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Electronic and optical properties of semiconducting FeSe2 polymorphs (marcasite and pyrite) were evaluated using density functional theory with norm-conserving pseudopotential. Marcasite and pyrite of FeSe2 show indirect band gaps of 0.86…

Materials Science · Physics 2013-03-07 B. G. Ganga , C. Ganeshraj , A. Gopal Krishna , P. N. Santhosh

Metal intercalation into layered topological insulator materials such as the binary chalcogenide Bi2X3 (X=Te or Se) has yielded novel two-dimensional electron-gas physics, phase transitions to superconductivity, as well as interesting…

Strongly Correlated Electrons · Physics 2020-03-03 Yanan Li , Nathaniel P. Smith , William Rexhausen , Marvin A Schofield , Prasenjit Guptasarma

Electronic structure calculations using the augmented spherical wave method have been performed for CuRhO2. For this semiconductor crystallizing in the delafossite structure, it is found that the valence band maximum is mainly due to the 4d…

Strongly Correlated Electrons · Physics 2009-09-03 Antoine Maignan , Volker Eyert , Christine Martin , Stefan Kremer , Raymond Fresard , Denis Pelloquin

The electronic structure of Na2Ti2Sb2O, a parent compound of the newly discovered titanium-based oxypnictide superconductors, is studied by photon energy and polarization dependent angle-resolved photoemission spectroscopy (ARPES). The…

Superconductivity · Physics 2015-05-11 S. Y. Tan , J. Jiang , Z. R. Ye , X. H. Niu , Y. Song , C. L. Zhang , P. C. Dai , B. P. Xie , X. C. Lai , D. L. Feng

We study the electronic structure of the ferromagnetic spinel $\mathrm{Hg}\mathrm{Cr}_2\mathrm{Se}_4$ by soft-x-ray angle-resolved photoemission spectroscopy (SX-ARPES) and first-principles calculations. While a theoretical study has…

Crystal phase semiconductor heterostructures allow for electron confinement without uncertainties caused by chemical intermixing found in material heterostructures and are candidates for next generation optoelectronics devices ranging from…

Materials Science · Physics 2023-08-16 Joseph Sink , Craig Pryor

In atomically thin transition metal dichalcogenide semiconductors, there is a crossover from indirect to direct bandgap as the thickness drops to one monolayer, which comes with a fast increase of the photoluminescence signal. Here, we show…

We have used angle resolved photoemission spectroscopy to investigate the band structure of ReS$_2$, a transition-metal dichalcogenide semiconductor with a distorted 1T crystal structure. We find a large number of narrow valence bands,…

While non-nitride III-V semiconductors typically have a zincblende structure, they may also form wurtzite crystals under pressure or when grown as nanowhiskers. This makes electronic structure calculation difficult since the band structures…

Mesoscale and Nanoscale Physics · Physics 2013-03-05 Amrit De , Craig E. Pryor

Density functional theory and molecular dynamics simulations have been used to optimize the structure of nanowires of SiO2. The starting structures were based on b-cristobalite, orthotridymite, b-tridymite, and rutile crystals. The analysis…

Materials Science · Physics 2012-08-02 José I. Martínez , Federico Calle-Vallejo , Clifford M. Krowne , Julio A. Alonso

The quest for environmentally benign and stable optoelectronic materials has intensified, and chalcogenide perovskites (CPs) have emerged as promising candidates owing to their non-toxic composition, stability, small bandgaps, large…

Materials Science · Physics 2025-02-21 Ayan Chakravorty , Surajit Adhikari , Priya Johari

Due to the strong quantum confinement effect, few-layer {\gamma}-InSe exhibits a layer-dependent bandgap, spanning the visible and near infrared regions, and thus recently draws tremendous attention. As a two-dimensional material, the…

Mesoscale and Nanoscale Physics · Physics 2018-03-20 Chaoyu Song , Fengren Fan , Ningning Xuan , Shenyang Huang , Guowei Zhang , Chong Wang , Zhengzong Sun , Hua Wu , Hugen Yan

In contrast to lead-based perovskites, double perovskites have attracted considerable interest due to their ability to modulate photovoltaic properties and high stability through elemental control. However, most double perovskites are…

Materials Science · Physics 2024-11-01 Yue Kuai , Changcheng Chen , Pengfei Lu

In order to explain the reason that all the sythesised \ce{AX2MQ6} chalcogenides compounds are phase-matching while isomorphic chalcogenides compounds \ce{AX4M5Q12} are not phase-matched materials. The linear optical property birefringence…

Materials Science · Physics 2017-01-06 Jusong Yu , Hua Lin , Yujun Zheng , Liming Wu

There are few known semiconductors exhibiting both strong optical response and large dielectric polarizability. Inorganic materials with large dielectric polarizability tend to be wide-band gap complex oxides. Semiconductors with strong…

In this work, the structural, electrical, and optical properties of bilayer SiX (X= N, P, As, and Sb) are studied using density functional theory (DFT). Five different stacking orders are considered for every compound and their structural…

Materials Science · Physics 2021-07-07 Nayereh Ghobadi , Shoeib Babaee Touski

We present a first-principles density functional theory study of the structural, electronic, optical, and thermoelectric properties of Sc2BeX4 (X = S, Se) chalcogenides for energy applications. Both compounds are dynamically and…

Materials Science · Physics 2025-10-02 Ahmad Ali , Haris Haider , Sikander Azam , Muhammad Talha , Muhammad Jawad , Imran Shakir

Single-layer TaS$_2$ is epitaxially grown on Au(111) substrates. The resulting two-dimensional crystals adopt the 1H polymorph. The electronic structure is determined by angle-resolved photoemission spectroscopy and found to be in excellent…

We utilized high-energy-resolution resonant inelastic X-ray scattering (RIXS) at both the Ta and Ni $L_3$-edges to map out element-specific particle-hole excitations in Ta$_2$NiSe$_5$ across the phase transition. Our results reveal a…

First principles FLAPW-GGA method was used for the comparative study of the structural and electronic properties of three related tetragonal ThCr2Si2-type phases KFe2Ch2, where Ch are S, Se, and Te. The main trends in electronic bands,…

Superconductivity · Physics 2011-02-23 I. R. Shein , A. L. Ivanovskii