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Electromagnetic fields with complex spatial variation routinely arise in Nature. We study the response of a small molecule to monochromatic fields of arbitrary three-dimensional geometry. First, we consider the allowed configurations of the…

Optics · Physics 2010-11-23 Nan Yang , Adam E. Cohen

In this article, we review the principles of macroscopic quantum electrodynamics and discuss a variety of applications of this theory to medium-assisted atom-field coupling and dispersion forces. The theory generalises the standard mode…

Quantum Physics · Physics 2009-03-02 Stefan Scheel , Stefan Yoshi Buhmann

Molecular-scale manipulation of electronic/ionic charge accumulation in materials is a preeminent challenge, particularly in electrochemical energy storage. Layered van der Waals (vdW) crystals exemplify a diverse family of materials that…

Displacement fields are one of the main tuning knobs employed to engineer flat electronic band dispersions in twisted van der Waals multilayers. Here, we show that electric fields can also be used to tune the phonon dispersion of moir\'e…

Mesoscale and Nanoscale Physics · Physics 2025-01-20 Alejandro Ramos-Alonso , Benjamin Remez , Daniel Bennett , Rafael M. Fernandes , Hector Ochoa

We have performed {\it ab initio} calculations for a series of energetic solids to explore their structural and electronic properties. To evaluate the ground state volume of these molecular solids, different dispersion correction methods…

Materials Science · Physics 2015-09-29 S. Appalakondaiah , G. Vaitheeswaran , S. Lebègue

Electrical control of magnetism in a two-dimensional (2D) semiconductor is of great interest for emerging nanoscale low-dissipation spintronic devices. Here, we propose a general approach of tuning magnetic coupling and anisotropy of a van…

Materials Science · Physics 2021-05-05 Chengxi Huang , Jingtong Guan , Qiongyu Li , Fang Wu , Puru Jena , Erjun Kan

In 2012, Bjorkman et al. posed the question "Are we van der Waals ready?" [J. Phys.: Condens. Matter, 2012, 24, 424218] about the ability of ab initio modelling to reproduce van der Waals (vdW) dispersion forces in layered materials. The…

Materials Science · Physics 2018-03-30 Sherif Abdulkader Tawfik , Tim Gould , Catherine Stamp , Michael J. Ford

Controlling magnetism by purely electrical means is a key challenge to better information technology1. A variety of material systems, including ferromagnetic (FM) metals2,3,4, FM semiconductors5, multiferroics6,7,8 and magnetoelectric (ME)…

Mesoscale and Nanoscale Physics · Physics 2018-03-21 Shengwei Jiang , Jie Shan , Kin Fai Mak

Although the precise microscopic knowledge of van der Waals interactions is crucial for understanding bonding in weakly bonded layered compounds, very little quantitative information on the strength of interlayer interaction in these…

Materials Science · Physics 2012-06-08 T. Björkman , A. Gulans , A. V. Krasheninnikov , R. M. Nieminen

Magnetic van der Waals (vdW) materials are promising for memory and logic applications because of their highly tunable magnetic properties and compatibility with vdW heterostructure devices. However, in conventional plan-view measurements,…

We present a way to manipulate an electron trapped in a layered quantum dot based on near-threshold properties of one-body potentials. We show that potentials with a simple global parameter allows the manipulation of the wave function…

Mesoscale and Nanoscale Physics · Physics 2012-05-10 Alejandro Ferrón , Pablo Serra , Omar Osenda

Semi-local density functional approximations are widely used. None of them can capture the long-range van der Waals (vdW) attraction between separated subsystems, but they differ remarkably in the extent to which they capture…

Materials Science · Physics 2020-03-04 Santosh Adhikari , Hong Tang , Bimal Neupane , Gabor I. Csonka , Adrienn Ruzsinszky

We consider the resonant van der Waals interaction between two correlated identical two-level atoms (at least one of which being excited) within the framework of macroscopic cavity quantum electrodynamics in linear, dispersing and absorbing…

Quantum Physics · Physics 2018-05-09 Saeideh Esfandiarpour , Robert Bennett , Hassan Safari , Stefan Yoshi Buhmann

Contemporary experiments in cavity quantum electrodynamics (cavity QED) with gas-phase neutral atoms rely increasingly on laser cooling and optical, magneto-optical or magnetostatic trapping methods to provide atomic localization with…

Quantum Physics · Physics 2015-05-13 Joseph Kerckhoff , Hideo Mabuchi

A van der Waals (vdW) density functional was implemented in the mixed basis approach previously developed for studying two dimensional systems, in which the vdW interaction plays an important role. The basis functions here are taken to be…

Computational Physics · Physics 2017-12-27 Chung-Yuan Ren , Yia-Chung Chang , Chen-Shiung Hsue

The structure and stability of atomic and molecular systems with van der Waals (vdW) bonding are often determined by the interplay between attractive dispersion interactions and repulsive interactions caused by electron confinement. Arising…

Chemical Physics · Physics 2022-02-17 Ornella Vaccarelli , Dmitry V. Fedorov , Martin Stöhr , Alexandre Tkatchenko

Two-dimensional materials can be combined by placing individual layers on top of each other, so that they are bound only by their van der Waals interaction. The sequence of layers can be chosen arbitrarily, enabling an essentially…

Applied Physics · Physics 2022-03-02 Jonas Haas , Finn Ulrich , Christoph Hofer , Xiao Wang , Kai Braun , Jannik C. Meyer

By inferring the dynamic permittivity of different material media from the observations and calculating dynamic electric dipole polarizabilties of the Li through Cs alkali atoms, precise values of $C_3$ coefficients were estimated in Phys.…

Atomic Physics · Physics 2023-10-02 Harpreet Kaur , Vipul Badhan , Bindiya Arora , B. K. Sahoo

While photons in free space barely interact, matter can mediate interactions between them resulting in optical nonlinearities. Such interactions at the single-quantum level result in an on-site photon repulsion, crucial for photon-based…

Mesoscale and Nanoscale Physics · Physics 2020-06-24 Weijie Li , Xin Lu , Sudipta Dubey , Luka Devenica , Ajit Srivastava

Quantum materials with stacked van der Waals (vdW) layers hosting non-trivial band structure topology and magnetism have shown many interesting properties. Using high throughput density functional theory calculations, we design and predict…