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To bridge the gap between single/isolated pore systems to multi-pore systems, such as membranes/electrodes, we studied an array of nanochannels with varying interchannel spacing that controlled the degree of channel communication. Instead…

Fluid Dynamics · Physics 2015-01-29 Yoav Green , Sinwook Park , Gilad Yossifon

When water molecules are confined to nanoscale spacings, such as in the nanometer size pores of activated carbon fiber (ACF), their freezing point gets suppressed down to very low temperatures ($\sim$ 150 K), leading to a metastable liquid…

Soft Condensed Matter · Physics 2015-06-23 S. O. Diallo , L. Vlcek , E. Mamontov , J. K. Keum , Jihua Chen , J. S. Hayes , A. A. Chialvo

Molecular dynamics simulations were used to explain the origin and properties of electrical double-layer capacitance in short graphene nanochannels with width below 2 nm. The results explain the previously reported experimental result on…

Chemical Physics · Physics 2017-04-06 Yinghua Qiu , Yunfei Chen

We observe a sequence of the anchoring transitions in nematic liquid crystals (NLC) sandwiched between the hydrophobic polyimide substrates treated with the plasma beam. There is a pronounced continuous transition from homeotropic to low…

Materials Science · Physics 2009-11-13 Oleg V. Yaroshchuk , Alexei D. Kiselev , Ruslan M. Kravchuk

A vertical partial gate carbon nanotube (CNT) field-effect transistor (FET), which is amenable to the vertical CNT growth process and offers the potential for a parallel CNT array channel, is simulated using a self-consistent atomistic…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Youngki Yoon , James Fodor , Jing Guo

Hydrophobic nanoporous materials can be intruded by water only by exerting an external action, typically increasing pressure. For some materials, water extrudes when the pressure is lowered again. Controlling intrusion/extrusion hysteresis…

Anisotropy describes the directional dependence of a material's properties such as transport and optical response. In conventional bulk materials, anisotropy is intrinsically related to the crystal structure, and thus not tunable by the…

Materials Science · Physics 2017-02-10 Ting Cao , Zhenglu Li , Diana Y. Qiu , Steven G. Louie

Equilibrium molecular dynamics simulations are used to investigate the effect of phase transitions on the transport properties of highly-confined water between parallel graphene sheets. An abrupt reduction by several orders of magnitude in…

Computational Physics · Physics 2019-01-23 Frederike Jaeger , Omar K. Matar , Erich A. Müller

Porous graphene has high mechanical strength and atomic layer thickness, which make it a promising material for material separation and biomolecule sensing. Electrostatic interactions between charges in aqueous solution are a kind of strong…

Chemical Physics · Physics 2016-08-02 Yinghua Qiu , Kun Li , Weiyu Chen , Wei Si , Qiyan Tan , Yunfei Chen

Electrical conductivity is an inherent property of a hydrophobic porous media (HPM) and has critical applications. This research aims to provide a solution for predicting the electrical conductivity of nanoscale HPM with heterogeneous pore…

Soft Condensed Matter · Physics 2021-05-31 Zhongliang Chen , Xiaohu Dong , Zhangxin Chen , Marc-Olivier Coppens

Nanoporous structures including single nanopores and nanoporous membranes have been utilized as a platform to study fundamental liquid-vapor phase change heat transfer (PCHT) processes as well as a promising candidate for high flux heat…

Applied Physics · Physics 2020-02-11 Qingyang Wang , Yang Shi , Renkun Chen

For a wide range of modern soft functional materials the selective transport of sub-nanometer-sized molecules (`penetrants') through a stimuli-responsive polymeric membrane is key to the desired function. In this study, we investigate the…

Soft Condensed Matter · Physics 2018-08-28 Matej Kanduc , Won Kyu Kim , Rafael Roa , Joachim Dzubiella

The non-wetting phenomena of water on certain solid surfaces have been under intensive study for decades, but the nature of hydrophobic/water interfaces remains controversial. Here a water/graphite interface is investigated with…

Soft Condensed Matter · Physics 2012-04-02 Ing-Shouh Hwang , Chih-Wen Yang , Yi-Hsien Lu

The present high-resolution inelastic neutron scattering experiment on ice XVII, containing molecular hydrogen with different ortho/para ratio, allows to assign the H$_2$ motion spectral bands to rotational and center-of-mass translational…

The thermodynamics of solid/liquid interfaces under nanoconfinement has tremendous implications for liquid transport properties. Here using molecular dynamics, we investigate graphite nanoslits and study how the water/graphite interfacial…

Fluid Dynamics · Physics 2022-05-17 Zixuan Wei , Mara Chiricotto , Joshua D. Elliott , Fausto Martelli , Paola Carbone

Among aquaglyceroporins that transport both water and glycerol across the cell membrane, Escherichia coli glycerol uptake facilitator (GlpF) is the most thoroughly studied. However, one question remains: Does glycerol modulate water…

Biomolecules · Quantitative Biology 2013-03-19 Liao Y. Chen

Molecular valves are becoming popular for potential biomedical applications. However, little is known concerning their performance in energy and environmental areas. Zeolite RHO shows unique pore deformations upon changes in hydration,…

We compared the diffusion of water confined in armchair and zigzag carbon nanotubes for rigid and flexible water models. Using one rigid model, TIP4P/2005, and two flexible models, SPC/Fw and SPC/FH, we found that the number of the number…

Adsorbed layers of water are ubiquitously present at surfaces and fill in microscopic pores, playing a central role in many phenomena in such diverse fields as materials science, geology, biology, tribology, nanotechnology. Despite such…

Mesoscale and Nanoscale Physics · Physics 2015-03-26 G. Algara-Siller , O. Lehtinen , F. C. Wang , R. R. Nair , U. Kaiser , H. A. Wu , I. V. Grigorieva , A. K. Geim

The energetic and transport properties of a double-stranded DNA dodecamer encapsulated in hydrophobic carbon nanotubes are probed employing two limiting nanotube diameters, D=4 nm and D=3 nm, corresponding to (51,0) and (40,0) zig-zag…

Biological Physics · Physics 2016-05-06 Fernando J. A. L. Cruz , Juan J. de Pablo , José P. B. Mota