Materials Science · Physics 2015-06-04 Chaoyu He , L. Z. Sun , C. X. Zhang , N. Jiao , K. W. Zhang , Jianxin Zhong

Electronic structures of graphene sheet with different defective patterns are investigated, based on the first principles calculations. We find that defective patterns can tune the electronic structures of the graphene significantly.…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 H. Y. He , Y. Zhang , B. C. Pan

The electronic transport properties and band structures for the graphene-based one-dimensional (1D) superlattices with periodic squared potentials are investigated. It is found that a new Dirac point is formed, which is exactly located at…

Mesoscale and Nanoscale Physics · Physics 2013-07-25 Li-Gang Wang , Shi-Yao Zhu

We investigate electronic transport in lithographically patterned graphene ribbon structures where the lateral confinement of charge carriers creates an energy gap near the charge neutrality point. Individual graphene layers are contacted…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Melinda Y. Han , Barbaros Oezyilmaz , Yuanbo Zhang , Philip Kim

Hexagonal Boron Nitride substrates have been shown to dramatically improve the electric properties of graphene. Recently, it has been observed that when the two honeycomb crystals are close to perfect alignment, strong lattice distortions…

Mesoscale and Nanoscale Physics · Physics 2014-10-08 Pablo San-Jose , Ángel Gutiérrez , Mauricio Sturla , Francisco Guinea

In this paper, we consider the optimum coordinate of the penta-graphene. Penta-graphene is a new stable carbon allotrope which is stronger than graphene. Here, we compare the band gap of penta-graphene with various density functional theory…

Materials Science · Physics 2016-02-17 H. Einollahzadeh , R. S. Dariani , S. M. Fazeli

Lacking a band gap largely limits the application of graphene in electronic devices. Previous study shows that grain boundaries (GBs) in polycrystalline graphene can dramatically alter the electrical properties of graphene. Here, we…

Materials Science · Physics 2013-01-11 Jiangtao Wu , Xinghua Shi , Yujie Wei

Graphene is of interest in the development of next-generation electronics due to its high electron mobility, flexibility and stability. However, graphene transistors have poor on/off current ratios because of the absence of a bandgap. One…

Materials Science · Physics 2021-05-03 Shaorui Li , Jiaheng Li , Yongchao Wang , Chenglin Yu , Yaoxin Li , Wenhui Duan , Yayu Wang , Jinsong Zhang

Graphene is one of the most important materials in science today due to its unique and remarkable electronic, thermal and mechanical properties. However in its pristine state, graphene is a gapless semiconductor, what limits its use in…

Materials Science · Physics 2014-08-13 P. A. S. Autreto , J. M. de Sousa , D. S. Galvao

We present atomistic calculations on structural and electronic properties of twisted double bilayer graphene (TDBG) consisting of two sets of rotationally misaligned Bernal-stacked bilayer graphene. Obtained equilibrium atomic structures…

Mesoscale and Nanoscale Physics · Physics 2019-11-20 Young Woo Choi , Hyoung Joon Choi
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