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Surface sensitive x-ray scattering techniques with atomic scale resolution are employed to investigate the microscopic structure of the surface of three classes of liquid binary alloys: (i) Surface segregation in partly miscible binary…

Disordered Systems and Neural Networks · Physics 2007-05-23 Holger Tostmann , Elaine DiMasi , Oleg G. Shpyrko , Ben M. Ocko , Peter S. Pershan , Moshe Deutsch

We have studied the dependence of metal oxide properties in molecular dynamics (MD) simulations on the polarizability of oxygen ions. We present studies of both liquid and crystalline structures of silica (SiO2), magnesia (MgO) and alumina…

Materials Science · Physics 2012-11-13 Philipp Beck , Peter Brommer , Johannes Roth , Hans-Rainer Trebin

Quaternary phases formed in copper alloys are investigated through a combination of quantum-mechanical and classical computer simulations and active machine learning. Focus is given on nickel, silicon, and chromium impurities in a copper…

Materials Science · Physics 2024-10-24 Ángel Díaz Carral , Simon Gravelle , Maria Fyta

Crystalline Co$_{x}$Cu$_{1-x}$ alloys show interesting magnetic behavior over the entire concentration regime. We here present a fully self- consistent first principles electronic structure studies of the electronic structure and magnetic…

Materials Science · Physics 2009-10-31 Subhradip Ghosh , Abhijit Mookerjee

We present the first ab initio molecular dynamics study of collisions between metal-oxide clusters and surfaces. The resulting trajectories reveal that the internal degrees of freedom of the cluster play a defining role in collision…

Materials Science · Physics 2008-04-10 Daniel A. Freedman , T. A. Arias

High-temperature solid-state reaction between orthorhombic AgF2 and monoclinic CuF2 (y = 0.15, 0.3, 0.4, 0.5) in a fluorine atmosphere resulted in coexisting solid solutions of Cu-poor orthorhombic and Cu-rich monoclinic phases with…

Materials Science · Physics 2025-03-14 D. Jezierski , K. Koteras , M. Domanski , P. Połczynski , Z. Mazej , J. Lorenzana , W. Grochala

The paper presents the results of investigation of the structure of porous condensates of Ag-NaCl and Cu-NaCl composition; chemical and phase compositions and dimensions of nanoparticles, produced from the vapour phase by EBPVD method.…

Materials Science · Physics 2019-01-04 Yu. A. Kurapov , S. E. Litvin , S. M. Romanenko , G. G. Didikin , N. N. Belyavina

A nearly-free-electron (NFE) model to describe STM spectroscopy of (111) metal surfaces with Kondo impurities is presented. Surface states are found to play an important role giving a larger contribution to the conductance in the case of…

Strongly Correlated Electrons · Physics 2009-11-10 J. Merino , O. Gunnarsson

Surface oxidation of high-purity copper is accelerated under tribological loading. Tribo-oxide formation at room temperature is associated with diffusion processes along defects, such as dislocations or grain boundaries. Here, we embark on…

Applied Physics · Physics 2021-10-15 Julia S. Raua , Oliver Schmidt , Reinhard Schneider , Christian Greiner

Lithium-ion batteries (LIBs) have become essential in modern energy storage; however, their performance is often limited by the stability and efficiency of their components, particularly the cathode and electrolyte. Transition metal layered…

Materials Science · Physics 2025-07-15 M. D. Hashan C. Peiris , Michael Woodcox , Diana Liepinya , Robert Shepard , Hao Liu , Manuel Smeu

We studied dynamics of Au (001) surface in situ in 0.1 M HClO4 electrolyte solution using both coherent x-ray scattering and scanning tunneling microscopy (STM). The surface of Au (001) is known to reconstruct at cathodic potentials; the…

Materials Science · Physics 2011-10-18 M. S. Pierce , V. Komanicky , A. Barbour , D. C. Hennessy , J. -D. Su , A. Sandy , C. Zhu , H. You

The forces of electrical imaging strongly polarize the surface of colloidal silica. I used X-ray scattering to study the adsorbed 2-nm-thick compact layer of alkali ions at the surface of concentrated solutions of 5-nm, 7-nm, and 22-nm…

Soft Condensed Matter · Physics 2007-05-23 Aleksey M. Tikhonov

Epitaxial silicene, which is one single layer of silicon atoms packed in a honeycomb structure, demonstrates a strong interaction with the substrate that dramatically affects its electronic structure. The role of electronic coupling in the…

Mesoscale and Nanoscale Physics · Physics 2014-12-08 Xun Xu , Jincheng Zhuang , Yi Du , Haifeng Feng , Nian Zhang , Chen Liu , Tao Lei , Jiaou Wang , Michelle Spencer , Tetsuya Morishita , Xiaolin Wang , Shi Xue Dou

Diffusion of Cu adatoms and dimers on Cu(111) and Ag(111) surfaces is analyzed basing on ab-initio surface potentials. As compared to the simple single adatom jumps that alternate between two states, dimers undergo more complex diffusion…

Statistical Mechanics · Physics 2015-09-30 Marcin Mińkowski , Magdalena A. Załuska--Kotur

Copper and hydrogen are among the most common elements that are widely used in industrial and fundamental research applications. Copper surfaces are often exposed to hydrogen in the form of charged ions. The hydrogen ions can accelerate…

Transition metal carbides have sparked unprecedented enthusiasm as high-performance catalysts in recent years. Still, the catalytic properties of copper (Cu) carbide remain unexplored. By introducing subsurface carbon (C) to Cu(111),…

Grain boundary (GB) segregation of solute atoms plays an important role in the microstructure and macroscopic mechanical properties of materials. The study of GB segregation of solute atoms using computational simulation has become one of…

Materials Science · Physics 2023-05-29 Zhihui Zhang , Liang Zhang , Xuan Zhang , Xiaoxu Huang

Using spin-density functional theory we investigated various possible structures of the hematite (0001) surface. Depending on the ambient oxygen partial pressure, two geometries are found to be particularly stable under thermal equilibrium:…

Materials Science · Physics 2009-10-31 X. -G. Wang , W. Weiss , Sh. K. Shaikhutdinov , M. Ritter , M. Petersen , F. Wagner , R. Schloegl , M. Scheffler

First principles electronic structure calculations based on density functional theory have been used to study the thermodynamic, structural and transport properties of solid solutions and liquid alloys of iron and oxygen at Earth's core…

Geophysics · Physics 2009-10-31 Dario Alfe` , G. David Price , Michael J. Gillan

Copper (Cu) segregation in medium and high-entropy alloys (M/HEAs) has shown significant influence on alloy properties. In this study, we investigate the effect of Cu segregation on evolution of irradiation-induced defects in FeNiCu, a…