Related papers: Carbon isotope fractionation in protoplanetary dis…
In the interstellar medium carbon exists in the form of two stable isotopes $^{12}$C and $^{13}$C and their ratio is a good indicator of nucleosynthesis in galaxies. However, chemical fractionation can potentially significantly alter this…
Carbon isotope fractionation of CO has been reported in the disk around TW Hya,where elemental carbon is more abundant than elemental oxygen ([C/O]$_{\rm elem}$> 1). We investigated the effects of the [C/O]$_{\rm elem}$ ratio on carbon…
CO is thought to be the main reservoir of volatile carbon in protoplanetary disks, and thus the primary initial source of carbon in the atmospheres of forming giant planets. However, recent observations of protoplanetary disks point towards…
C-fractionation has been studied from a theoretical point of view with different models of time-dependent chemistry, including both isotope-selective photodissociation and low-temperature isotopic exchange reactions. Recent chemical models…
We present the first detection of 13CCH in a protoplanetary disk (TW Hya). Using observations of C2H we measure CCH/13CCH = 65 +/- 20 in gas with a CO isotopic ratio of 12CO/13CO = 21 +/- 5 (Yoshida et al. 2022a). The TW Hya disk exhibits a…
Our current understanding of interstellar carbon fractionation hinges on the interpretation of astrochemical kinetic models. Yet, the various reactions included carry large uncertainties in their (estimated) rate coefficients, notably those…
We present the results of models of the chemistry, including deuterium, in the inner regions of protostellar disks. We find good agreement with recent gas phase observations of several (non--deuterated) species. We also compare our results…
The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the…
Planetary systems are thought to be born in protoplanetary disks. Isotope ratios are a powerful tool for investigating the material origin and evolution from molecular clouds to planetary systems via protoplanetary disks. However, it is…
The gas mass of protoplanetary disks, and the gas-to-dust ratio, are two key elements driving the evolution of these disks and the formation of planetary system. We explore here to what extent CO (or its isotopologues) can be used as a…
(abridged) We analyse the evolution of the fractional ionisation in a steady-state protoplanetary disc with a vertical temperature gradient and with gas-grain chemistry including surface reactions. The ionisation due to stellar X-rays,…
Recent measurements of carbon isotope ratios in both protoplanetary disks and exoplanet atmospheres have suggested a possible transfer of significant carbon isotope fractionation from disks to planets. For a clearer understanding of the…
Element isotopic ratios are powerful tools to reconstruct the journey of planetary material, from the parental molecular cloud to protoplanetary disks, where planets form and accrete their atmosphere. Radial variations in isotopic ratios in…
Nitrogen fractionation is commonly used to assess the thermal history of Solar System volatiles. With ALMA it is for the first time possible to directly measure 14N/15N ratios in common molecules during the assembly of planetary systems. We…
CO has long been thought to be the best tracer to measure gas masses as it is readily detected at (sub)mm wavelengths in many disks. Inferred gas masses from CO in recent ALMA observations of large samples of disks seem inconsistent with…
Recent high-resolution and sensitivity ALMA observations have unveiled the carbon isotope ratios ($^{12}$C/$^{13}$C) of Complex Organic Molecules (COMs) in a low-mass protostellar source. To understand the $^{12}$C/$^{13}$C ratios of COMs,…
The oxygen isotope fractionation scenario, which has been developed to explain the oxygen isotope anomaly in the solar system materials, predicts that CO gas is depleted in 18O in protoplanetary disks, where segregation between solids and…
The gas present in planet-forming disks typically exhibits strong emission features of abundant carbon and oxygen molecular carriers. In some instances, protoplanetary disks show an elevated C/O ratio above interstellar values, which leads…
Carbon containing molecules in cold molecular clouds show various levels of isotopic fractionation through multiple observations. To understand such effects, we have developed a new gas-grain chemical model with updated 13C fractionation…
The elemental carbon-to-oxygen ratio (C/O) in the atmosphere of a giant planet is a promising diagnostic of that planet's formation history in a protoplanetary disk. Alongside efforts in the exoplanet community to measure C/O in planetary…