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We report photoassociative spectroscopy of $^{88}$Sr$_2$ in a magneto-optical trap operating on the ${^1S_0}\to{^3P_1}$ intercombination line at 689 nm. Photoassociative transitions are driven with a laser red-detuned by 600-2400 MHz from…

We perform a theoretical analysis to interpret the spectra of purely long-range helium dimers produced by photoassociation (PA) in an ultra-cold gas of metastable helium atoms. The experimental spectrum obtained with the PA laser tuned…

Quantum Physics · Physics 2009-11-10 J. Leonard , A. P. Mosk , M. Walhout , P. Van Der Straten , M. Leduc , C. Cohen-Tannoudji

Ultracold collisions of neutral atoms and molecules have been of great interest since experimental advances enabled the cooling and trapping of such species. This study is a theoretical investigation of a low-energy collision between an…

Atomic Physics · Physics 2025-11-25 Ahmed A. Elkamshishy , Chris H. Greene

The general formalism of the multipolar expansion of electrostatic interactions is applied to the calculation the potential energy between an excited atom (without fine structure) and a ground state diatomic molecule at large separations.…

Quantum Physics · Physics 2017-04-11 M. Lepers , O. Dulieu , V. Kokoouline

A model for photoassociation of ultracold atoms and molecules is presented, and applied to the case of $^{39}$K and $^{23}$Na$^{39}$K bosonic particles. The model relies on the assumption that photoaossociation is dominated by long-range…

Chemical Physics · Physics 2023-03-22 Baraa Shammout , Leon Karpa , Silke Ospelkaus , Eberhard Tiemann , Olivier Dulieu

We study the photonic interactions between two distant atoms which are coupled by an optical element (a lens or an optical fiber) focussing part of their emitted radiation onto each other. Two regimes are distinguished depending on the…

Quantum Physics · Physics 2008-07-15 Stefan Rist , Jürgen Eschner , Markus Hennrich , Giovanna Morigi

We demonstrate photoassociation (PA) of ultracold fermionic $^{87}$Sr atoms. The binding energies of a series of molecular states on the $^1\Sigma^+_u$ $5s^2\,^1$S$_0+5s5p\,^1$P$_1$ molecular potential are fit with the semiclassical…

Atomic Physics · Physics 2021-02-24 J. C. Hill , W. Huie , P. Lunia , J. D. Whalen , S. K. Kanungo , Y. Lu , T. C. Killian

Photoassociation of ultracold atoms is a resonant light-assisted collision process, in which two colliding atoms absorb a photon and form an excited molecule. Since the first observation about three decades ago, the photoassociation of…

Atomic Physics · Physics 2024-03-19 Jin Cao , Bo-Yuan Wang , Huan Yang , Zhi-Jie Fan , Zhen Su , Jun Rui , Bo Zhao , Jian-Wei Pan

The creation of ultracold molecules is currently limited to diatomic species. In this letter we present a theoretical description of the photoassociation of ultracold atoms and molecules to create ultracold excited triatomic molecules, thus…

Atomic Physics · Physics 2015-09-02 Jesús Pérez-Ríos , Maxence Lepers , Olivier Dulieu

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

Quantum Physics · Physics 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

We study the rotational predissociation of atom - molecule complexes with very small binding energy. Such complexes can be produced by Feshbach resonance association of ultracold molecules with ultracold atoms. Numerical calculations of the…

Chemical Physics · Physics 2011-10-03 Alisdair O. G. Wallis , Roman V. Krems

We study the collective radiation properties of cold, trapped ensembles of atoms. We consider the high density regime with the mean interatomic distance being comparable to, or smaller than, the wavelength of the resonant optical radiation…

Quantum Physics · Physics 2021-02-08 David Petrosyan , Klaus Mølmer

Weakly bound molecules have physical properties without atomic analogues, even as the bond length approaches dissociation. In particular, the internal symmetries of homonuclear diatomic molecules result in formation of two-body superradiant…

We describe two-photon photoassociation (PA) experiments operated in an ultracold gas of metastable $^4$He$^*$ atoms in the $2^3S_1$ state. Atom-molecule dark resonances as well as Raman signals provide information on the exotic molecule in…

Other Condensed Matter · Physics 2016-08-16 Steven Moal , Maximilien Portier , Nassim Zahzam , Michèle Leduc

Correlation measurements on the states of two-level atoms having passed through a micromaser at different times can be used to infer properties of the quantum state of the radiation field in the cavity. Long(short) correlation length in…

Condensed Matter · Physics 2008-02-03 Per Elmfors , Benny Lautrup , Bo-Sture Skagerstam

We study how the radiative properties of a dense ensemble of atoms can be modified when they are placed near or between metallic or dielectric surfaces. If the average separation between the atoms is comparable or smaller than the…

Quantum Physics · Physics 2018-06-06 Ryan Jones , Jemma A. Needham , Igor Lesanovsky , Francesco Intravaia , Beatriz Olmos

We investigate the photoassociation dynamics of exactly two laser-cooled $^{85}$Rb atoms in an optical tweezer and reveal fundamentally different behavior to photoassociation in many-atom ensembles. We observe non-exponential decay in our…

Atomic Physics · Physics 2021-03-03 M. Weyland , S. S. Szigeti , R. A. B. Hobbs , P. Ruksasakchai , L. Sanchez , M. F. Andersen

Precision spectroscopy has long played a central role in testing the foundations of physics, from the early insights that led to the development of quantum mechanics to the validation of quantum electrodynamics and the determination of…

High Energy Physics - Phenomenology · Physics 2026-02-26 Cédric Delaunay , Jean-Philippe Karr , Yotam Soreq

Radiative emission during cold collisions between trapped laser-cooled Rb atoms and alkaline-earth ions (Ca$^+$, Sr$^+$, Ba$^+$) and Yb$^+$, and between Li and Yb$^+$, are studied theoretically, using accurate effective-core-potential based…

Atomic Physics · Physics 2015-06-23 Humberto Da Silva , Maurice Raoult , Mireille Aymar , Olivier Dulieu

Cold quantum gases, when acted upon by electromagnetic fields, can give rise to samples where isolated atoms coexist with dimers or trimers, which raises the question of the interactions between these various constituents. Here we perform…

Quantum Gases · Physics 2022-11-10 C. Maury , B. Bakkali-Hassani , G. Chauveau , F. Rabec , S. Nascimbene , J. Dalibard , J. Beugnon
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