Related papers: On the frequency of N2H+ and N2D+
Context: In the last years, the H2D+ and D2H+ molecules have gained great attention as probes of cold and depleted dense molecular cloud cores. These ions are at the basis of molecular deuterium fractionation, a common characteristic…
Very recently, molecular rotational transitions observed in the photon-dominated region of the Horsehead nebula have been attributed to l-C3H+. In an effort to corroborate this finding, we employed state-of-the art and proven high-accuracy…
We present observations of the $J$=1--0, 2--1, and 3--2 rotational transitions of N$_2$H$^+$ and N$_2$D$^+$ towards a sample of prototypical dark clouds. The data have been interpreted using non--local radiative transfer models.
We report rest frequencies for rotational transitions of the deuterated ammonium isotopologues NH3D+, NH2D2+ and NHD3+, measured in a cryogenic ion trap machine. For the symmetric tops NH3D+ and NHD3+ one and three transitions are detected,…
Context. The study of pre-stellar cores (PSCs) suffers from a lack of undepleted species to trace the gas physical properties in their very dense inner parts. Aims. We want to carry out detailed modelling of N2H+ and N2D+ cuts across the…
The high resolution spectrum of the v4 band of NH3D+ has been measured by difference frequency IR laser spectroscopy in a multipass hollow cathode discharge cell. From the set of molecular constants obtained from the analysis of the…
Prestellar cores are unique laboratories for studies of the chemical and physical conditions preceding star formation. We observed the prestellar core L1544 in the fundamental transition of ortho-H2D+ (1_1,0-1_1,1) at different positions…
We have observed the J=3-2 transition of N2H+ and N2D+ to investigate the trend of deuterium fractionation with evolutionary stage in three selected regions in the Infrared Dark Cloud (IRDC) G28.34+0.06 with the Submillimeter Telescope…
Deuterium enhancement of monodeuterated species has been recognized for more than 30 years as a result of the chemical fractionation that results from the difference in zero point energies of deuterated and hydrogenated molecules. The key…
Finding tracers of the innermost regions of prestellar cores is important for understanding their chemical and dynamical evolution before the onset of gravitational collapse. While classical molecular tracers, such as CO and CS, have been…
We present a study on the spatial distribution of N2D+ and N2H+ in thirteen protostellar systems. Eight of thirteen objects observed with the IRAM 30m telescope show relative offsets between the peak N2D+ (J=2-1) and N2H+ (J=1-0) emission.…
Context: The $^{15}$N fractionation has been observed to show large variations among astrophysical sources, depending both on the type of target and on the molecular tracer used. These variations cannot be reproduced by the current chemical…
Context. The high degree of deuteration observed in some prestellar cores depends on the ortho-to-para H2 ratio through the H3+ fractionation. Aims. We want to constrain the ortho/para H2 ratio across the L183 prestellar core. This is…
Aims. The purpose of this study is to examine the prediction that the deuterated H3+ ion, H2D+, can be found exclusively in the coldest regions of molecular cloud cores. This is also a feasibility study for the detection of the ground-state…
The H3+ ion plays a key role in the chemistry of dense interstellar gas clouds where stars and planets are forming. The low temperatures and high extinctions of such clouds make direct observations of H3+ impossible, but lead to large…
We measure the absolute frequency of seven out of the nine allowed transitions between the 2$^3${\it S} and 2$^3${\it P} hyperfine manifolds in a metastable $^3$He beam by using an optical frequency comb synthesizer-assisted spectrometer.…
Observations of low mass protostars which probe small enough size scales to be within likely CO depletion regions show the highest [NH2D]/[NH3] ratios yet measured, of 4--33%. These molecular D/H ratios are higher than those measured on…
Aims. This paper reports accurate laboratory frequencies of the rotational ground state transitions of two astronomically relevant molecular ions, NH3D+ and CF+. Methods. Spectra in the millimeter-wave band were recorded by the method of…
Context: The depletion of heavy elements in cold cores of interstellar molecular clouds can lead to a situation where deuterated forms of H_3^+ are the most useful spectroscopic probes of the physical conditions. Aims: The aim is to predict…
Transition frequencies and fine-structure splittings of the $2\,{}^3\!S_1 \rightarrow 2\,{}^3\!P_{\!J}$ transitions in helium-like $^{12}\mathrm{C}^{4+}$ were measured by collinear laser spectroscopy on a 1-ppb level. Accuracy is increased…