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Understanding the adhesion between graphene and other materials is crucial for achieving more reliable graphene-based applications in electronic devices and nanocomposites. The ultra-thin profile of graphene, however, poses significant…

Materials Science · Physics 2011-11-10 Zhao Zhang , Teng Li

We perform a phenomenological analysis of the problem of the electronic doping of a graphene sheet by deposited transition metal atoms, which aggregate in clusters. The sample is placed in a capacitor device such that the electronic doping…

Strongly Correlated Electrons · Physics 2015-03-19 Jaime E. Santos , Nuno M. R. Peres , Joao M. B. Lopes dos Santos , Antonio H. Castro Neto

Graphene is believed to be an excellent candidate material for next-generation electronic devices. However, one needs to take into account the nontrivial effect of metal contacts in order to precisely control the charge injection and…

Mesoscale and Nanoscale Physics · Physics 2013-10-08 Salvador Barraza-Lopez , Markus Kindermann , M. Y. Chou

Graphene is a single layer of carbon atoms arranged in a honeycomb lattice with remarkable mechanical, electrical and optical properties. For the first time graphene layers suspended on copper meshes were installed into a gas detector…

The revealing properties of transition metal (T)-doped graphene systems are investigated with the use of the first-principles method. The detailed calculations cover the bond length, position and height of adatoms, binding energy,…

Materials Science · Physics 2019-05-06 Ngoc Thanh Thuy Tran , Duy Khanh Nguyen , Shih-Yang Lin , Godfrey Gumbs , Ming Fa-Lin

Pristine graphene interacts relatively weakly with Al, which is a specie of importance for novel generations of metal-ion batteries. We employ DFT calculations to explore the possibility of enhancing Al interaction with graphene. We…

Materials Science · Physics 2021-06-23 Jovana Vlahović , Ana S. Dobrota , Natalia V. Skorodumova , Igor A. Pašti

We calculate the potential energy surfaces for graphene adsorbed on Cu(111), Ni(111), and Co(0001) using density functional theory and the Random Phase Approximation (RPA). For these adsorption systems covalent and dispersive interactions…

Materials Science · Physics 2012-08-24 T. Olsen , J. Yan , J. J. Mortensen , K. S. Thygesen

Layered electrides, as typified by Ca$_2$N, are a new class of quasi-two-dimensional materials with low work functions. Using first-principles calculations, we have shown that a graphene layer deposited on Ca$_2$N is doped to $n=5\times…

Materials Science · Physics 2017-12-20 Takeshi Inoshita , Masaru Tsukada , Susumu Saito , Hideo Hosono

Supercapacitors store energy via the formation of an electric double layer, which generates a strong electric field at the electrode-electrolyte interface. Unlike conventional metallic electrodes, graphene-derived materials suffer from a…

Materials Science · Physics 2015-03-12 Maxwell D. Radin , Tadashi Ogitsu , Minoru Otani , Juergen Biener , Brandon C. Wood

We investigate theoretically the adhesion and electronic properties of graphene on a muscovite mica surface using the density functional theory (DFT) with van der Waals (vdW) interactions taken into account (the vdW-DF approach). We found…

Mesoscale and Nanoscale Physics · Physics 2011-01-25 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

Motivated by the recent realization of graphene sensors to detect individual gas molecules, we investigate the adsorption of H2O, NH3, CO, NO2, and NO on a graphene substrate using first-principles calculations. The optimal adsorption…

Materials Science · Physics 2009-11-13 O. Leenaerts , B. Partoens , F. M. Peeters

Graphene is a single layer of carbon atoms arranged in a honeycomb lattice with remarkable mechanical and electrical properties. Regarded as the thinnest and narrowest conductive mesh, it has drastically different transmission behaviours…

Quantum transport properties in molecularly thin perovskite/graphene heterostructure are experimentally investigated by Shubnikov-de Hass (SdH) oscillation and photo-resistance spectroscopy. We find an efficient charge transfer between the…

Mesoscale and Nanoscale Physics · Physics 2023-12-22 Yan Sun , C. Morice , D. Garrot , R. Weil , K. Watanabe , T. Taniguchi , M. Monteverde , A. D. Chepelianskii

The interaction between graphene and metals represents an important issue for the large-area preparation of graphene, graphene transfer and the contact quality in graphene devices. We demonstrate a simple method for estimating and…

Materials Science · Physics 2023-03-06 Sara D. Costa , Johan Ek Weis , Otakar Frank , Martin Kalbac

The electron band structure of graphene on SrTiO3 substrate has been investigated as a function of temperature. The high-resolution angle-resolved photoemission study reveals that the spectral width at Fermi energy and the Fermi velocity of…

The DFT/vdW-WF2s1 method, recently developed to include the van der Waals interactions in the Density Functional Theory and describe adsorption processes on metal surfaces by taking metal-screening effects into account, is applied to the…

Materials Science · Physics 2015-06-11 Pier Luigi Silvestrelli , Alberto Ambrosetti

We report angle-resolved electron transmission measurements through freestanding graphene sheets in the energy range of 18 to 30 eV above the Fermi level. The measurements are carried out in a low-energy electron point source microscope,…

Mesoscale and Nanoscale Physics · Physics 2016-08-19 Flavio Wicki , Jean-Nicolas Longchamp , Tatiana Latychevskaia , Conrad Escher , Hans-Werner Fink

The density of states (DOS) of graphene underneath a metal is estimated through a quantum capacitance measurement of the metal/graphene/SiO2/n+-Si contact structure fabricated by a resist-free metal deposition process. Graphene underneath…

Materials Science · Physics 2013-07-22 Ryota Ifuku , Kosuke Nagashio , Tomonori Nishimura , Akira Toriumi

We have performed an {\it ab initio} theoretical investigation of graphene sheet adsorbed on amorphous SiO$_2$ surface (G/a-SiO$_2$). We find that graphene adsorbs on the a-SiO$_2$ surface through van der Waals interactions. The…

Materials Science · Physics 2015-05-28 R. H. Miwa , T. M. Schmidt , A. Fazzio

We investigate charge transport in pentacene-graphene nanojunctions employing density functional theory (DFT) electronic structure calculations and the Landauer transport formalism. The results show that the unique electronic properties of…

Mesoscale and Nanoscale Physics · Physics 2013-02-26 Ivan A. Pshenichnyuk , Pedro B. Coto , Susanne Leitherer , Michael Thoss