English
Related papers

Related papers: Exchange-Correlation Hole of a Generalized Gradien…

200 papers

In the present work, we revisit the problem of the inhomogeneous electron gas under the influence of a weak external potential, which allows us to calculate the gradient corrections to the density functional within linear response, an…

Materials Science · Physics 2026-02-03 Mario Benites , Angel Rosado , Efstratios Manousakis

A complete understanding of a material requires both knowledge of the excited states as well as of the ground state. In particular, the low energy excitations are of utmost importance while studying the electronic, magnetic, dynamical, and…

Materials Science · Physics 2019-01-30 N. Singh , P. Elliott , T. Nautiyal , J. K. Dewhurst , S. Sharma

We present and discuss some ideas concerning an ``average-pair-density functional theory'', in which the ground-state energy of a many-electron system is rewritten as a functional of the spherically and system-averaged pair density. These…

Materials Science · Physics 2009-11-11 Paola Gori-Giorgi , Andreas Savin

The exact-exchange (EXX) potential, which is obtained by solving the optimized-effective potential (OEP) equation, is compared to various approximate semilocal exchange potentials for a set of selected solids (C, Si, BN, MgO, Cu$_{2}$O, and…

Strongly Correlated Electrons · Physics 2016-08-07 Fabien Tran , Markus Betzinger , Peter Blaha , Stefan Blügel

We developed a method for calculating solid-state ground-state properties and fundamental band-gaps using a generalized Kohn-Sham approach combining a local density approximation (LDA) functional with a long-range explicit exchange orbital…

Materials Science · Physics 2019-03-27 Helen R. Eisenberg , Roi Baer

We construct a nonlocal density functional approximation with full exact exchange, while preserving the constraint-satisfaction approach and justified error cancellations of simpler semilocal functionals. This is achieved by interpolating…

Chemical Physics · Physics 2009-11-13 John P. Perdew , Viktor N. Staroverov , Jianmin Tao , Gustavo E. Scuseria

A simple approximate expression in real and reciprocal spaces is given for the static exchange-correlation kernel of a uniform electron gas interacting with the long-range part only of the Coulomb interaction. This expression interpolates…

Materials Science · Physics 2009-11-11 Julien Toulouse

The strong-interaction functionals $W_\infty[n]$ and ${W'}_\infty[n]$ play an important role in the adiabatic-connection method of Density Functional Theory. The strictly-correlated electron approach can be used to exactly compute these…

Other Condensed Matter · Physics 2026-03-09 L. A. Constantin , F. Naeem , 3 E. Fabiano , F. Sarcinella , F. Della Sala

We performed density functional calculations to estimate the formation energies of intermetallic alloys. We used two semilocal approximations, the generalized gradient approximation (GGA) by Perdew-Burke-Ernzerhof (PBE) and the strongly…

Materials Science · Physics 2020-11-25 Niraj K. Nepal , Santosh Adhikari , Bimal Neupane , Adrienn Ruzsinszky

The many-body correlation effects in the spatially separated electron and hole layers in the coupled quantum wells are investigated. The specific case of the many-component electron-hole system is considered. Keeping the main diagrams in…

Strongly Correlated Electrons · Physics 2012-11-30 V. S. Babichenko , I. Ya. Polishchuk

In the present work, first-principles calculations based on the density functional theory (DFT), GW approximation and Bethe-Salpeter equation (BSE) are performed to study the electronic and optical properties of penta-graphene (PG)…

Computational Physics · Physics 2024-01-12 Babak Minaie , Seyed A. Ketabi , José M. De Sousa

Conversion of energy of beta-particles into electric energy in a p-n junction based on direct-bandgap semiconductors, such as GaAs, considering realistic semiconductor system parameters is analyzed. An expression for the collection…

An asymptotic corrected exchange hole potential analogous to Becke-Roussel [A. D. Becke and M. R. Roussel, Phys. Rev. A 39, 3761 (1989)] is constructed by modeling the exchange hole using the generalized coordinate transformation based on…

Materials Science · Physics 2017-07-05 Subrata Jana , Hemanadhan Myneni , Prasanjit Samal

The electronic structure of noble-gas solids is calculated within density functional theory's exact-exchange method (EXX) and compared with the results from the local-density approximation (LDA). It is shown that the EXX method does not…

Materials Science · Physics 2007-05-23 R. J. Magyar , A. Fleszar , E. K. U. Gross

The van der Waals density functional (vdW-DF) of Dion et al. [Phys. Rev. Lett. 92, 246401 (2004)] is a promising approach for including dispersion in approximate density functional theory exchange-correlation functionals. Indeed, an…

Materials Science · Physics 2013-01-30 Jiří Klimeš , David R. Bowler , Angelos Michaelides

We report the successful adaptation of the quasi-boson approximation, a technique traditionally employed in nuclear physics, to the analysis of the two-dimensional electron gas. We show that the correlation energy estimated from this…

Strongly Correlated Electrons · Physics 2025-05-05 Tobias M. R. Wolf , Chunli Huang

We propose a long-range corrected hybrid meta-GGA functional, based on a global hybrid meta-GGA functional, M05 [Y. Zhao, N. E. Schultz, and D. G. Truhlar, J. Chem. Phys. 123, 161103 (2005)], and empirical atom-atom dispersion corrections.…

Chemical Physics · Physics 2015-06-03 You-Sheng Lin , Chen-Wei Tsai , Guan-De Li , Jeng-Da Chai

The Pb/Si(111) thin films were simulated within the density functional theory (DFT). The well-known Perdew-Burke-Ernzerhof (PBE) version of the generalized gradient approximation (GGA) and its recent nonempirical successor Wu-Cohen (WC)…

Mesoscale and Nanoscale Physics · Physics 2009-11-23 M. Rafiee , S. Jalali Asadabadi

We have carried out a thorough benchmark of the FDE-ET method for calculating hole transfer couplings. We have considered 10 exchange-correlation functionals, 3 non-additive kinetic energy functionals and 3 basis sets. Overall, we conclude…

Chemical Physics · Physics 2015-03-02 Pablo Ramos , Markos Papadakis , Michele Pavanello

A recently developed quasi two-dimensional exact-exchange formalism within the framework of Density Functional Theory has been applied to a strongly inhomogeneous interacting electron gas, and the results were compared with state-of-the-art…

Condensed Matter · Physics 2009-11-07 S. Rigamonti , F. A. Reboredo , C. R. Proetto