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In the context of the exact factorization of the electron-nuclear wave function, the coupling between electrons and nuclei beyond the adiabatic regime is encoded (i) in the time-dependent vector and scalar potentials and (ii) in the…

Chemical Physics · Physics 2023-07-19 Federica Agostini , Seung Kyu Min , E. K. U. Gross

We explore nonadiabatic quantum phase transitions in an Ising spin chain with a linearly time-dependent transverse field and two different spins per unit cell. Such a spin system passes through critical points with gapless excitations,…

Statistical Mechanics · Physics 2021-02-23 Bin Yan , Vladimir Y. Chernyak , Wojciech H. Zurek , Nikolai A. Sinitsyn

We study effects of nonadiabatic couplings in a model of a diatomic molecule in the context of attosecond transient absorption spectroscopy. By using a model system consisting of four diabatic electronic states and with a variable strength…

Atomic Physics · Physics 2021-03-03 Nikolaj S. W. Ravn , Lars Bojer Madsen

Chemical relaxation phenomena, including photochemistry and electron transfer processes, form a vigorous area of research in which nonadiabatic dynamics plays a fundamental role. Here, we show that for nonadiabatic dynamics with two…

Chemical Physics · Physics 2022-07-20 Yanze Wu , Xuezhi Bian , Jonathan Rawlinson , Robert G. Littlejohn , Joseph E. Subotnik

We consider quantum dynamics for which the strict adiabatic approximation fails but which do not escape too far from the adiabatic limit. To treat these systems we introduce a generalisation of the time dependent wave operator theory which…

Quantum Physics · Physics 2015-06-16 David Viennot

We consider an inhomogeneous quantum phase transition across a multicritical point of the XY quantum spin chain. This is an example of a Lifshitz transition with a dynamical exponent z = 2. Just like in the case z = 1 considered in New J.…

Statistical Mechanics · Physics 2010-10-28 Jacek Dziarmaga , Marek M. Rams

We derive an exact solution of an explicitly time-dependent multichannel model of quantum mechanical nonadiabatic transitions. In the limit N >>1, where N is the number of states, we find that the survival probability of the initially…

Quantum Physics · Physics 2015-06-15 N. A. Sinitsyn

The dynamics of models described by a one-dimensional discrete nonlinear Schr\"odinger equation is studied. The nonlinearity in these models appears due to the coupling of the electronic motion to optical oscillators which are treated in…

Condensed Matter · Physics 2009-10-28 P. K. Datta , K. Kundu

The exactly solvable model of quasi-conical quantum dot, having a form of spherical sector is proposed. Due to the specific symmetry of the problem the separation of variables in spherical coordinates is possible in the one-electron…

Mesoscale and Nanoscale Physics · Physics 2016-08-03 Eduard Kazaryan , Lyudvig Petrosyan , Vanik Shahnazaryan , Hayk Sarkisyan

A simple one-dimensional model for SNS weak links in the ballistic limit is presented. In the presence of a bias voltage, the quasiparticle state at any given instant of time is described as a superposition of that particular set of…

Superconductivity · Physics 2009-10-31 Herbert Kroemer

We investigate coherent and incoherent tunneling phenomena in conditions of crossing diabatic potentials. We consider a model of two crossing parabolic diabatic potentials with an independent of coordinates constant adiabatic coupling. As a…

Statistical Mechanics · Physics 2007-05-23 V. A. Benderskii , E. V. Vetoshkin , E. I. Kats

Within the effective mass approximation an adiabatic description of spheroidal and dumbbell quantum dot models in the regime of strong dimensional quantization is presented using the expansion of the wave function in appropriate sets of…

Streaking of photoelectrons has long been used for the temporal characterization of attosecond extreme ultraviolet pulses. When the time-resolved photoelectrons originate from a coherent superposition of electronic states, they carry an…

Chemical Physics · Physics 2016-07-27 Markus Kowalewski , Kochise Bennett , Jérémy R. Rouxel , Shaul Mukamel

Quantum pumping, in its different forms, is attracting attention from different fields, from fundamental quantum mechanics, to nanotechnology, to superconductivity. We investigate the crossover of quantum pumping from the adiabatic to the…

An asymptotic approach for a Schroedinger type equation with non selfadjoint Hamiltonian of a special type in the case of two close degeneracy (turning) points is developed. Both real and complex degeneracy points are treated by a method of…

Mathematical Physics · Physics 2021-07-20 Ignat Fialkovsky , Maria Perel

The Schroedinger equation for N particles interacting through effective pair potentials is derived from the massless Nelson model with ultraviolet cutoffs. We consider a scaling limit where the particles are slow and heavy, but, in contrast…

Mathematical Physics · Physics 2015-06-26 Stefan Teufel

This article deals with non-adiabatic processes (i.e. processes excluded by the adiabatic theorem) from the geometrical (group-theoretical) point of view. An approximated formula for the probabilities of the non-adiabatic transitions is…

Quantum Physics · Physics 2009-11-06 M. S. Marinov , E. Strahov

The superadiabatic quantum driving, producing a perfect adiabatic transfer on a given Hamitonian by introducing an additional Hamiltonian, is theoretically analysed for transfers within a three-level system. Our starting point is the…

Quantum Physics · Physics 2016-11-18 Luigi Giannelli , Ennio Arimondo

We investigate the evolution of an electron undergoing coherent tunneling via adiabatic passage (CTAP) using the solution of the one-dimensional Schroedinger equation in both space and time for a triple well potential. We find the…

Mesoscale and Nanoscale Physics · Physics 2008-06-18 Jared H. Cole , Andrew D. Greentree , L. C. L. Hollenberg , S. Das Sarma

We reconsider the time-dependent Born-Oppenheimer theory with the goal to carefully separate between the adiabatic decoupling of a given group of energy bands from their orthogonal subspace and the semiclassics within the energy bands. Band…

Mathematical Physics · Physics 2009-11-07 Herbert Spohn , Stefan Teufel