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Related papers: Adiabatic-connection fluctuation-dissipation densi…

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Using Green-function many-body theory, we present the details of a formally exact adiabatic-connection fluctuation-dissipation density-functional theory based on range separation, which was sketched in Toulouse, Gerber, Jansen, Savin and…

Chemical Physics · Physics 2010-09-13 Julien Toulouse , Wuming Zhu , Janos G. Angyan , Andreas Savin

We present a graphical analysis of the adiabatic connections underlying double-hybrid density-functional methods that employ second-order perturbation theory. Approximate adiabatic connection formulae relevant to the construction of these…

Chemical Physics · Physics 2013-06-26 Yann Cornaton , Odile Franck , Andrew M. Teale , Emmanuel Fromager

We present calculations of the correlation energies of crystalline solids and isolated systems within the adiabatic-connection fluctuation-dissipation formulation of density-functional theory. We perform a quantitative comparison of a set…

Materials Science · Physics 2016-07-29 Christopher E. Patrick , Kristian S. Thygesen

We explore several random phase approximation (RPA) correlation energy variants within the adiabatic-connection fluctuation-dissipation theorem approach. These variants differ in the way the exchange interactions are treated. One of these…

Chemical Physics · Physics 2014-04-08 János G. Angyán , Ru-Fen Liu , Julien Toulouse , Georg Jansen

We consider a dynamical system subjected to weak but adiabatically slow fluctuations of external origin. Based on the ``adiabatic following'' approximation we carry out an expansion in \alpha/|\mu|, where \alpha is the strength of…

Statistical Mechanics · Physics 2009-10-31 S. K. Banik , D. S. Ray

In this paper, an alternative method to range-separated linear-response time-dependent density-functional theory and perturbation theory is proposed to improve the estimation of the energies of a physical system from the energies of a…

Chemical Physics · Physics 2015-06-24 Elisa Rebolini , Julien Toulouse , Andrew M. Teale , Trygve Helgaker , Andreas Savin

Long-range exchange and correlation effects, responsible for the failure of currently used approximate density functionals in describing van der Waals forces, are taken into account explicitly after a separation of the electron-electron…

Materials Science · Physics 2009-11-11 Janos G. Angyan , Iann C. Gerber , Andreas Savin , Julien Toulouse

We investigate the construction of approximated exchange-correlation functionals by interpolating locally along the adiabatic connection between the weak- and the strong-coupling regimes, focussing on the effect of using approximate…

Chemical Physics · Physics 2017-04-05 Stefan Vuckovic , Lucas O. Wagner , Andrew M. Teale , Paola Gori-Giorgi

Interatomic pairwise methods are currently among the most popular and accurate ways to include dispersion energy in density functional theory (DFT) calculations. However, when applied to more than two atoms, these methods are still…

Chemical Physics · Physics 2014-10-13 Alexandre Tkatchenko , Alberto Ambrosetti , Robert A. DiStasio

The adiabatic connection of density functional theory (DFT) for electronic systems is generalized here to negative values of the coupling strength $\alpha$ (with {\em attractive} electrons). In the extreme limit $\alpha\to-\infty$ a simple…

Other Condensed Matter · Physics 2015-05-14 Michael Seidl , Paola Gori-Giorgi

Recent experimental advances in strongly coupled light-matter systems has sparked the development of general ab-initio methods capable of describing interacting light-matter systems from first principles. One of these methods,…

Chemical Physics · Physics 2022-10-12 Johannes Flick

Recently there has been a renewed interest in the calculation of exact-exchange and RPA correlation energies for realistic systems. These quantities are main ingredients of the so-called EXX/RPA+ scheme which has been shown to be a…

Materials Science · Physics 2009-07-22 Huy-Viet Nguyen , Stefano de Gironcoli

The adiabatic connection fluctuation-dissipation theorem with the random phase approximation (RPA) has recently been applied with success to obtain correlation energies of a variety of chemical and solid state systems. The main merit of…

Materials Science · Physics 2015-03-20 Thomas Olsen , Kristian S. Thygesen

We investigate the adiabatic approximation to the exact-exchange kernel for calculating correlation energies within the adiabatic-connection fluctuation-dissipation framework of time-dependent density functional theory. A numerical study is…

Chemical Physics · Physics 2023-05-12 Maria Hellgren , Lucas Baguet

In the current density functional theory of linear and nonlinear time-dependent phenomena, the treatment of exchange and correlation beyond the level of the adiabatic local density approximation is shown to lead to the appearance of…

Condensed Matter · Physics 2009-10-30 G. Vignale , C. A. Ullrich , S. Conti

We present a system composed of two flux qubits and a transmission-line resonator. Instead of using the rotating wave approximation (RWA), we analyse the system by the adiabatical approximation methods under two opposite extreme conditions.…

Quantum Physics · Physics 2015-06-04 Ping Yang , Zhi-Ming Zhang

We formulate an adiabatic connection for the exchange-correlation energy in terms of pairing matrix fluctuation. This connection opens new channels for density functional approximations based on pairing interactions. Even the simplest…

Chemical Physics · Physics 2015-06-16 Helen van Aggelen , Yang Yang , Weitao Yang

We show that the time dependent single electron, nuclear density matrix of an interacting electronic system coupled to nuclear degrees of freedom can be exactly reproduced by that of an electronic system with arbitrarily specified…

Materials Science · Physics 2009-02-07 Vinod Krishna

We present a new method for realizing the adiabatic connection approach in density functional theory, which is based on combining accurate variational quantum Monte Carlo calculations with a constrained optimization of the ground state…

Materials Science · Physics 2015-06-25 Maziar Nekovee , W. M. C. Foulkes , A. J. Williamson , G. Rajagopal , R. J. Needs

We consider the response of a dynamical system driven by external adiabatic fluctuations. Based on the `adiabatic following approximation' we have made a systematic separation of time-scales to carry out an expansion in $\alpha |\mu|^{-1}$,…

Statistical Mechanics · Physics 2009-10-31 S. K. Banik , J. R. Chaudhuri , D. S. Ray
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