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We present a new method for the generation of rotationally and vibrationally state-selected, translationally cold molecular ions in ion traps. Our technique is based on the state-selective threshold photoionization of neutral molecules…

Chemical Physics · Physics 2010-06-30 Xin Tong , Alexander H. Winney , Stefan Willitsch

Cold molecular ions are promising candidates in various fields ranging from precision spectroscopy and test of fundamental physics to ultra-cold chemistry. Control of internal and external degrees of freedom is a prerequisite for many of…

Quantum Physics · Physics 2015-05-06 Yong Wan , Florian Gebert , Fabian Wolf , Piet O. Schmidt

Chemical reactions can be surprisingly efficient at ultracold temperatures ( < 1mK) due to the wave nature of atoms and molecules. The study of reactions in the ultracold regime is a new research frontier enabled by cooling and trapping…

Atomic Physics · Physics 2017-01-16 Lee R. Liu , Jessie T. Zhang , Yichao Yu , Nicholas R. Hutzler , Yu Liu , Till Rosenband , Kang-Kuen Ni

Experimental setups that study laser-cooled ions immersed in baths of ultracold atoms merge the two exciting and well-established fields of quantum gases and trapped ions. These experiments benefit both from the exquisite read-out and…

Atomic Physics · Physics 2022-06-30 Rianne S. Lous , Rene Gerritsma

We review the current status of the field of sympathetically cooled molecular ions, i.e. the method used for cooling the translational degrees of freedom, the techniques applied for detection and analysis of the cold trapped ion ensembles…

Quantum Physics · Physics 2008-12-08 Bernhard Roth , Stephan Schiller

Experiments with cold ion-atom mixtures have recently opened the way for the production and application of ultracold molecular ions. Here, in a comparative study, we theoretically investigate ground and several excited electronic states and…

Atomic Physics · Physics 2020-08-12 Wissem Zrafi , Hela Ladjimi , Halima Said , Hamid Berriche , Michał Tomza

Cooling a range of molecules to ultracold temperatures (<1 mK) is a difficult but important challenge in molecular physics and chemistry. Collective cavity cooling of molecules is a promising method that does not rely on molecular energy…

Atomic Physics · Physics 2012-05-11 Guangjiong Dong , Chang Wang , Weiping Zhang

An increasingly large variety of molecular species are being cooled down to low energies in recent years, and innovative ideas and powerful techniques continue to emerge to gain ever more precise control of molecular motion. In this brief…

Quantum Gases · Physics 2024-05-24 Tim Langen , Giacomo Valtolina , Dajun Wang , Jun Ye

We demonstrated sympathetic cooling of a single ion in a buffer gas of ultracold atoms with small mass. Efficient collisional cooling was realized by suppressing collision-induced heating. We attempt to explain the experimental results with…

Atomic Physics · Physics 2018-02-07 Shinsuke Haze , Mizuki Sasakawa , Ryoichi Saito , Ryosuke Nakai , Takashi Mukaiyama

Recent experiments with ultracold neutral plasmas show an intrinsic heating effect based on the development of spatial correlations. We investigate whether this effect can be reversed, so that imposing strong spatial correlations could in…

Atomic Physics · Physics 2009-11-10 T. Pohl , T. Pattard , J. M. Rost

We review recent progress in the field of cold trapped molecular ions. A new generation of collision and cold chemistry experiments between atoms and ions has emerged, where cold atoms and ions are brought into contact in a controlled way…

Atomic Physics · Physics 2024-08-28 Markus Deiß , Stefan Willitsch , Johannes Hecker Denschlag

A novel method of ground state laser cooling of trapped atoms utilizes the absorption profile of a three (or multi-) level system which is tailored by a quantum interference. With cooling rates comparable to conventional sideband cooling,…

Quantum Physics · Physics 2010-03-26 F. Schmidt-Kaler , J. Eschner , G. Morigi , C. F. Roos , D. Leibfried , A. Mundt , R. Blatt

Sympathetic cooling with ultracold atoms and atomic ions enables ultralow temperatures in systems where direct laser or evaporative cooling is not possible. It has so far been limited to the cooling of other microscopic particles, with…

Sympathetic cooling of molecular ions through the Coulomb interaction with laser-cooled atomic ions is an efficient tool to prepare translationally cold molecules without, ideally, affecting the internal state of the molecular ions.…

Quantum Physics · Physics 2026-04-20 J. Martin Berglund , Michael Drewsen , Christiane P. Koch

It is shown that the translational degrees of freedom of a large variety of molecules, from light diatomic to heavy organic ones, can be cooled sympathetically and brought to rest (crystallized) in a linear Paul trap. The method relies on…

Quantum Physics · Physics 2009-11-10 S. Schiller , C. Laemmerzahl

We suggest a protocol for the sympathetic cooling of a molecular asymmetric top rotor co-trapped with laser-cooled atomic ions, based on resonant coupling between the molecular ion's electric dipole moment and a common normal mode of the…

Quantum Physics · Physics 2026-02-04 Monika Leibscher , Alexander Blech , Christiane P. Koch

One limit to the fidelity of quantum logic operations on trapped ions arises from heating of the ions' collective modes of motion. Sympathetic cooling of the ions during the logic operations may eliminate this source of errors. We discuss…

The translational motion of molecular ions can be effectively cooled sympathetically to temperatures below 100 mK in ion traps through Coulomb interactions with laser-cooled atomic ions. The distribution of internal rovibrational states,…

Quantum Physics · Physics 2009-11-07 I. S. Vogelius , L. B. Madsen , M. Drewsen

Efficient cooling of trapped charged particles is essential to many fundamental physics experiments, to high-precision metrology, and to quantum technology. Until now, sympathetic cooling has required close-range Coulomb interactions, but…

Cooling atoms to ultralow temperatures has produced a wealth of opportunities in fundamental physics, precision metrology, and quantum science. The more recent application of sophisticated cooling techniques to molecules, which has been…

Atomic Physics · Physics 2017-09-21 John L Bohn , Ana Maria Rey , Jun Ye
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