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Platelet-like single crystals of the Ca(Fe1-xCox)2As2 series having lateral dimensions up to 15 mm and thickness up to 0.5 mm were obtained from the high temperature solution growth technique using Sn flux. Upon Co doping, the c-axis of the…

Co-doping of lanthanum and phosphorus in CaFe2As2 induces superconductivity at 45 K. This superconducting transition temperature is higher than the 38 K transition in Ba1-xKxFe2As2, which is the maximum found thus far among the 122 phases.…

Polycrystalline samples with nominal composition of Ba(Fe1-xIrx)2As2 (x=0.10, 0.15, and 0.20) were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), electrical resistivity, and magnetization measurements.…

Superconductivity · Physics 2015-05-14 X. L. Wang , H. Y. Shi , X. W. Yan , Y. C. Yuan , Z. -Y. Lu , X. Q. Wang , T. -S. Zhao*

Magnetization, susceptibility, specific heat, resistivity, neutron and x-ray diffraction have been used to characterize the properties of single crystalline CaFe2-xNixAs2 as a function of Ni doping for x varying from 0 to 0.1. The combined…

Establishing a complete electronic phase diagram for REFeAsO (RE = rare earth, RE1111) ironbased superconductors has remained experimentally challenging. Here, we report a systematic investigation of PrFeAsO1-xFx over the full nominal…

Utilizing the high stability of calcium and rare earth hydrides, CaFeAsF1-xHx (x = 0.0-1.0) and SmFeAsO1-xHx (x = 0.0-0.47) have been first synthesized using high pressure to form hydrogen-substituted 1111 type iron-arsenide…

We report the interplay between charge-density-wave (CDW) and superconductivity of 1$T$-Fe$_{x}$Ta$_{1-x}$S$_{2}$ ($0\leq x \leq 0.05$) single crystals. The CDW order is gradually suppressed by Fe-doping, accompanied by the disappearance of…

Superconductivity · Physics 2013-01-11 L. J. Li , W. J. Lu , X. D. Zhu , L. S. Ling , Z. Qu , Y. P. Sun

We report the successful substitution of cobalt, nickel, and copper for iron in the 1038 phase parent compound Ca$_{10}$(FeAs)$_{10}$(Pt$_3$As$_8$) yielding Ca$_{10}$(Fe$_{1-x}$Co$_x$As)$_{10}$(Pt$_3$As$_8$),…

Superconductivity · Physics 2014-10-29 Tobias Stürzer , Fabian Kessler , Dirk Johrendt

Superconductivity was achieved in Ti-doped iron-arsenide compound Sr4Cr0.8Ti1.2O6Fe2As2 (abbreviated as Cr-FeAs-42622). The x-ray diffraction measurement shows that this material has a layered structure with the space group of…

Superconductivity · Physics 2015-05-13 Xiyu Zhu , Fei Han , Gang Mu , Peng Cheng , Bing Shen , Bin Zeng , Hai-Hu Wen

Single crystals of the Ni-doped FeAs-based superconductor SrFe2-xNixAs2 were grown using a self-flux solution method and characterized via x-ray measurements and low temperature transport, magnetization, and specific heat studies. A doping…

Superconductivity · Physics 2009-06-17 S. R. Saha , N. P. Butch , K. Kirshenbaum , Johnpierre Paglione

Compounds of Sr1-xLaxFe2As2 were synthesized by solid state reaction at 1273 K, under pressures of 2 or 3 GPa. The Sr1-xLaxFe2As2 phase was dominant up to x = 0.5, and superconductivity was observed at $x \ge 0.2$. A maximum critical…

Superconductivity · Physics 2015-05-18 Yoshinori Muraba , Satoru Matsuishi , Sung-Wng Kim , Toshiyuki Atou , Osamu Fukunaga , Hideo Hosono

Hydrogen is the simplest bipolar element and its valence state can be controlled from +1 to -1. We synthesized the 1111-type CaFeAsH and LnFeAsO1-xHx (Ln = lanthanide) with the ZrCuSiAs type structure by a high-pressure synthesis method.…

Superconductivity · Physics 2017-08-02 Hideo Hosono , Satoru Matsuishi

By substituting the Fe with the 4d and 5d-transition metals Rh, Ir and Pd in SrFe_2As_2, we have successfully synthesized a series of superconductors SrFe_{2-x}M_xAs_2 (M = Rh, Ir and Pd) and explored the phase diagrams of them. The…

Superconductivity · Physics 2016-06-28 Fei Han , Xiyu Zhu , Peng Cheng , Gang Mu , Ying Jia , Lei Fang , Yonglei Wang , Huiqian Luo , Bin Zeng , Bing Shen , Lei Shan , Cong Ren , Hai-Hu Wen

Aliovalent rare earth substitution into the alkaline earth site of CaFe2As2 single-crystals is used to fine-tune structural, magnetic and electronic properties of this iron-based superconducting system. Neutron and single crystal x-ray…

Superconductivity · Physics 2015-03-19 S. R. Saha , N. P. Butch , T. Drye , J. Magill , S. Ziemak , K. Kirshenbaum , P. Y. Zavalij , J. W. Lynn , J. Paglione

CaFeAsF is an iron-based superconductor parent compound whose Fermi surface is quasi-two dimensional, composed of Dirac-electron and Schr\"odinger-hole cylinders elongated along the $c$ axis. We measured the longitudinal and Hall…

In rare-earth doped single crystalline CaFe2As2, the mysterious small volume fraction which superconducts up to 49 K, much higher than the bulk Tc ~ 30s K, has prompted a long search for a hidden variable that could enhance the Tc by more…

Superconductivity · Physics 2016-02-16 F. Y. Wei , B. Lv , L. Z. Deng , J. K. Meen , Y. Y. Xue , C. W. Chu

We report a systematic and ab-initio electronic structure calculation of Ca0.75 M0.25 Fe2 As2 with M = Ca, Sr, Eu, La, Ce, Pr, Nd, Pm, Sm, Na, K, Rb. The recently reported experimentally observed structural trends in rare earths-doped CaFe2…

Superconductivity · Physics 2014-06-26 A. Sanna , G. Profeta , S. Massidda , E. K. U. Gross

Using one-step solid state reaction method, we have successfully synthesized the superconductor SrFe1-xRuxAs. X-ray diffraction indicates that the material has formed the ThCr2Si2-type structure with a space group I4/mmm. The systematic…

Superconductivity · Physics 2015-05-13 Yanpeng Qi , Lei Wang , Zhaoshun Gao , Dongliang Wang , Xianping Zhang , Yanwei Ma

The effects of pressure on antiferromagnetic (AFM) and superconducting phase transitions of 112-type Ca$_{1-x}$La$_{x}$FeAs$_{2}$ were studied, and the in-plane electrical resistivity $\rho_{ab}$ was measured with an indenter-type pressure…

Here we report the superconductivity in the LaFeAsO1-xFx system prepared by high pressure synthesis. The highest onset superconducting transition temperature (Tc) in this La-based system is 41.0 K with the nominal composition of…