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We present some of the universal properties in ion-atom interaction derived from a newly formulated quantum-defect theory for $-1/r^4$ type of long-range interactions. For bound states, we present the universal bound spectrum, namely the…

Atomic Physics · Physics 2010-06-04 Bo Gao

We show that ultracold chemical reactions can be manipulated and controlled by using Rydberg-dressed interactions. Scattering in the ultracold regime is sensitive to long-range interactions, especially when weakly bound (or quasi-bound)…

Atomic Physics · Physics 2015-06-19 Jia Wang , Jason N. Byrd , Ion Simbotin , R. Côté

We present a comprehensive collection of ultracold three-body collisions properties near overlapping Feshbach resonances. Our results incorporate variations of all scattering lengths and demonstrate novel collisional behavior, such as…

Atomic Physics · Physics 2015-05-13 J. P. D'Incao , B. D. Esry

Chemical reaction rates often depend strongly on stereodynamics, namely the orientation and movement of molecules in three-dimensional space. An ultracold molecular gas, with a temperature below 1 uK, provides a highly unusual regime for…

Quantum Physics · Physics 2016-11-25 M. H. G. de Miranda , A. Chotia , B. Neyenhuis , D. Wang , G. Quemener , S. Ospelkaus , J. L. Bohn , J. Ye , D. S. Jin

Chemical reactions can be surprisingly efficient at ultracold temperatures ( < 1mK) due to the wave nature of atoms and molecules. The study of reactions in the ultracold regime is a new research frontier enabled by cooling and trapping…

Atomic Physics · Physics 2017-01-16 Lee R. Liu , Jessie T. Zhang , Yichao Yu , Nicholas R. Hutzler , Yu Liu , Till Rosenband , Kang-Kuen Ni

We consider controlled collisions between two ultracold atoms guided by external harmonic potentials. We derive analytical solutions of the Schroedinger equation for this system, and investigate the properties of eigenergies and eigenstates…

Quantum Gases · Physics 2009-10-30 Michał Krych , Zbigniew Idziaszek

We investigate the presence of Feshbach resonances in ultracold alkali-dialkali reactive collisions. Quantum scattering calculations are performed on a new Na_3 quartet potential energy surface. An analysis of scattering features is…

Quantum Physics · Physics 2009-11-13 A. Simoni , J-M. Launay , P. Soldan

Quantum control of reactive systems has enabled microscopic probes of underlying interaction potentials, the opening of novel reaction pathways, and the alteration of reaction rates using quantum statistics. However, extending such control…

It has recently become possible to form molecules in ultracold gases of trapped alkali metal atoms. Once formed, the molecules may undergo elastic, inelastic and reactive collisions. Inelastic and reactive collisions are particularly…

Atomic Physics · Physics 2010-03-09 Jeremy M. Hutson , Pavel Soldan

Scattering resonances are an essential tool for controlling interactions of ultracold atoms and molecules. However, conventional Feshbach scattering resonances, which have been extensively studied in various platforms, are not expected to…

We explore the feasibility of optically forming long-range tetratomic and larger polyatomic molecules in their ground electronic state from ultracold pairs of polar molecules aligned by external fields. Depending on the relative orientation…

Atomic Physics · Physics 2021-06-16 Marko Gacesa , Jason N. Byrd , Jonathan Smucker , John A. Montgomery, , Robin Côté

Rapid progress in atomic, molecular, and optical (AMO) physics techniques enabled the creation of ultracold samples of molecular species and opened opportunities to explore chemistry in the ultralow temperature regime. In particular, both…

Chemical Physics · Physics 2020-05-04 Yu Liu , David D. Grimes , Ming-Guang Hu , Kang-Kuen Ni

The collision of molecules at ultracold temperatures is of great importance for understanding the chemical interactions at the quantum regime. While much theoretical work has been devoted to this, experimental data are only available…

Quantum Gases · Physics 2018-01-30 Xin Ye , Mingyang Guo , Maykel L. González-Martínez , Goulven Quéméner , Dajun Wang

In systems of ultracold atoms, pairwise interactions are resonantly enhanced by the application of an oscillating magnetic field that is parallel to the spin-quantization axis of the atoms. The resonance occurs when the frequency of the…

Quantum Gases · Physics 2016-11-17 D. Hudson Smith

Ultra-cold RbCs molecules in high-lying vibrational levels of the a$^3\Sigma^+$ ground electronic state are confined in an optical trap. Inelastic collision rates of these molecules with both Rb and Cs atoms are determined for individual…

We investigate the properties of two interacting ultracold polar molecules described as distinguishable quantum rigid rotors, trapped in a one-dimensional harmonic potential. The molecules interact via a multichannel two-body contact…

Atomic Physics · Physics 2018-07-03 Anna Dawid , Maciej Lewenstein , Michał Tomza

We consider ultracold, chemically reactive scattering collisions of the diatomic molecules KRb. When two such molecules collide in an ultracold gas, we find that they are energetically forbidden from reacting to form the trimer species…

Atomic Physics · Physics 2015-05-18 Edmund R. Meyer , John L. Bohn

Ultracold molecules can be associated from ultracold atoms by ramping the magnetic field through a Feshbach resonance. A reverse ramp dissociates the molecules. Under suitable conditions, more than one outgoing partial wave can be…

We extend Multichannel Quantum Defect Theory (MQDT) to ultracold collisions involving high partial wave quantum numbers $L$. This requires a careful standardization of the MQDT reference wave functions at long range to ensure their linear…

Atomic Physics · Physics 2015-06-12 Brandon P. Ruzic , Chris H. Greene , John L. Bohn

Multichannel quantum defect theory (MQDT) provides a powerful toolkit for describing and understanding collisions of cold alkali atoms. Various MQDT approximations differ primarily in how they characterize the so-called short-ranged…

Atomic Physics · Physics 2023-08-01 Alyson Laskowski , Nirav Mehta