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Koopmans spectral functionals aim to describe simultaneously ground state properties and charged excitations of atoms, molecules, nanostructures and periodic crystals. This is achieved by augmenting standard density functionals with simple…

Materials Science · Physics 2022-07-25 Nicola Colonna , Riccardo De Gennaro , Edward Linscott , Nicola Marzari

We present a rapidly convergent scheme for computing globally optimal Wannier functions of isolated single bands for matrix models in two dimensions. The scheme proceeds first by constructing provably exponentially localized Wannier…

Mathematical Physics · Physics 2025-04-24 Hanwen Zhang

In this work we investigate the Wigner localization of two interacting electrons at very low density in two and three dimensions using the exact diagonalization of the many-body Hamiltonian. We use our recently developed method based on…

Strongly Correlated Electrons · Physics 2021-10-13 Miguel Escobar Azor , Estefania Alves , Stefano Evangelisti , J. Arjan Berger

We develop a computational workflow for high-throughput Wannierization of density functional theory (DFT) based electronic band structure calculations. We apply this workflow to 1771 materials, and we create a database with the resulting…

Materials Science · Physics 2020-07-03 Kevin F. Garrity , Kamal Choudhary

We develop a comprehensive theory for the effective dynamics of Bloch electrons based on symmetry. We begin with a scheme to systematically derive the irreducible representations (IRs) characterizing the Bloch functions. Starting from a…

Mesoscale and Nanoscale Physics · Physics 2019-09-06 E. A. Fajardo , R. Winkler

We propose a computational scheme for the ab initio calculation of Wannier functions (WFs) for correlated electronic materials. The full-orbital Hamiltonian H is projected into the WF subspace defined by the physically most relevant…

Maximally localized Wannier functions (MLWFs) are conventionally constructed by iteratively minimizing a spread functional over a high-dimensional gauge landscape. In this work, we present a non-variational constructive algorithm that…

Materials Science · Physics 2026-05-15 Yuji Hamai , Katsunori Wakabayashi

The problem of construction of the Wannier functions (WFs) in a restricted Hilbert space of eigenstates of the one-electron Hamiltonian $\hat{H}$ (forming the so-called low-energy part of the spectrum) can be formulated in several different…

Strongly Correlated Electrons · Physics 2007-05-23 I. V. Solovyev , Z. V. Pchelkina , V. I. Anisimov

Computing the $GW$ quasiparticle bandstructure and Bethe-Salpeter Equation (BSE) absorption spectra for materials with spin-orbit coupling has commonly been done by treating $GW$ corrections and spin-orbit coupling as separate perturbations…

The accurate prediction of band gaps and structural properties in periodic systems continues to be one of the central goals of electronic structure theory. However, band gaps obtained from popular exchange-correlation functionals (such as…

Materials Science · Physics 2022-03-18 Ravindra Shinde , Sharma S. R. K. C. Yamijala , Bryan M. Wong

We present an extension of the quasiparticle self-consistent $GW$ approximation (QS$GW$) [Phys. Rev. B, 76 165106 (2007)] to include vertex corrections in the screened Coulomb interaction $W$. This is achieved by solving the Bethe-Salpeter…

Materials Science · Physics 2023-10-11 Brian Cunningham , Myrta Grüning , Dimitar Pashov , Mark van Schilfgaarde

We propose a general method of constructing Wannier functions in disordered systems directly out of energy eigenstates. This method consists of two successive operations: (i) a phase transformation setting the proper localization center;…

Disordered Systems and Neural Networks · Physics 2015-12-24 Junbo Zhu , Zhu Chen , Biao Wu

With its monoelemental composition, various crystalline forms and an inherently strong spin-orbit coupling, bismuth has been regarded as an ideal prototype material to expand our understanding of topological electronic structures. In…

In this paper we present calculations on the electronic band structure of a two-dimensional lateral superlattice subject to a perpendicular magnetic field by employing a projection operator technique based on the ray-group of…

Materials Science · Physics 2009-11-11 G. S. Kliros , P. C. Divari

A multiband empirical tight-binding model for group-III-nitride semiconductors with a wurtzite structure has been developed and applied to both bulk systems and embedded quantum dots. As a minimal basis set we assume one s-orbital and three…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Daniel Mourad , Stefan Barthel , Gerd Czycholl

Maximally-localized Wannier functions (MLWFs) are widely employed as an essential tool for calculating the physical properties of materials due to their localized nature and computational efficiency. Projectability-disentangled Wannier…

Materials Science · Physics 2025-11-25 Yuhao Jiang , Junfeng Qiao , Nataliya Paulish , Weisheng Zhao , Nicola Marzari , Giovanni Pizzi

We establish a first-principles theory of vacuum Wannier functions unifying tight-binding and nearly-free-electron descriptions across solid-vacuum interfaces. Analytic solutions for canonical Wannier functions in arbitrary dimension and…

Materials Science · Physics 2026-03-17 Tyler Wu , Tomás Arias

Hedin's $GW$ approximation to the electronic self-energy has been impressively successful to calculate quasiparticle energies, such as ionization potentials, electron affinities, or electronic band structures. The success of this fairly…

Chemical Physics · Physics 2024-10-31 Arno Förster , Fabien Bruneval

The electronic band structure of V$_2$O$_5$ is calculated using an all-electron quasiparticle self-consistent (QS) $GW$ method, including electron-hole ladder diagrams in the screening of $W$. The optical dielectric function calculated with…

Materials Science · Physics 2024-07-31 Claudio Garcia , Santosh Kumar Radha , Swagata Acharya , Walter R. L. Lambrecht

We present an efficient first-principles approach for calculating Fermi surface averages and spectral properties of solids, and use it to compute the low-field Hall coefficient of several cubic metals and the magnetic circular dichroism of…

Materials Science · Physics 2009-11-13 Jonathan R. Yates , Xinjie Wang , David Vanderbilt , Ivo Souza