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Doping at the rare-earth site by divalent alkaline-earth ions in perovskite lattice has witnessed a variety of magnetic and electronic orders with spatially correlated charge, spin and orbital degrees of freedom. Here, we report an antisite…

Strongly Correlated Electrons · Physics 2016-02-17 J. Krishna Murthy , K. D. Chandrasekhar , H. C. Wu , H. D. Yang , J. Y. Lin , A. Venimadhav

The La2CoMnO6 (LCMO) perovskite has received a lot of attention due to its near room temperature magnetodielectric effect. Despite the recent efforts, the mechanism ruling the correlation between its magnetic and dielectric properties is…

In this paper, we reported the effect of Cu doping on the structural and dielectric properties of Ba$_2$Y$_{1-x}$Cu$_x$TaO$_{6-y}$ (0.00 $\leq$ x $\leq$ 0.50) ceramics at room temperature. The Copper for Yttrium substitution reduces the…

Materials Science · Physics 2019-10-25 F. S. Oliveira , C. A. M. dos Santos , A. J. S. Machado , P. Banerjee , A. Franco

We report the effect of La-substitution on the magnetic and magnetotransport properties of Brownmillerite-like bilayered compounds Ca2.5-xLaxSr0.5GaMn2O8 (x = 0, 0.05, 0.075, and 0.1) by using dc-magnetization, resistivity and…

Materials Science · Physics 2010-03-16 A. K. Bera , S. M. Yusuf

Effect of Co, Ru and Cu substitution at B and B' sites on the magnetic and transport properties of LaSrCoRuO$_6$ have been investigated. All the doped compositions crystallize in the monoclinic structure in the space group $P2_1/n$…

Strongly Correlated Electrons · Physics 2010-11-12 P. S. Ramu Murthy , K. R. Priolkar , P. A. Bhobe , A. Das , P. R. Sarode , A. K. Nigam

Studies of the doping process can provide a better understanding of the superconducting mechanisms in cuprous oxide materials. In this work, we studied the doping effects on the crystal structure, electric, morphologic and magnetic…

Aliovalent doping of the two-dimensional dimer antiferromagnet SrCu$_2$(BO$_3$)$_2$ has long been proposed as a potential route toward realizing resonating valence bond (RVB) superconductivity in this system; however, experimental progress…

Double perovskite-based magnets wherein frustration and competition between emergent degrees of freedom are at play can lead to novel electronic and magnetic phenomena. Herein, we report the electronic structure and magnetic properties of…

Combining experimental investigations and first-principles DFT calculations, we report physical and magnetic properties of Gd-substituted Y$_2$CoMnO$_6$ double perovskite, which are strongly influenced by antisite-disorder-driven spin…

Materials Science · Physics 2023-02-28 Anasua Khan , Sarita Rajput , M. Anas , V. K. Malik , T. Maitra , T. K Nath , A. Taraphder

he structural, transport, magnetic and optical properties of the double perovskite $A_2$CrWO$_6$ with $A=\text{Sr, Ba, Ca}$ have been studied. By varying the alkaline earth ion on the $A$ site, the influence of steric effects on the Curie…

Strongly Correlated Electrons · Physics 2009-11-10 J. B. Philipp , P. Majewski , L. Alff , A. Erb , R. Gross , T. Graf , M. S. Brandt , J. Simon , T. Walther , W. Mader , D. Topwal , D. D. Sarma

CaRuO3 is a perovskite with an orthorhombic distortion and shows the characteristics of spin-glass behavior below TC=87 K. The La3+ substitution for Ca2+ in Ca1-xLaxRuO3 samples, induces a disorder in the Ca site (the A site) and the system…

Superconductivity · Physics 2009-11-07 I. Felner , U. Asaf

Using first principles density functional calculations, together with exact diagonalization of Fe-Mo Hamiltonian constructed in a first principles Wannier function basis, we studied the electronic structure of La doped double perovskite…

Materials Science · Physics 2015-05-14 Prabuddha Sanyal , Hena Das , T. Saha-Dasgupta

Here we present a detailed investigation of the Co and Ir local electronic structures in La1.5A0.5CoIrO6 (A = Ba, Ca) compounds in order to unravel the orbital hybridization mechanism in these CoIr-based double perovskites. Our results of…

Bi1-xLaxFe1-xMnxO3 (x = 0.000 - 0.300) ceramics prepared by the tartaric acid modified sol-gel technique have been studied to analyze the effect of composition driven structural transition on the magnetic properties of bismuth ferrite…

Materials Science · Physics 2014-11-25 Pawan Kumar , Manoranjan Kar

The Ca$_2$MnReO$_6$ double perovskite is a spin-orbit-assisted Mott insulator with exotic magnetic properties, including a largely non-collinear Mn$^{2+}$ spin arrangement and nearly orthogonal coupling between such spins and the much…

Strongly Correlated Electrons · Physics 2022-04-27 A. S. Cavichini , M. T. Orlando , M. C. A. Fantini , R. Tartaglia , C. W. Galdino , F. Damay , F. Porcher , E. Granado

In this manuscript, we report room temperature structural, microstructural, optical, dielectric, and magnetic properties of CuO and Cu0.995La0.005 ceramics, synthesized by solid-state reaction method. La doping in CuO leads to the evolution…

Materials Science · Physics 2022-01-03 Kumar Brajesh , Sudhir Ranjan , Rajeev Gupta , Ambesh Dixit , Ashish Garg

We have prepared crystallographically ordered and disorder specimens of the double perovskite, Sr$_2$FeMoO$_6$ and investigated their magnetoresistance behaviour. The extent of ordering between the Fe and Mo sites in the two samples is…

Strongly Correlated Electrons · Physics 2009-10-31 D. D. Sarma , E. V. Sampathkumaran , Sugata Ray , R. Nagarajan , Subham Majumdar , Ashwani Kumar , G. Nalini , T. N. GuruRow

The magnetism of the double perovskite compounds \SLFCOx\ ($x$ = 0, 1, 2) are contrasted using magnetization, neutron diffraction and electron paramagnetic resonance with the support from density functional theory calculations. \LFCO\ is…

The electron spin polarization on half-metallic double-perovskites is usually conditioned to the ordered rock-salt arrangement of the transition-metal ions along the lattice. In this work, we investigate a polycrystalline sample of the…

Electron- and hole-doped La$_2$CoMnO$_6$(LCMO) are investigated using first principles DFT calculations. Hole and electron doping are achieved respectively by introducing Sr$^{2+}$ at La$^{3+}$ sites and by inducing O-site vacancies in…

Materials Science · Physics 2021-09-02 Anasua Khan , Swastika Chatterjee , T. K. Nath , A. Taraphder