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Related papers: Ab-initio Green's Functions Calculations of Atoms

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A self-consistent random phase approximation (RPA) is proposed as an effective Hamiltonian method in Light-Front Field Theory (LFFT). We apply the general idea to the light-front massive Schwinger model to obtain a new bound state equation…

High Energy Physics - Theory · Physics 2009-10-31 Koji Harada

Average atom models are widely used to make equation of state tables and for calculating other properties of materials over a wide range of conditions, from zero temperature isolated atom to fully ionized free electron gases. The numerical…

Computational Physics · Physics 2018-12-05 C. E. Starrett , N. M. Gill , T. Sjostrom , C. W. Greeff

An analytical representation for the potential energy curve for the ground state $X^1\Sigma^+$ of the hydrogen fluoride molecule (HF) is presented in the frame of the Born-Oppenheimer approximation. The analytical expression for the…

Chemical Physics · Physics 2021-10-29 Laura E. Angeles Gantes , Horacio Olivares-Pilón

We introduce an orbital free electron density functional approximation based on alchemical perturbation theory. Given convergent perturbations of a suitable reference system, the accuracy of popular self-consistent Kohn-Sham density…

Chemical Physics · Physics 2020-05-27 Guido Falk von Rudorff , O. Anatole von Lilienfeld

Significant effort in applied quantum computing has been devoted to the problem of ground state energy estimation for molecules and materials. Yet, for many applications of practical value, additional properties of the ground state must be…

Quantum Physics · Physics 2022-07-13 Ruizhe Zhang , Guoming Wang , Peter Johnson

The Green's function method in the \emph{Quasiparticle Time Blocking Approximation} is applied to nuclear excitations in $^{132}$Sn and $^{208}$Pb. The calculations are performed self-consistently using a Skyrme interaction. The method…

Nuclear Theory · Physics 2008-11-26 N. Lyutorovich , J. Speth , A. Avdeenkov , F. Gruemmer , S. Kamerdzhiev , S. Krewald , V. I. Tselyaev

A novel self-consistent implementation of Hedin's GW perturbation theory is introduced. This finite-temperature method uses Hartree-Fock wave functions to represent Green's function. GW equations are solved with full potential linear…

Strongly Correlated Electrons · Physics 2015-05-13 Andrey Kutepov , Sergey Yu. Savrasov , Gabriel Kotliar

Attaining a reliable complete basis set (CBS) limit remains a significant challenge in ab initio correlated electronic-structure calculations. Building on our previous work for atoms and diatomic molecules, we present a finite-element (FE)…

Materials Science · Physics 2026-03-30 Hao Peng , Haochen Liu , Chuhao Li , Hehu Xie , Xinguo Ren

Random Phase Approximation (RPA) is the basic method for calculation of excited states of nuclei over the Hartree-Fock ground state, suitable also for energy density functionals (EDF or DFT). We developed a convenient formalism for…

Nuclear Theory · Physics 2025-06-19 Anton Repko , Jan Kvasil , V. O. Nesterenko , P. -G. Reinhard

Double excitations are crucial to understanding numerous chemical, physical, and biological processes, but accurately predicting them remains a challenge. In this work, we explore the particle-particle random phase approximation (ppRPA) as…

Chemical Physics · Physics 2024-11-26 Jincheng Yu , Jiachen Li , Tianyu Zhu , Weitao Yang

With recent developments in simulating nonadiabatic systems to high accuracy, it has become possible to determine how much energy is attributed to nuclear quantum effects beyond zero-point energy. In this work we calculate the…

Chemical Physics · Physics 2016-08-23 Yubo Yang , Ilkka Kylanpaa , Norm Tubman , Jaron Krogel , Sharon Hammes-Schiffer , David Ceperley

We recently introduced an efficient methodology to perform density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) calculations and an extension to it we called "corrected" HF DFT (C(HF)-DFT). In this work, we take a further…

Chemical Physics · Physics 2023-11-10 Daniel Graf , Alex J. W. Thom

The random phase approximation (RPA) builds in correlations left out by mean-field theory. In full 0-hbar-omega shell-model spaces we calculate the Hartree-Fock + RPA binding energy, and compare it to exact diagonalization. We find that in…

Nuclear Theory · Physics 2009-11-07 Ionel Stetcu , Calvin W. Johnson

Calculations of excited states in Green's function formalism often invoke the diagonal approximation, in which the quasiparticle states are taken from a mean-field calculation. Here, we extend the stochastic approaches applied in the…

Computational Physics · Physics 2023-09-28 Annabelle Canestraight , Xiaohe Lei , Khaled Ibrahim , Vojtech Vlcek

We extend the capabilities of correlation energy functionals based on the adiabatic-connection fluctuation-dissipation theorem by implementing the analytical atomic forces within the random phase approximation (RPA), in the context of plane…

Materials Science · Physics 2026-03-19 Damian Contant , Maria Hellgren

The Faddeev technique is employed to study the influence of both particle-particle and particle-hole phonons on the one-hole spectral function of 16O. The formalism includes the effects of nuclear fragmentation and accounts for collective…

Nuclear Theory · Physics 2007-05-23 C. Barbieri , W. H. Dickhoff

The two-time Green function method in quantum electrodynamics of high-Z few-electron atoms is described in detail. This method provides a simple procedure for deriving formulas for the energy shift of a single level and for the energies and…

Atomic Physics · Physics 2009-11-06 V. M. Shabaev

It is known that a Green's function-type condition may be used to derive rates for approximation by radial basis functions (RBFs). In this paper, we introduce a method for obtaining rates for approximation by functions which can be…

Classical Analysis and ODEs · Mathematics 2013-05-29 John Paul Ward

We present a method to integrate predictions from a theoretical model of a reaction with three bodies in the final state over the region of phase space covered by a given experiment. The method takes into account the true experimental…

A new approach proposed recently by author for the calculation of Green functions in quantum field theory and quantum mechanics is briefly reviewed. The method is applied to nonperturbative calculations for anharmonic oscillator,…

High Energy Physics - Theory · Physics 2007-05-23 V. E. Rochev