Related papers: Temperature-driven phase transitions in SrBi$_2$Ta…
Full pattern Le-Bail refinement using x-ray powder diffraction profiles of Sr1-xCaxTiO3 for x=0.02, 0.04 in the temperature range 12 to 300 K reveals anomalies in the unit cell parameters at 170, 225 K due to an antiferrodistortive (cubic…
Motivated by the experimental synthesis of two-dimensional (2D) perovskite materials, we study the stability of 2D SrTiO$_3$ from first principles. We find that the TiO$_6$ octahedral rotations emerge in 2D SrTiO$_3$ with a rotation angle…
The rotational instability of the electric polarization P during phase transformations between ferroelectric phases is of great practical interest, since it may be accompanied by extremely large values of the piezoelectric coefficient, and…
In transition metal perovskites (ABO3) most physical properties are tunable by structural parameters such as the rotation of the BO6 octahedra. Examples include the N\'eel temperature of orthoferrites, the conductivity of mixed-valence…
The temperature-dependent phase transitions in Ruddlesden-Popper oxides with perovskite bilayers have been under increased scrutiny in recent years due to the so-called hybrid improper ferroelectricity that some chemical compositions…
We present here the results of frequency dependent dielectric, polarization and powder X-ray powder diffraction studies in the 300 to 100K temperature range for Ba_0.55Sr_0.45TiO_3. The dielectric results indicate a succession of three…
The results for dilatometric, ultrasonic velocity and the domain struct-ure studies of Cs3Bi2I9 crystals in the course of ferroelastic phase trans-ition are presented. It is shown that the phase transition in Cs3Bi2I9 is of the first order.…
The magnetic compound Ba_2CuGe_2O_7 has recently been shown to be an essentially two-dimensional spiral antiferromagnet that exhibits an incommensurate-to-commensurate phase transition when a magnetic field applied along the c-axis exceeds…
EuTiO_{3} undergoes a structural phase transition from cubic to tetragonal at T_S = 282 K which is not accompanied by any long range magnetic order. However, it is related to the oxygen ocathedra rotation driven by a zone boundary acoustic…
The highly mobile electrons at the interface of SrTiO3 with other oxide insulators, such as LaAlO3 or AlOx, are of great current interest. A vertical gate voltage allows controlling a metal/superconductor-to-insulator transition, as well as…
We have recently predicted and subsequently verified experimentally by specific heat measurements that EuTiO3 undergoes a structural phase transition at elevated temperature TS = 282 K. The origin of the phase transition has been attributed…
The metamagnetic transition between the antiferromagnetic and paramagnetic state in UIrGe has been studied at various temperatures by magnetization, heat capacity and magnetocaloric-effect measurements on a single crystal in static and…
The origin of the very large piezoelectric response observed in the vicinity of the morphotropic phase boundary (MPB) in perovskite lead zirconate titanate and related systems has been under intensive studies. Polarization rotation ideas…
I critically examine Goodenough's explanation for the experimentally observed phase transition in LiVO$_2$ using microscopic calculations based on density functional and dynamical mean field theories. The high-temperature rhombohedral phase…
Two correlated superconducting phases are identified in layered superconductor BaTi2(Sb1-xBix)2O (x=0.16), with the superconducting transition temperatures of TC = 6 K (the high TC phase) and 3.4 K (the low TC Phase), respectively. The 6 K…
We present temperature-dependent single-crystal diffraction results on seven antifluorite-type $A_2MeX_6$ compounds with $Me$=Os or Ir: K$_2$OsCl$_6$, $A_2$OsBr$_6$ with $A$=K, Rb, Cs and NH$_4$, and K$_2$Ir$X_6$ with $X$=Cl and Br. The…
It is shown that the properties of the superconductivity observed in Sr$_2$RuO$_4$ can be accounted for by properly taking into account the internal degrees of freedom of the system. The electrons are strongly correlated in the RuO$_2$…
The two dimensional electron gas formed between the two band insulators SrTiO3 and LaAlO3 exhibits a variety of interesting physical properties which make it an appealing material for use in future spintronics and/or quantum computing…
Pressure induced phase transitions of MIAgIIF3 perovskites where M = K, Rb, Cs, have been predicted theoretically for the first time for pressures up to 100 GPa. The sequence of phase transitions for M = K and Rb consists of an orthorhombic…
A detailed elastic neutron scattering study of the structural and magnetic phase transitions in single-crystal SrFe$_2$As$_2$ reveals that the orthorhombic (O)-tetragonal (T) and the antiferromagnetic transitions coincide at $T_\texttt{O}$…