Related papers: [SiPAH]+ pi-Complexes in the Interstellar Medium
The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 micron are ubiquitously seen in a wide variety of astrophysical regions and commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules.…
The aromatic infrared bands (AIBs) observed in the mid infrared spectrum are attributed to Polycyclic Aromatic Hydrocarbons (PAHs). We observe the NGC 7023-North West (NW) PDR in the mid-infrared (10 - 19.5 micron) using the Infrared…
Using a novel suite of cosmological simulations zooming in on a Mpc-scale intergalactic sheet or "pancake" at z~3-5, we conduct an in-depth study of the thermal properties and HI content of the warm-hot intergalactic medium (WHIM) at those…
The interstellar medium (ISM) consists of a diversity of structures across a range of spatial scales, intimately tied to galactic evolution. In this work, Fourier analysis is used to characterize the spatial structures of dust and…
We report new correlations between ratios of band intensities of the 15-20 {\mu}m emission bands of polycyclic aromatic hydrocarbons (PAHs) in a sample of fifty-seven sources observed with Spitzer/IRS. This sample includes Large Magellanic…
This work proposes deuteronated PAH (DPAH+ ) molecules as a potential carrier of the 4.4 and 4.65 {\mu}m mid infrared emission bands that have been observationally detected towards the Orion and M17 regions. Density Functional Theory…
An absorption feature is occasionally reported around 11 microns in astronomical spectra, including those of forming stars. Candidate carriers include water ice, polycyclic aromatic hydrocarbons (PAHs), silicon carbide, crystalline…
Polycyclic Aromatic Hydrocarbons (PAHs) are organic molecules which comprise the smallest particles of dust in the interstellar medium (ISM). Due to their broad/complex emission profiles, obtaining kinematics is a challenge with traditional…
As the only moon in the solar system with a thick atmosphere, Titan is a compelling and enigmatic world containing a complex organic haze. Polycyclic aromatic hydrocarbon (PAH) molecules are believed to play an essential role in the…
Although H$_{2}$ is the simplest and the most abundant molecule in the Universe, its formation in the interstellar medium, especially in the photodissociation regions is far from being fully understood. According to suggestions, the…
A combined mid-IR spectrum of five colliding-wind, massive, dust-producing Population I Wolf-Rayet (WR) binaries shows a wealth of absorption and emission details coming from the circumstellar dust envelopes, as well as from the…
Long-slit 8-13 um spectroscopy of the nebula around NGC 1333 SVS reveals spatial variations in the strength and shape of emission features which are probably produced by polycyclic aromatic hydrocarbons (PAHs). Close to SVS 3, the 11.2 um…
While powerful techniques exist to accurately account for anharmonicity in vibrational molecular spectroscopy, they are computationally very expensive and cannot be routinely employed for large species and/or at non- zero vibrational…
I present a spatially resolved analysis of the polycyclic aromatic hydrocarbon (PAH) population in the Pillars of Creation within the Eagle Nebula (M16) using the James Webb Space Telescope's (JWST) Mid Infrared Instrument (MIRI) and Near…
We investigate the relationship between 8.44\,GHz brightness temperatures and 1.4 to 8.44\,GHz radio spectral indices with 6.2\,$\mu$m polycyclic aromatic hydrocarbon (PAH) emission and 9.7\,$\mu$m silicate absorption features for a sample…
The amount of deuterium locked up in polycyclic aromatic hydrocarbons (PAHs) has to date been an uncertain value. We present a near-infrared (NIR) spectroscopic survey of HII regions in the Milky Way, Large Magellanic Cloud (LMC), and Small…
Polycyclic Aromatic Hydrocarbons (PAHs) are commonly detected in protoplanetary disks, but it is unclear what causes the wide range of intensities across the samples. In this work, the measured PAH intensities of a range of disks are…
Polycyclic Aromatic Hydrocarbon (PAH) emission features dominate the mid-infrared spectra of star-forming galaxies and can be useful to calibrate star formation rates and diagnose ionized states of grains. However, the PAH 3.3 micron…
Rapid, efficient deactivation of the photoexcited PAH cations accounts for their remarkable photostability and have important implications for astrochemistry, as these cations are the leading candidates for the species responsible for the…
Polycyclic Aromatic Hydrocarbons (PAHs) constitute a significant fraction of the Universe's carbon budget, playing a key role in the cosmic carbon cycle and dominating the mid-infrared spectra of astrophysical environments in which they…