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For Kohn variational calculations on low energy positron hydrogen molecule elastic scattering, we prove that the phase shift approximation obtained using the complex Kohn method is precisely equal to a value which can be obtained…

Quantum Physics · Physics 2015-05-14 J. N. Cooper , M. Plummer , E. A. G. Armour

Using the complex Kohn method, we have calculated variational values of phase shifts and the annihilation parameter, Z_{eff}, for the elastic scattering of positrons by molecular hydrogen. Our results are sensitive to small changes in the…

Quantum Physics · Physics 2008-12-02 J. N. Cooper , E. A. G. Armour , M. Plummer

The three-nucleon ground state and the N--d scattering states are obtained using variational principles. The wave function of the system is decomposed into angular-spin-isospin channels and the corresponding two dimensional spatial…

Nuclear Theory · Physics 2009-10-30 Alejandro Kievsky

The Complex Kohn variational method for electron-polyatomic molecule scattering is formulated using an overset grid representation of the scattering wave function. The overset grid consists of a central grid and multiple dense,…

Chemical Physics · Physics 2017-12-06 Loren Greenman , Robert R. Lucchese , C. William McCurdy

Positronium-hydrogen (Ps-H) scattering is of interest, as it is a fundamental four-body Coulomb problem. We have investigated low-energy Ps-H scattering below the Ps(n=2) excitation threshold using the Kohn variational method and variants…

Atomic Physics · Physics 2015-08-25 Denton Woods

The Kohn variational principle is formulated for calculating elastic proton-deuteron scattering amplitudes at energies above the deuteron breakup threshold. The use of such a principle with an expansion of the wave function on the…

Nuclear Theory · Physics 2009-11-07 M. Viviani , A. Kievsky , S. Rosati

We construct an efficient emulator for two-body scattering observables using the general (complex) Kohn variational principle and trial wave functions derived from eigenvector continuation. The emulator simultaneously evaluates an array of…

Nuclear Theory · Physics 2021-11-23 C. Drischler , M. Quinonez , P. G. Giuliani , A. E. Lovell , F. M. Nunes

The general formulas to calculate the phase shifts of wave function of a particle scattering on a target formed by a pair of non-identical zero-range potentials are derived. It is shown that at asymptotically great distances from the target…

Quantum Physics · Physics 2022-06-20 A. S. Baltenkov , I. Woiciechowski

The article discusses the correctness of the assumption about the similarity of molecular continuum electron functions with wave functions in electron-atom scattering. The elastic scattering of slow particles by pair of non-overlapping…

Atomic Physics · Physics 2022-08-01 A. S. Baltenkov , I. Woiciechowski

Background: The phase-shift analysis for proton-proton scattering has been studied by various research groups using the realistic potentials to be comprised of various internal interactions based on an exchange of pions and mesons,…

Nuclear Theory · Physics 2024-04-10 Lalit Kumar , Arushi Sharma , Anil Khachi , Ayushi Awasthi , O. S. K. S. Sastri

The article discusses how the pattern of elastic scattering of an electron on a pair of identical atomic spheres will look if we abandon the standard in the molecular physics assumption that, outside the molecular sphere, in the external…

Atomic Physics · Physics 2022-09-20 A. S. Baltenkov , I. Woiciechowski

We propose a new method to obtain kinetic properties of infrequent events from molecular dynamics simulation. The procedure employs a recently introduced variational approach [Valsson and Parrinello, Phys. Rev. Lett. 113, 090601 (2014)] to…

Statistical Mechanics · Physics 2015-08-19 James McCarty , Omar Valsson , Pratyush Tiwary , Michele Parrinello

We study three wave function optimization methods based on energy minimization in a variational Monte Carlo framework: the Newton, linear and perturbative methods. In the Newton method, the parameter variations are calculated from the…

Chemical Physics · Physics 2015-06-26 Julien Toulouse , C. J. Umrigar

The Kohn variational principle and the hyperspherical harmonics technique are applied to study n-3H elastic scattering at low energies. In this contribution the first results obtained using a non-local realistic interaction derived from the…

Nuclear Theory · Physics 2009-11-13 M. Viviani , A. Kievsky , L. Girlanda , L. E. Marcucci

Nonperturbative polaron variational methods are applied, within the so-called particle or worldline representation of relativistic field theory, to study scattering in the context of the scalar Wick - Cutkosky model. Important features of…

Nuclear Theory · Physics 2009-10-30 C. Alexandrou , R. Rosenfelder , A. W. Schreiber

The paper is devoted to a comprehensive study of composite models in variational analysis and optimization the importance of which for numerous theoretical, algorithmic, and applied issues of operations research is difficult to overstate.…

Optimization and Control · Mathematics 2019-12-10 Ashkan Mohammadi , Boris S. Mordukhovich , M. Ebrahim Sarabi

The prevalence of variational methods in near-term quantum computing makes optimizer choice critical, yet selection is frequently intuition-based. We therefore present a systematic benchmark of eight classical optimization algorithms for…

Quantum Physics · Physics 2026-01-23 S. Illésová , V. Novák , T. Bezděk , C. Possel , M. Beseda

We propose a variational alternative to the Trotter-Suzuki decomposition that provides greater control over errors while preserving the unitary structure of time evolution. The variational parameters in our ansatz are derived from a global…

Quantum Physics · Physics 2025-11-20 Ibsal Assi , Michael Vogl , Meenu Kumari , J. P. F. LeBlanc

Inspired by anomalies which the standard scattering matrix pole-extraction procedures have produced in a mathematically well defined coupled-channel model, we have developed a new method based solely on the assumption of partial-wave…

High Energy Physics - Phenomenology · Physics 2014-11-18 Sasa Ceci , Jugoslav Stahov , Alfred Svarc , Shon Watson , Branimir Zauner

We construct an emulator for a multi-channel scattering problem based on the eigenvector continuation. To this end, we employ the Kohn variational principle formulated in the discrete basis formalism. We apply this to one-dimensional…

Nuclear Theory · Physics 2025-05-30 K. Hagino , Zehong Liao , S. Yoshida , M. Kimura , K. Uzawa
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