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Boltzmann defined the entropy of a macroscopic system in a macrostate $M$ as the $\log$ of the volume of phase space (number of microstates) corresponding to $M$. This agrees with the thermodynamic entropy of Clausius when $M$ specifies the…

Statistical Mechanics · Physics 2009-11-10 S. Goldstein , Joel L. Lebowitz

The canonical ensemble describes an open system in equilibrium with a heat bath of fixed temperature. The probability distribution of such a system, the Boltzmann distribution, is derived from the uniform probability distribution of the…

Statistical Mechanics · Physics 2015-06-05 Julian Lee

We present novel bounds for estimating discrete probability distributions under the $\ell_\infty$ norm. These are nearly optimal in various precise senses, including a kind of instance-optimality. Our data-dependent convergence guarantees…

Statistics Theory · Mathematics 2024-02-14 Aryeh Kontorovich , Amichai Painsky

Entropy and differential entropy are important quantities in information theory. A tractable extension to singular random variables-which are neither discrete nor continuous-has not been available so far. Here, we present such an extension…

Information Theory · Computer Science 2017-01-04 Günther Koliander , Georg Pichler , Erwin Riegler , Franz Hlawatsch

Let $ X_1, \ldots, X_n $ be independent random variables taking values in the alphabet $ \{0, 1, \ldots, r\} $, and $ S_n = \sum_{i = 1}^n X_i $. The Shepp--Olkin theorem states that, in the binary case ($ r = 1 $), the Shannon entropy of $…

Information Theory · Computer Science 2022-05-10 Mladen Kovačević

During the past dozen years there have been numerous articles on a relation between entropy and probability which is non-additive and has a parameter $q$ that depends on the nature of the thermodynamic system under consideration. For $q=1$…

Statistical Mechanics · Physics 2009-11-07 Michael Nauenberg

We propose a general approach, named by us hyperstatistics, to treat complex systems, in which Boltzmann-Gibbs statistics breaks down in domains of the system. Hyperstatistics preserves the concavity of nonadditive $q$-entropy. We obtain…

Statistical Mechanics · Physics 2026-04-29 Lucas Squillante , Samuel M. Soares , Constantino Tsallis , Mariano de Souza

The violation of the Pauli principle has been surmised in several models of the Fractional Exclusion Statistics and successfully applied to several quantum systems. In this paper, a classical alternative of the exclusion statistics is…

Statistical Mechanics · Physics 2022-10-17 Projesh Kumar Roy

Attempts to replicate probabilistic reasoning in expert systems have typically overlooked a critical ingredient of that process. Probabilistic analysis typically requires extensive judgments regarding interdependencies among hypotheses and…

Artificial Intelligence · Computer Science 2013-04-15 Marvin S. Cohen

We define a diagonal entropy (d-entropy) for an arbitrary Hamiltonian system as $S_d=-\sum_n \rho_{nn}\ln \rho_{nn}$ with the sum taken over the basis of instantaneous energy states. In equilibrium this entropy coincides with the…

Statistical Mechanics · Physics 2012-08-10 Anatoli Polkovnikov

The foundations of the Boltzmann-Gibbs (BG) distributions for describing equilibrium statistical mechanics of systems are examined. Broadly, they fall into: (i) probabilistic paaroaches based on the principle of equal a priori probability…

Statistical Mechanics · Physics 2009-11-10 A. K. Rajagopal , Sumiyoshi Abe

Shannon entropy, a cornerstone of information theory, statistical physics and inference methods, is uniquely identified by the Shannon-Khinchin or Shore-Johnson axioms. Generalizations of Shannon entropy, motivated by the study of…

Data Analysis, Statistics and Probability · Physics 2026-04-20 Andrea Somazzi , Diego Garlaschelli

In order to study as a whole a wide part of entropy measures, we introduce a two-parameter non-extensive entropic form with respect to the $h$-derivative, which generalizes the conventional Newton--Leibniz calculus. This new entropy,…

Statistical Mechanics · Physics 2023-06-14 Jin-Wen Kang , Ke-Ming Shen , Ben-Wei Zhang

Building on work of Kontsevich, we introduce a definition of the entropy of a finite probability distribution in which the "probabilities" are integers modulo a prime p. The entropy, too, is an integer mod p. Entropy mod p is shown to be…

Number Theory · Mathematics 2020-12-03 Tom Leinster

Entropy is a fundamental property of both classical and quantum systems, spanning myriad theoretical and practical applications in physics and computer science. We study the problem of obtaining estimates to within a multiplicative factor…

Quantum Physics · Physics 2021-11-23 Tom Gur , Min-Hsiu Hsieh , Sathyawageeswar Subramanian

After a brief introduction to Probability Bracket Notation (PBN), indicator operator and conditional density operator (CDO), we investigate probability spaces associated with various quantum systems: system with one observable (discrete or…

Probability · Mathematics 2009-11-10 Xing M. Wang

In this letter we show that the Shore--Johnson axioms for Maximum Entropy Principle in statistical estimation theory account for a considerably wider class of entropic functional than previously thought. Apart from a formal side of the…

Statistical Mechanics · Physics 2019-04-03 Petr Jizba , Jan Korbel

The entropic way of formulating Heisenberg's uncertainty principle not only plays a fundamental role in applications of quantum information theory but also is essential for manifesting genuine nonclassical features of quantum systems. In…

Quantum Physics · Physics 2024-03-05 Shan Huang , Hua-Lei Yin , Zeng-Bing Chen , Shengjun Wu

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

Chemical Physics · Physics 2009-12-03 Chi-Ho Cheng

By using the Jacobi metric of the configuration space, and assuming ergodicity, we calculate the Boltzmann entropy $S$ of a finite-dimensional system around a non-degenerate critical point of its potential energy $V$. We compare $S$ with…

Mathematical Physics · Physics 2009-11-11 Nikos Kalogeropoulos
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