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The spatial distribution of structural relaxation in a supercooled liquid is studied using molecular dynamics simulations of a 2D binary mixture. It is shown that the spatial heterogeneity of the relaxation along with the time scale of the…

Soft Condensed Matter · Physics 2011-09-08 Asaph Widmer-Cooper , Peter Harrowell

Mutual information between local stress and local non-affine deformation is proposed as a collective field variable quantifying the {\em local softness} of soft materials. The liquid-solid transition in a simple liquid is considered as a…

Soft Condensed Matter · Physics 2025-02-18 Tamoghna Das

We study the solid-to-liquid transition in a two-dimensional fully periodic soft-glassy model with an imposed spatially heterogeneous stress. The model we consider consists of droplets of a dispersed phase jammed together in a continuous…

Soft Condensed Matter · Physics 2018-06-06 Matteo Lulli , Roberto Benzi , Mauro Sbragaglia

Super-cooled liquids are characterized by their fragility: the slowing down of the dynamics under cooling is more sudden and the jump of specific heat at the glass transition is generally larger in fragile liquids than in strong ones.…

Disordered Systems and Neural Networks · Physics 2014-01-14 Le Yan , Gustavo Düring , Matthieu Wyart

Dynamical heterogeneity is a signature phenomenon of deeply supercooled liquids and glasses. Here, we demonstrate that the spatiotemporal correlations between local relaxation events that underpin it are the result of local relaxation…

Soft Condensed Matter · Physics 2024-12-05 Rahul N. Chacko

The process of structural relaxation in disordered solids subjected to repeated tension-compression loading is studied using molecular dynamics simulations. The binary glass is prepared by rapid cooling well below the glass transition…

Soft Condensed Matter · Physics 2020-05-04 Pritam Kumar Jana , Nikolai V. Priezjev

Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the…

Soft Condensed Matter · Physics 2018-03-23 Lijin Wang , Ning Xu , W. H. Wang , Pengfei Guan

This perspective article reviews arguments that glass-forming liquids are different from those of standard liquid-state theory, which typically have a viscosity in the mPa$\cdot$s range and relaxation times of order picoseconds. These…

Soft Condensed Matter · Physics 2024-02-13 Jeppe C. Dyre

The deformation and flow of disordered solids, such as metallic glasses and concentrated emulsions, involves swift localized rearrangements of particles that induce a long-range deformation field. To describe these heterogeneous processes,…

Disordered Systems and Neural Networks · Physics 2019-01-02 Alexandre Nicolas , Ezequiel E. Ferrero , Kirsten Martens , Jean-Louis Barrat

The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…

Soft Condensed Matter · Physics 2013-03-26 Aaron S. Keys , Juan P. Garrahan , David Chandler

A broad fundamental understanding of the mechanisms underlying the phenomenology of supercooled liquids has remained elusive, despite decades of intense exploration. When supercooled beneath its characteristic melting temperature, a liquid…

Soft Condensed Matter · Physics 2016-11-10 Nicholas B. Weingartner , Chris Pueblo , Flavio S. Nogueira , K. F. Kelton , Zohar Nussinov

We explore the link between soft vibrational modes and local relaxation events in polymer glasses during physical aging, active deformation at constant strain rate, and subsequent recovery. A softness field is constructed out of the…

Soft Condensed Matter · Physics 2015-11-18 Anton Smessaert , Joerg Rottler

We numerically study the interplay between heterogeneous dynamics and properties of negatively curved regions of the potential energy surface in a model glassy system. We find that the unstable modes of saddles and quasi-saddles undergo a…

Statistical Mechanics · Physics 2007-05-23 D. Coslovich , G. Pastore

Amorphous solids, or glasses, are distinguished from crystalline solids by their lack of long-range structural order. At the level of two-body structural correlations, glassformers show no qualitative change upon vitrifying from a…

Soft Condensed Matter · Physics 2015-06-11 C. Patrick Royall , Stephen R. Williams

We derive a phase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids of water exist in several different forms. Application of large-deviation theory allows us to prepare such phases in computer…

Statistical Mechanics · Physics 2015-06-16 David T Limmer , David Chandler

We study the shear induced fluidization of amorphous solids subjected to external loading by investigating the relaxation dynamics of the deformed states using computer simulation. A simple shear deformation is employed at constant rate to…

Soft Condensed Matter · Physics 2021-12-07 Santhosh Kumar R , Bhaskar Sen Gupta

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow…

Disordered Systems and Neural Networks · Physics 2008-08-23 Simone Capaccioli , Giancarlo Ruocco , Francesco Zamponi

We perform molecular-dynamics simulations of a molecular system in supercooled states for different values of inertia parameters to provide evidence that the long-time dynamics depends only on the equilibrium structure. This observation is…

Soft Condensed Matter · Physics 2009-11-10 S. -H. Chong , F. Sciortino

One of the central problems of the liquid-glass transition is whether there is a structural signature that can qualitatively distinguish different dynamic behaviors at different degrees of supercooling. Here, we propose a novel structural…

Soft Condensed Matter · Physics 2015-09-24 Yan-Wei Li , You-Liang Zhu , Zhao-Yan Sun

We present a first principle scheme to compute the rigidity, i. e. the shear-modulus of structural glasses at finite temperatures using the cloned liquid theory, which combines the replica theory and the liquid theory. With the aid of the…

Soft Condensed Matter · Physics 2012-06-08 Hajime Yoshino