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We calculate the thermomechanical properties of $\alpha$-iron, and in particular its isothermal and adiabatic elastic constants, using first-principles total-energy and lattice-dynamics calculations, minimizing the quasi-harmonic…

Materials Science · Physics 2015-06-23 Daniele Dragoni , Davide Ceresoli , Nicola Marzari

In this study, an efficient first-principles approach for calculating the thermodynamic properties of mixed metal oxides at high temperatures is demonstrated. More precisely, this procedure combines density functional theory and harmonic…

Materials Science · Physics 2023-05-12 Joakim Brorsson , Ivana Staničić , Jonatan Gastaldi , Tobias Mattison , Anders Hellman

This paper gives a short overview of the calculation of thermal properties of materials from first principles, using the Quasi-Harmonic Approximation (QHA). We first introduce some of the thermal properties of interest and describe how they…

Materials Science · Physics 2011-12-22 Stefano Baroni , Paolo Giannozzi , Eyvaz Isaev

A tight-binding model is fit to first-principles calculations for copper that include structures distorted according to elastic constants and high-symmetry phonon modes. With the resulting model the first-principles-based phonon dispersion…

Materials Science · Physics 2009-11-07 Sven P. Rudin , M. D. Jones , C. W. Greeff , R. C. Albers

We present the ab-initio thermoelastic properties of body-centered cubic molybdenum under extreme conditions obtained within the quasi-harmonic approximation including both the vibrational and the electronic thermal excitations…

Materials Science · Physics 2024-06-25 Xuejun Gong , Andrea Dal Corso

Elastic constants are central material properties, frequently reported in experimental and theoretical studies. While their computation is straightforward in the absence of thermal fluctuations, finite--temperature methods often suffer from…

Materials Science · Physics 2026-04-28 Debashish Mukherji , Marcus Müller , Martin H. Müser

The thermal properties of silver are calculated within the quasi-harmonic approximation, by using phonon dispersions from density-functional perturbation theory, and the pseudopotential plane-wave method. The resulting free energy provides…

Materials Science · Physics 2009-10-31 Jianjun Xie , Stefano de Gironcoli , Stefano Baroni , Matthias Scheffler

Thermoelectric materials can achieve direct energy conversion between electricity and heat, thus can be applied to waste heat harvesting and solid-state cooling. The discovery of new thermoelectric materials is mainly based on experiments…

Materials Science · Physics 2024-05-07 Tao Fan , Artem R. Oganov

We develop a general and unified first-principles theory of piezoelectric and flexoelectric tensor, formulated in such a way that the tensor elements can be computed directly in the context of density-functional calculations, including…

Materials Science · Physics 2013-11-21 Jiawang Hong , David Vanderbilt

A method is presented to calculate from first principles the higher-order elastic constants of a solid material. The method relies on finite strain deformations, a density functional theory approach to calculate the Cauchy stress tensor,…

Materials Science · Physics 2025-10-08 Ruvini Attanayake , Umesh C. Roy , Abhiyan Pandit , Angelo Bongiorno

We present a scheme to construct model potentials, with parameters computed from first principles, for large-scale lattice-dynamical simulations of materials. Our method mimics the traditional solid-state approach to the investigation of…

Materials Science · Physics 2013-12-04 Jacek C. Wojdeł , Patrick Hermet , Mathias P. Ljungberg , Philippe Ghosez , Jorge Íñiguez

We present a simple methodology to compute the spontaneous volume magnetostriction with first-principles calculations on the basis of the magnetoelastic energy. This method makes use of deformations of the unit cell only at the…

Materials Science · Physics 2023-01-23 P. Nieves , S. Arapan , D. Legut

We investigate the elastic and isotropic aggregate properties of ferromagnetic bcc iron as a function of temperature and pressure by computing the Helmholtz free energies for the volume-conserving strained structures using the…

Materials Science · Physics 2009-11-11 Xianwei Sha , R. E. Cohen

Computing the temperature and stress dependence of the full elastic constant tensor from first-principles in non-cubic materials remains a challenging problem. Here we circumvent the aforementioned challenge via the generalized…

Materials Science · Physics 2024-03-01 Mark A. Mathis , Chris A. Marianetti

Understanding the anharmonic phonon properties of crystal compounds -- such as phonon lifetimes and thermal conductivities -- is essential for investigating and optimizing their thermal transport behaviors. These properties also impact…

The quasiharmonic approximation (QHA), in its simplest form also called the statically constrained (SC) QHA, has been shown to be a straightforward method to compute thermoelastic properties of crystals. Recently we showed that for…

Materials Science · Physics 2009-11-13 Pierre Carrier , João F. Justo , Renata M. Wentzcovitch

We calculate the temperature-dependent elastic constants of palladium, platinum, copper and gold within the quasi-harmonic approximation using a first-principles approach and evaluating numerically the second derivatives of the Helmholtz…

Materials Science · Physics 2021-09-22 Cristiano Malica , Andrea Dal Corso

The structural and magnetic properties of functional Ni-Mn-Z (Z = Ga, In, Sn) Heusler alloys are studied by first-principles and Monte Carlo methods. The \textit{ab initio} calculations give a basic understanding of the underlying physics…

Recent discovery of new materials for thermoelectric energy conversion is enabled by efficient prediction of materials' performance from first-principles, without empirically fitted parameters. The novel simplified approach for computing…

Materials Science · Physics 2018-05-02 Georgy Samsonidze , Boris Kozinsky

We have investigated the finite temperature elastic properties of AlRE (RE=Y, Tb, Pr, Nd, Dy) with B2-type structures from first principles. The phonon free energy and thermal expansion is obtained from the quasiharmonic approach based on…

Materials Science · Physics 2011-11-08 Rui Wang , Shaofeng Wang , Xiaozhi Wu
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