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By analyzing the dielectric non-linearity with the Landau thermodynamic expansion, we find a simple and direct way to assess the importance of the eighth order term. Following this approach, it is demonstrated that the eighth order term is…

Materials Science · Physics 2009-11-11 Y. L. Wang , A. K. Tagantsev , D. Damjanovic , N. Setter , V. K. Yarmarkin , A. I. Sokolov

The experimentally observed temperature dependence of the quartic coefficients in the Landau-Devonshire expansion for BaTiO_3 is naturally accounted for within a proper fluctuation model. It is explained, in particular, why one of the…

Statistical Mechanics · Physics 2009-11-07 A. I. Sokolov , A. K. Tagantsev

In the paper, the description of the dielectric and ferroelectric properties of BaTiO_3 single crystals using Landau thermodynamic potential is addressed. Our results suggest that when using the sixth-power free energy expansion of the…

Statistical Mechanics · Physics 2009-11-13 Y. L. Wang , A. K. Tagantsev , D. Damjanovic , N. Setter , V. K. Yarmarkin , A. I. Sokolov , I. A. Lukyanchuk

Precise specific heat of barium titanate single crystals of different quality has been measured with special attention to the temperature region above the ferroelectric phase transition. It is shown that excess specific heat of the…

Materials Science · Physics 2013-04-19 S. V. Grabovsky , I. V. Shnaidshtein , M. Takesada , A. Onodera , B. A. Strukov

The phase transition into the ferroelectric phase in barium titanate occurs in many stages with the appearance of nonlinear phenomena. The mixed nature of the transition: displacive and order-disorder type, causes the occurrence of a…

Materials Science · Physics 2024-10-18 Olga Mazur , Ken-ichi Tozaki , Leonid Stefanovich

We investigate the influence of quantum effects on the dielectric and piezoelectric properties of barium titanate in its (low-temperature) rhombohedral phase, and show the strongly anharmonic character of this system even at low…

Materials Science · Physics 2015-06-12 Gregory Geneste , Hichem Dammak , Marc Hayoun , Mickael Thiercelin

The ferroelectric phase transition in barium titanate under pressure was studied within the framework of Landau-Ginzburg theory using differential scanning calorimetry. An innovative method for high-sensitive thermal measurements under…

Materials Science · Physics 2024-10-18 Olga Mazur , Ken-ichi Tozaki , Yukio Yoshimura , Leonid Stefanovich

The effect of Sr doping in BaTiO3 (BTO) with nominal compositions Ba0.80Sr0.20TiO3 (BSTO) have been explored in its structural, lattice vibration, dielectric, ferroelectric and electrocaloric properties. The temperature dependent dielectric…

Materials Science · Physics 2020-03-02 Satish Yadav , Mohit Chandra , R. Rawat , Vasant Sathe , A. K. Sinha , Kiran Singh

Investigating the competition between ferroelectric ordering and quantum fluctuations is essential to tailor the desired functionalities of mixed ferroelectric and incipient ferroelectric systems, like, (Ba,Sr)TiO3 and (Eu,Ba)TiO3.…

Materials Science · Physics 2021-10-26 Bommareddy Poojitha , Km Rubi , Soumya Sarkar , R. Mahendiran , T. Venkatesan , Surajit Saha

The Helmholtz free energy density is parametrized as a function of temperature and baryon density near the chiral critical point of QCD. The parametrization incorporates the expected critical exponents and amplitudes. An expansion away from…

Nuclear Theory · Physics 2014-11-21 Joseph Kapusta

Barium titanate (BaTiO$_3$) is a prototypical ferroelectric perovskite that undergoes the rhombohedral-orthorhombic-tetragonal-cubic phase transitions as the temperature increases. In this work, we develop a classical interatomic potential…

Materials Science · Physics 2016-11-23 Yubo Qi , Shi Liu , Ilya Grinberg , Andrew M. Rappe

Landau theory relates phase transitions to the minimization of the Landau functional (e.g., free energy functional), which is expressed as a power series of the order parameter. It has been shown that the critical behavior of certain…

Statistical Mechanics · Physics 2025-04-30 Krzysztof Ptaszynski , Massimiliano Esposito

In contrast to ordinary ferroelectrics where the temperature, Tm, of the permittivity maximum monotonically increases with bias field, E, in (1-x)PbMg1/3Nb2/3O3-(x)PbTiO3 (0<x<0.35) single crystals, Tm was found to remain constant or…

While anomalous diffusion coefficients with non-Arrhenius like temperature dependence are observed in a number of metals, a conclusive comprehensive framework of explanation has not been brought forward to date. Here, we use…

Materials Science · Physics 2022-07-19 Yaxian Wang , Zhangqi Chen , Wolfgang Windl , Ji-Cheng Zhao

For Sn$_2$P$_2$S$_6$ family of uniaxial ferroelectrics, the anharmonic quantum oscillators model, based on local three-well potential for spontaneous polarization fluctuations, has been used for a description of anharmonic properties,…

Materials Science · Physics 2018-09-26 R. Yevych , Yu. Vysochanskii

We study the fluctuations and correlations of conserved charges, i.e. the baryon number, electric charge and the strangeness at finite temperature and nonzero baryon chemical potential with an effective model. The fluctuations are…

High Energy Physics - Phenomenology · Physics 2010-10-27 Wei-jie Fu , Yue-liang Wu

An effect of the volume change upon proper ferroelastic (martensitic) phase transitions in cubic crystals is considered. Corresponding terms in the Ginzburg-Landau expansion of the Gibbs free energy are analyzed for the first- as well as…

Condensed Matter · Physics 2008-02-03 M. A. Fradkin

BaTiO$_3$ (BTO) is a prototypical perovskite ferroelectric, whose dielectric permittivity and loss spectra -- which are strongly temperature and frequency dependent -- include contributions from inhomogeneous polarization patterns, with…

Materials Science · Physics 2024-07-31 Ashok Gurung , Mohammad Fatin Ishtiyaq , S. Pamir Alpay , John Mangeri , Serge Nakhmanson

Shifting the Curie temperature in dependence on both uniaxial pressure and electric field in BaTiO$_3$ crystals was studied based on literature data. It was shown that both these dependences perfectly coincide when adjusting the scale.…

Materials Science · Physics 2020-12-15 E. Dul'kin , M. Roth

We show that for Ni$_3$V$_2$O$_8$ long-range ferroelectric and incommensurate magnetic order appear simultaneously in a single phase transition. The temperature and magnetic field dependence of the spontaneous polarization show a strong…

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