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Ca2Co2O5 in the brownmillerite form was synthesized using a high-pressure optical-image floating zone furnace, and single crystals with dimensions up to 1.4x0.8x0.5 mm3 were obtained. At room temperature, Ca2Co2O5 crystallizes as a fully…

The complex metal oxide Mn3TeO6 exhibits a corundum related structure and has been prepared both in forms of single crystals by chemical transport reactions and of polycrystalline powders by a solid state reaction route. The crystal…

Materials Science · Physics 2011-09-15 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter , N. Golubko , E. D. Politova , M. Weil

The behavior of identical particles interacting through the harmonic-repulsive pair potential has been studied in 3D using molecular dynamics simulations at a number of different densities. We found that at many densities, as the…

Soft Condensed Matter · Physics 2017-10-11 V. A. Levashov

We have investigated the crystal structure of LaOBiPbS3 using neutron diffraction and synchrotron X-ray diffraction. From structural refinements, we found that the two metal sites, occupied by Bi and Pb, were differently surrounded by the…

Materials Science · Physics 2017-10-03 Y. Mizuguchi , Y. Hijikata , T. Abe , C. Moriyoshi , Y. Kuroiwa , Y. Goto , A. Miura , S. Lee , S. Torii , T. Kamiyama , C. H. Lee , M. Ochi , K. Kuroki

Anomalous low temperature electronic and structural behaviour has been discovered in PbRuO3. The structure (space group Pnma, a = 5.56314(1), b = 7.86468(1), c = 5.61430(1) A) and metallic conductivity at 290 K are similar to those of…

Strongly Correlated Electrons · Physics 2009-11-13 S. A. J. Kimber , J. A. Rodgers , H. Wu , C. A. Murray , D. N. Argyriou , A. N. Fitch , D. I. Khomskii , J. P. Attfield

The structural phase diagram of the La1-xSrxMnO3 system in the compositional range 0.08 <= x <= 0.125 has been investigated by high-resolution synchrotron x-ray powder diffraction techniques between 20-600 K. Recent studies have reported…

Strongly Correlated Electrons · Physics 2009-10-31 D. E. Cox , T. Iglesias , E. Moshopoulou , K. Hirota , K. Takahashi , Y. Endoh

Using first-principles calculations, we study theoretically the stable 2H hexagonal structure of BaMnO3. We show that from the stable high temperature P63/mmc structure, the compound should exhibit an improper ferroelectric structural phase…

Materials Science · Physics 2015-06-15 Julien Varignon , Philippe Ghosez

A ferroelectric monoclinic phase of space group $Cm$ ($M_A$ type) has been discovered in 0.65Pb(Mg$_{1/3}$Nb$_{2/3})O_3$-0.35PbTiO$_3$ by means of high resolution synchrotron X-ray diffraction. It appears at room temperature in a single…

Materials Science · Physics 2009-11-07 Z. -G. Ye , B. Noheda , M. Dong , D. Cox , G. Shirane

Starting from Cs2CuCl4 and Cs2CuBr4 our project focuses on the growth of the Cs2CuCl4-xBrx mixed crystals from aqueous solution and the investigation of the occurring structural variations. The well known orthorhombic structure (space group…

Strongly Correlated Electrons · Physics 2011-03-02 N. Krüger , S. Belz , F. Schossau , A. A. Haghighirad , P. T. Cong , B. Wolf , S. Gottlieb-Schoenmeyer , F. Ritter , W. Assmus

Based on the relativistic spin-polarized density functional theory calculations we investigate the crystal structure, electronic and magnetic properties of a family MnPn2Ch4 compounds, where pnictogen metal atoms (Pn) are Sb and Bi;…

Materials Science · Physics 2018-09-28 S. V. Eremeev , M. M. Otrokov , E. V. Chulkov

We demonstrated the lattice structures and the superconducting phases of metallic double-chain based cuprate Pr2Ba4Cu7O15-delta exhibiting higher Tc. After the oxygen heat treatment on citrate pyrolysis precursors, their reduction treatment…

Although the structural phase transitions in single-crystal hybrid methyl-ammonium (MA) lead halide perovskites (MAPbX3, X = Cl, Br, I) are common phenomena, they have never been observed in the corresponding nanocrystals. Here we…

Applied Physics · Physics 2020-04-08 Yuri D. Glinka , Rui Cai , Xian Gao , Dan Wu , Rui Chen , Xiao Wei Sun

In this study we report the results of study of novel ternary $Np_2PtGa_3$ compound. The x-ray-powder diffraction analysis reveals that the compound crystallizes in the orthorhombic CeCu$_2$-type crystal structure (space group Imma) with…

Strongly Correlated Electrons · Physics 2014-12-08 V. H. Tran , J. -C. Griveau , R. Eloirdi , E. Colineau

The high pressure structural properties of bismuth oxide Bi2SiO5 have been investigated up to 28 GPa using in situ powder synchrotron X-ray diffraction and up to 50 GPa with DFT calculations. The monoclinic structure is found to persist up…

YCrO3 which has a monoclinic structure, shows weak ferromagnetism below 140 K (TN) and a ferroelectric transition at 473 K accompanied by hysteresis. We have determined the structure and energetics of YCrO3 with ferromagnetic and…

Materials Science · Physics 2007-05-23 Claudy Rayan Serrao , Asish K. Kundu , S. B. Krupanidhi , Umesh V. Waghmare , C. N. R. Rao

Unit cell parameters obtained from X-ray powder diffraction data are presented for the crystalline phase of a liquid crystal 4-butyloxyphenyl 4'-decyloxybenzoate: a = 23.098 (4) {\AA}, b = 5.974 (6) {\AA}, c = 12.357 (10) {\AA}, \b{eta} =…

Materials Science · Physics 2014-12-01 M. Cvetinov , M. Stojanović , D. Obadović , S. Rakić , A. Vajda , K. Fodor-Csorba , N. Éber

Structural evolution of a prospective hydrogen storage material, ammonia borane NH3BH3, has been studied at high pressures up to 12 GPa and at low temperatures by synchrotron powder diffraction. At 293 K and above 1.1 GPa a disordered I4mm…

Materials Science · Physics 2009-06-26 Yaroslav Filinchuk , Andriy H. Nevidomskyy , Dmitry Chernyshov , Vladimir Dmitriev

Ba3Yb2Zn5O11 is unique among breathing pyrochlore compounds for being in the nearly decoupled limit where inter-tetrahedron interactions are weak, hosting isolated clusters or "molecular magnet" like tetrahedra of magnetic ytterbium (Yb3+)…

We investigate the structural and magnetic phase transitions in EuTi1-xNbxO3 with synchrotron powder X-ray diffraction (XRD), resonant ultrasound spectroscopy (RUS), and magnetization measurements. Upon Nb-doping, the Pm-3m to I4/mcm…

We report the magnetic structure and properties of a thiocyanate-based honeycomb magnet [Na(OH$_2$)$_3$]Mn(NCS)$_3$ which crystallises in the unusual low-symmetry trigonal space group $P\overline{3}$. Magnetic measurements on powder samples…