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Two approaches for the efficient rational approximation of the Fermi-Dirac function are discussed: one uses the contour integral representation and conformal mapping and the other is based on a version of the multipole representation of the…

Numerical Analysis · Mathematics 2009-12-14 Lin Lin , Jianfeng Lu , Lexing Ying , E Weinan

We present a method to compute the Fermi function of the Hamiltonian for a system of independent fermions, based on an exact decomposition of the grand-canonical potential. This scheme does not rely on the localization of the orbitals and…

Materials Science · Physics 2009-11-13 Michele Ceriotti , Thomas Kuehne , Michele Parrinello

Multipoles provide a systematic framework for describing the electronic structures of quantum materials from a symmetry perspective. Thermodynamic multipole moments in crystalline solids exhibit direct microscopic connections to certain…

Mesoscale and Nanoscale Physics · Physics 2026-04-01 Takumi Sato , Satoru Hayami

Linear-scaling electronic structure methods based on the calculation of moments of the underlying electronic Hamiltonian offer a computationally efficient and numerically robust scheme to drive large-scale atomistic simulations, in which…

Materials Science · Physics 2017-01-09 Eunan J. McEniry , Ralf Drautz

Accurate rational approximations of the Fermi-Dirac distribution are a useful component in many numerical algorithms for electronic structure calculations. The best known approximations use $O( \log (\beta \Delta) \log (\epsilon^{-1}))$…

Computational Physics · Physics 2016-11-11 Jonathan E. Moussa

A version of the configuration interaction method, which has been recently developed to deal with large number of valence electrons, has been used to calculate magnetic dipole and electric quadrupole hyperfine structure constants for a…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

We present a second-order recursive Fermi-operator expansion scheme using mixed precision floating point operations to perform electronic structure calculations using tensor core units. A performance of over 100 teraFLOPs is achieved for…

A rational expansion of the Fermi density operator is proposed. This approach allows to calculate efficiently physical properties of fermionic systems at finite temperatures without solving an eigenvalue problem. Using N evaluations of the…

Computational Physics · Physics 2009-10-30 F. Gagel

In this chapter we focus first on the theoretical methods and relevant computational approaches to calculate the electronic structure of atoms, molecules, and clusters containing heavy elements for which relativistic effects become…

Chemical Physics · Physics 2021-10-05 Simone Taioli , Stefano Simonucci

In a recent paper we have suggested that the finite temperature density matrix can be computed efficiently by a combination of polynomial expansion and iterative inversion techniques. We present here significant improvements over this…

Materials Science · Physics 2010-10-19 Michele Ceriotti , Thomas D. Kühne , Michele Parrinello

We present several finite-temperature recursive Fermi-operator expansion schemes based on the second-order spectral projection (SP2) method. Our approach builds on a previous observation that the electronic structure problem, as formulated…

We theoretically describe the optical computation of the divergence of a two-dimensional vector field, which is composed by the transverse electric field components of an incident light beam. The divergence is computed in reflection at…

The generalized Fermi-Dirac functions and their derivatives are important in evaluating the thermodynamic quantities of partially degenerate electrons in hot dense stellar plasmas. New recursion relations of the generalized Fermi-Dirac…

Astrophysics · Physics 2009-11-06 Zhigang Gong , Ladislav Zejda , Werner Dappen , Josep M. Aparicio

We present an analytically solvable model for correlated electrons, which is able to capture the major Fermi surface modifications occurring in both hole- and electron-doped cuprates as a function of doping. The proposed Hamiltonian…

Strongly Correlated Electrons · Physics 2024-10-18 Paul Worm , Matthias Reitner , Karsten Held , Alessandro Toschi

The nuclear energy density functional method at finite temperature is a useful tool for studies of nuclear structure at high excitation, and also for researches of nuclear matter involved in explosive stellar phenomena and neutron stars.…

Nuclear Theory · Physics 2023-03-02 Takashi Nakatsukasa

Smooth, highly accurate analytical representations of Fermi-Dirac (FD) integral combinations important in free-energy density functional calculations are presented. Specific forms include those that occur in the local density approximation…

Computational Physics · Physics 2015-04-21 Valentin V. Karasiev , Debajit Chakraborty , S. B. Trickey

Explicit treatment of many-body Fermi statistics in path integral Monte Carlo (PIMC) results in exponentially scaling computational cost due to the near cancellation of contributions to observables from even and odd permutations. Through…

Strongly Correlated Electrons · Physics 2014-09-12 Jonathan L DuBois , Ethan W. Brown , Berni J. Alder

We present extensive \textit{ab initio} path integral Monte Carlo (PIMC) simulations of two-dimensional quantum dipole systems in a harmonic confinement, taking into account both Bose- and Fermi-statistics. This allows us to study the…

Computational Physics · Physics 2020-08-12 Tobias Dornheim

The Fermi surface is an abstract object in the reciprocal space of a crystal lattice, enclosing the set of all those electronic band states that are filled according to the Pauli principle. Its topology is dictated by the underlying lattice…

Strongly Correlated Electrons · Physics 2016-07-20 Mukunda P. Das , Frederick Green

Discretizing an analytic function on a uniform real-space grid is often done via a straightforward collocation method. This is ubiquitous in all areas of computational physics and quantum chemistry. An example in Density Functional Theory…

Computational Physics · Physics 2016-01-20 Luigi Genovese , Thierry Deutsch
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