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Based on the first-principles plane wave calculations, we showed that Ca adsorbed on graphene can serve as a high-capacity hydrogen storage medium, which can be recycled by operations at room temperature. Ca is chemisorbed by donating part…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 C. Ataca , E. Akturk , S. Ciraci

The graphane with chemically bonded alkali metals (Li, Na, K) was considered as potential material for hydrogen storage. The ab initio calculations show that such material can adsorb as many as 4 hydrogen molecules per Li, Na and K metal…

Two-dimensional porous carbon nanomaterials are proven to be promising hydrogen storage substrates as they possess high surface area, large number of active sites, low molecular mass, and hydrogen molecules can be adsorbed on both sides of…

Materials Science · Physics 2023-12-05 Vikram Mahamiya , Alok Shukla , Brahmananda Chakraborty

Porous nanocarbon materials are seen as potential excellent materials for hydrogen storage due to their high surface area, excellent cycling stability and favorable kinetics. This study employs Density Functional Theory (DFT) simulations to…

Materials Science · Physics 2026-01-21 Hongyan Ma , Qing Wang , Huilin Sun , Qingyu Li , Yunhui Wang , Zhihong Yang , Huaihong Zhao , Huazhong Shu

Nanomaterials are anticipated to be promising storage media, owing to their high surface-to-mass ratio. The high hydrogen capacity achieved by using graphene has reinforced this opinion and motivated investigations of the possibility to use…

Materials Science · Physics 2013-11-26 Yuanyue Liu , Vasilii I. Artyukhov , Mingjie Liu , Avetik R. Harutyunyan , Boris I. Yakobson

Sorbent materials, such as graphene-based systems coated with Cr, are being investigated as potential hydrogen storage materials. Graphene, a 2D material with a high surface-to-volume ratio, has been employed. A comparison is conducted…

Materials Science · Physics 2025-07-30 Pratyasha Tripathy , Hetvi Jadav , Himanshu Pandey

Strain effects on the stability, electronic structure, and hydrogen storage capacity of lithium-doped graphane (CHLi) have been investigated by stateof-the art first principle density functional theory (DFT). Molecular dynamics MD)…

Materials Science · Physics 2015-06-05 Tanveer Hussain , Abir De Sarkar , Rajeev Ahuja

A promising material for hydrogen storage at room temperature-Al doped graphene was proposed theoretically by using density functional theory calculation. Hydrogen storage capacity of 5.13 wt% was predicted at T = 300 K and P = 0.1 Gpa with…

Materials Science · Physics 2009-11-13 Z. M. Ao , Q. Jiang , R. Q. Zhang , T. T. Tan , S. Li

Pristine graphene is not suitable for hydrogen storage at ambient conditions since it binds the hydrogen molecules only by van der Waals interactions. However, the adsorption energy of the hydrogen molecules can be improved by doping or…

Materials Science · Physics 2022-10-24 Vikram Mahamiya , Alok Shukla , Nandini Garg , Brahmananda Chakraborty

Hydrogen is a key player in global strategies to reduce greenhouse gas emissions. In order to make hydrogen a widely-used fuel, we require more efficient methods of storing it than the current standard of pressurized cylinders. An…

Materials Science · Physics 2025-01-14 Yasmine S. Al-Hamdani , Andrea Zen , Angelos Michaelides , Dario Alfè

We have investigated the adsorption of Li on graphene oxide using density functional theory. We show a novel and simple approach to achieve a positive lithiation potential on epoxy and hydroxyl functionalized graphene, compared to the…

Materials Science · Physics 2015-10-28 Rajiv K. Chouhan , Pushpa Raghani

The shift from fossil fuels to renewable energy sources is essential for reducing global carbon emissions and addressing climate change. Developing advanced materials for efficient hydrogen storage enables sustainable energy solutions in…

We study polylithiated molecules as building blocks for hydrogen storage materials, using first-principles calculations. $\clifour$ and $\olitwo$ bind 12 and 10 hydrogen molecules, respectively, with an average binding energy of 0.10 and…

Materials Science · Physics 2009-05-18 Süleyman Er , Gilles A. de Wijs , Geert Brocks

The ability of atomic hydrogen to chemisorb on graphene makes the latter a promising material for hydrogen storage. Based on scanning tunneling microscopy techniques, we report on site-selective adsorption of atomic hydrogen on convexly…

A simple analysis is performed for the absorption properties of graphene; sandwiched between two media. For a proper choice of media and graphene doping/gating one can approach 50-100% absorption in the GHz-THz range for the one atom thick…

Optics · Physics 2012-01-17 S. P. Apell , G. W. Hanson , C. Hägglund

From first-principles calculations, we predict that a single ethylene molecule can form a stable complex with two transition metals (TM) such as Ti. The resulting TM-ethylene complex then absorbs up to ten hydrogen molecules, reaching to…

Other Condensed Matter · Physics 2009-11-11 Engin Durgun , Salim Ciraci , W. Zhou , Taner Yildirim

Holey graphyne (HGY), a novel 2D single-crystalline carbon allotrope, was synthesized most recently by Castro-Stephens coupling reaction. The natural existing uniform periodic holes in the 2D carbon-carbon network demonstrate its tremendous…

Applied Physics · Physics 2020-04-07 Yan Gao , Huanian Zhang , Hongzhe Pan , Qingfang Li , Haifeng Wang , Jijun Zhao

We have investigated the hydrogen storage capabilities of scandium decorated holey graphyne, a recently synthesized carbon allotrope, by applying density functional theory and molecular dynamics simulations. We have observed that one unit…

Materials Science · Physics 2022-02-11 Vikram Mahamiya , Alok Shukla , Nandini Garg , Brahmananda Chakraborty

We propose a multi-layer graphene-based device in which storage and release of atomic hydrogen is obtained by exploiting and controlling the corrugation of the layers. The proposal is based on density-functional simulations of hydrogen…

Mesoscale and Nanoscale Physics · Physics 2011-01-07 Valentina Tozzini , Vittorio Pellegrini

Density function theory calculations were carried out to clarify storage states of Lithium (Li) ions in graphene clusters. The adsorption energy, spin polarization, charge distribution, electronic gap, surface curvature and dipole momentum…

Materials Science · Physics 2015-06-03 N. Kheirabadi , A. Shafiekhani
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