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We present a self-consistent theory for the description of the spectroscopic properties of odd nuclei which includes exact blocking, particle-number and angular-momentum projection and configuration mixing. In our theory the pairing…

Nuclear Theory · Physics 2018-11-14 M. Borrajo , J. Luis Egido

Large-scale calculation based on the multi-configuration Skyrme density functional theory is performed for the light N=Z even-even nucleus, 12C. Stochastic procedures and the imaginary-time evolution are utilized to prepare many Slater…

Nuclear Theory · Physics 2012-12-04 Y. Fukuoka , T. Nakatsukasa , Y. Funaki , K. Yabana

The energy balance of a partially molten rocky planet can be expressed as a non-linear diffusion equation using mixing length theory to quantify heat transport by both convection and mixing of the melt and solid phases. In this formulation…

Earth and Planetary Astrophysics · Physics 2017-11-22 Dan J. Bower , Patrick Sanan , Aaron S. Wolf

Coupled cluster theory with a Kohn-Sham reference (KS-CC) can dramatically outperform its Hartree-Fock counterpart for strongly correlated systems, but the origin of these improvements has remained unclear. Here we demonstrate that these…

In many of the approximate functionals in one-body reduced density matrix (1RDM) functional theory, the approximate two-body reduced density matrix (2RDM) in the natural orbital representation only depends on the natural occupation numbers.…

Chemical Physics · Physics 2020-11-24 Klaas J. H. Giesbertz

Within the framework of Skyrme energy density formalism, we investigate the role of surface corrections on the fusion of colliding nuclei. For this, the coefficient of surface correction was varied between 1/36 and 4/36, and its impact was…

Nuclear Theory · Physics 2011-07-08 Ishwar Dutt , Narinder K. Dhiman

It seems self-evident that a density functional calculation should be normalized to the number of electrons in the system. We present multiple examples where the accuracy of the approximate energy is improved (sometimes greatly) by…

Chemical Physics · Physics 2026-03-13 Adam Clay , Kiril Datchev , Wenlan Miao , Adam Wasserman , Kimberly J. Daas , Kieron Burke

The ground-state properties of superfluid nuclear systems with ^1S_0 pairing are studied within a local energy-density functional (LEDF) approach. A new form of the LEDF is proposed with a volume part which fits the Friedman- Pandharipande…

Nuclear Theory · Physics 2011-04-15 S. A. Fayans , D. Zawischa

For the theoretical understanding of the reactivity of complex chemical systems accurate relative energies between intermediates and transition states are required. Despite its popularity, density functional theory (DFT) often fails to…

Chemical Physics · Physics 2016-06-23 Gregor N. Simm , Markus Reiher

We show that single-particle energies in doubly magic nuclei depend almost linearly on the coupling constants of the nuclear energy density functional. Therefore, they can be very well characterized by the linear regression coefficients,…

Nuclear Theory · Physics 2008-11-26 M. Kortelainen , J. Dobaczewski , K. Mizuyama , J. Toivanen

Building on the discussion in PRA 93, 042510 (2016), we present a systematic derivation of gradient corrections to the kinetic-energy functional and the one-particle density, in particular for two-dimensional systems. We derive the leading…

Quantum Gases · Physics 2017-09-08 Martin-Isbjörn Trappe , Yink Loong Len , Hui Khoon Ng , Berthold-Georg Englert

The most recent parametrizations D1S, D1N and D1M of the Gogny energy density functional are used to describe fission in the isotopes $^{232-280}$ U. Fission paths, collective masses and zero point quantum corrections, obtained within the…

Nuclear Theory · Physics 2014-05-27 R. Rodriguez-Guzman , L. M. Robledo

Density Functional Theory (DFT) is a robust framework for modeling interacting many-body systems, including the equation of state (EoS) of dense matter. Many models, however, rely on energy functionals based on assumptions that have not…

Nuclear Theory · Physics 2025-06-06 Udita Shukla , Pok Man Lo

Based on a functional-integral formalism, a generalization of the self-energy-functional theory (SFT) is proposed which is applicable to systems of interacting electrons with disorder. Similar to the pure case without disorder, a…

Strongly Correlated Electrons · Physics 2013-05-29 Michael Potthoff , Matthias Balzer

The aim of this paper is to study the asymptotic properties of a class of kernel conditional mode estimates whenever functional stationary ergodic data are considered. To be more precise on the matter, in the ergodic data setting, we…

Methodology · Statistics 2014-07-09 Mohamed Chaouch , Naamane Laib , Djamal Louani

Density functional theory (DFT) has transformed our ability to investigate and understand electronic ground states. In its original formulation, however, DFT is not suited to addressing (e.g.) degenerate ground states, mixed states with…

Chemical Physics · Physics 2025-10-30 Tim Gould , Leeor Kronik , Stefano Pittalis

Due to their small size and unique properties, single-molecule electronics have long seen research interest from experimentalists and theoreticians alike. From a theoretical standpoint, modeling these systems using electronic structure…

Chemical Physics · Physics 2021-10-04 Andrew M. Sand , Justin T. Malme , Erik P. Hoy

An alternative to Density Functional Theory are wavefunction based electronic structure calculations for solids. In order to perform them the Exponential Wall (EW) problem has to be resolved. It is caused by an exponential increase of the…

Chemical Physics · Physics 2017-06-07 Peter Fulde , Hermann Stoll

Equilibrium polyethylene crystal structure, cohesive energy, and elastic constants are calculated by density-functional theory applied with a recently proposed density functional (vdW-DF) for general geometries [Phys. Rev. Lett. 92, 246401…

Materials Science · Physics 2009-11-11 Jesper Kleis , Bengt I. Lundqvist , David C. Langreth , Elsebeth Schroder

We present an accurate local density-functional for electronic-structure calculations within the density functional theory (DFT). The functional is derived by analyzing the structure of the standard perturbative expansion of the correlation…

Materials Science · Physics 2024-11-28 Mario Benites , Angel Rosado , Efstratios Manousakis