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We report a theoretical study of the thermopower of single-molecule junctions, with focus on phenyl-based molecular junctions. In contrast to prior studies, thermal fluctuations of the torsional angle between the phenyl rings and variations…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Yonatan Dubi

Symmetry relations are manifestations of fundamental principles and constitute cornerstones of modern physics. An example are the Onsager relations between coefficients connecting thermodynamic fluxes and forces, central to transport theory…

Mesoscale and Nanoscale Physics · Physics 2014-12-11 J. Matthews , F. Battista , D. Sanchez , P. Samuelsson , H. Linke

Molecular junctions comprise small molecules on the order of one or a few nanometers in length, chemically attached to two electrodes of metal or semiconductors. They have recently been identified as promising candidates for…

Mesoscale and Nanoscale Physics · Physics 2021-11-12 Andrea Gemma , Bernd Gotsmann

The nonlinear Seebeck effect, nonlinear conversion of a temperature gradient into an electric current, was observed at room temperature. Based on a second-harmonic lock-in method combined with an a.c. temperature gradient, $\nabla T$, we…

Strongly Correlated Electrons · Physics 2025-07-08 Y. Hirata , T. Kikkawa , H. Arisawa , E. Saitoh

We investigate the thermoelectric properties of Fe/MgO/Fe(001) magnetic tunnel junctions (MTJs) by means of the linear-response theory combined with a first-principles-based Landauer-B\"uttiker approach. We find that the Seebeck coefficient…

Materials Science · Physics 2020-03-27 Kaoru Yamamoto , Keisuke Masuda , Ken-ichi Uchida , Yoshio Miura

We study electrical and thermoelectrical properties for a double quantum dot system. We consider the cases of both single-level and multilevel quantum dots whatever the way they are coupled, either in a series or in a parallel arrangement.…

Mesoscale and Nanoscale Physics · Physics 2020-09-28 M. Lavagna , V. Talbo , T. Q. Duong , A. Crépieux

Thermoelectric effects result from the coupling of charge and heat transport, and can be used for thermometry, cooling and harvesting of thermal energy. The microscopic origin of thermoelectric effects is a broken electron-hole symmetry,…

Superconductivity · Physics 2016-04-08 S. Kolenda , P. Machon , D. Beckmann , W. Belzig

The thermoelectric voltage developed across an atomic metal junction (i.e., a nanostructure in which one or a few atoms connect two metal electrodes) in response to a temperature difference between the electrodes, results from the quantum…

We introduce a direct (Seebeck) and inverse (Peltier) thermoelectric effect induced by electron tunneling between closely separated conducting films. When a transverse temperature gradient is applied along one of two films, a bias voltage…

Mesoscale and Nanoscale Physics · Physics 2024-09-10 Mauricio Gómez Viloria , Riccardo Messina , Philippe Ben-Abdallah

We study charge and heat transport from first-principles in the topological Weyl semimetal TaAs. Electron-phonon coupling matrix elements are calculated using density functional perturbation theory and used to derive the thermo-electric…

Materials Science · Physics 2025-05-22 Guillaume E. Allemand , Matteo Giantomassi , Matthieu J. Verstraete

Here we present a theoretical study of the thermoelectric transport through {[}2,2{]}para\-cyclo\-phane-based single-molecule junctions. Combining electronic and vibrational structures, obtained from density functional theory (DFT), with…

Mesoscale and Nanoscale Physics · Physics 2017-04-07 Marius Bürkle , Thomas J. Hellmuth , Fabian Pauly , Yoshihiro Asai

In the present work we theoretically analyze thermoelectric transport in single-molecule junctions (SMJ) characterized by strong interactions between electrons on the molecular linkers and phonons in their nuclear environments where…

Mesoscale and Nanoscale Physics · Physics 2024-01-17 Natalya A. Zimbovskaya

Thermoelectric effects in magnetic nanostructures and the so-called spin caloritronics are attracting much interest. Indeed it provides a new way to control and manipulate spin currents which are key elements of spin-based electronics. Here…

A systematic analysis of thermodynamic properties performed on Ce-base exemplary compounds allows to identify different types of behaviors as the system approaches the quantum critical region. They are recognized in the respective magnetic…

Strongly Correlated Electrons · Physics 2011-08-02 Julian G. Sereni

The spin Seebeck effect is studied across a charge insulating magnetic junction, in which thermal-spin conjugate transport is assisted by the exchange interactions between the localized spin in the center and electrons in metallic leads. We…

Mesoscale and Nanoscale Physics · Physics 2014-06-23 Jie Ren , Jonas Fransson , Jian-Xin Zhu

In this paper we investigate the effect of strong electronic interactions on the thermoelectric properties of a simple generic system, consisting of a single correlated layer sandwiched between two metallic leads. Results will be given for…

Strongly Correlated Electrons · Physics 2017-09-07 Irakli Titvinidze , Antonius Dorda , Wolfgang von der Linden , Enrico Arrigoni

The ratio of the symmetry energy coefficient to temperature, $a_sym/T$, in Fermi energy heavy ion collisions, has been experimentally extracted as a function of the fragment atomic number using isoscaling parameters and the variance of the…

Nuclear Experiment · Physics 2014-11-20 Z. Chen , S. Kowalski , M. Huang , R. Wada , T. Keutgen , K. Hagel , J. Wang , L. Qin , J. B. Natowitz , T. Materna , P. K. Sahu , A. Bonasera

The Seebeck coefficient in liquids often reaches the mV/K range, yet its microscopic origin remains unclear due to the complexity of electrolyte systems. Here we propose a minimal electrostatic theory focusing on solvation entropy. Using…

Statistical Mechanics · Physics 2026-03-06 Wataru Kobayashi

The Seebeck coefficient, $S=L_{12}/(TL_{11})$, which is proportional to a ratio of the thermoelectric conductivity $L_{12}$ to the electric conductivity $L_{11}$ with $T$ being temperature is examined for two-dimensional Dirac electrons in…

Mesoscale and Nanoscale Physics · Physics 2025-11-18 Yoshikazu Suzumura , Takao Tsumuraya , Masao Ogata

We derive formal expressions of time-dependent energy and heat currents through a nanoscopic device using the Keldysh nonequilibrium Green function technique. Numerical results are reported for a metal/dot/metal junction where the dot level…

Mesoscale and Nanoscale Physics · Physics 2012-05-16 Adeline Crépieux , Fedor Simkovic , Benjamin Cambon , Fabienne Michelini
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