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Related papers: Laser-induced alignment and orientation of quantum…

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We show that field-free molecular orientation induced by a half-cycle pulse may be considerably enhanced by an additional laser pulse inducing molecular anti-alignment. Two qualitatively different enhancement mechanisms are identified…

Quantum Physics · Physics 2009-11-11 E. Gershnabel , I. Sh. Averbukh , R. J. Gordon

A beam of diatomic molecules scattered off a standing wave laser mode splits according to the rovibrational quantum state of the molecules. Our numerical calculation shows that single state resolution can be achieved by properly tuned,…

Quantum Physics · Physics 2009-11-06 P. Domokos , T. Kiss , J. Janszky

We study interaction of generic asymmetric molecules with a pair of strong time-delayed short laser pulses with crossed linear polarizations. We show that such an excitation not only provides unidirectional rotation of the most polarizable…

Chemical Physics · Physics 2018-02-28 E. Gershnabel , I. Sh. Averbukh

We present a theoretical study of recent laser-alignment and mixed-field-orientation experiments of asymmetric top molecules. In these experiments, pendular states were created using linearly polarized strong ac electric fields from pulsed…

We present a method to design a finite decay rate for excited rotational states in polar molecules. The setup is based on a hybrid system of polar molecules with atoms driven into a Rydberg state. The atoms and molecules are coupled via the…

Quantum Gases · Physics 2012-05-15 Sebastian D. Huber , Hans Peter Büchler

We computationally demonstrate a new method for coherently controlling the rotation-axis direction in asymmetric top molecules with an optical centrifuge. Appropriately chosen electric-field strengths and the centrifuge's acceleration rate…

Chemical Physics · Physics 2021-06-16 Emil J. Zak , Andrey Yachmenev , Jochen Küpper

Collective coherent scattering of laser light by an ensemble of polarizable point particles creates long range interactions, whose properties can be tailored by choice of injected laser powers, frequencies and polarizations. We use a…

Quantum Physics · Physics 2015-06-17 Stefan Ostermann , Matthias Sonnleitner , Helmut Ritsch

In recent years it became possible to align molecules in free space using ultrashort laser pulses. Here we explore two schemes for controlling molecule-surface scattering process, which are based on the laser-induced molecular alignment. In…

Chemical Physics · Physics 2015-05-28 Yuri Khodorkovsky , J. R. Manson , Ilya Sh. Averbukh

We propose a method for achieving highly efficient transfer between the vibrational states in a diatomic molecule. The process is mediated by strong laser pulses and can be understood in terms of light-induced potentials. In addition to…

Quantum Physics · Physics 2009-11-06 M. Rodriguez , K. -A. Suominen , B. M. Garraway

Laser-induced alignment of particles and molecules was long envisioned to support three-dimensional structure determination using "single-molecule diffraction" with x-ray free-electron lasers [PRL 92, 198102 (2004)]. However, the alignment…

Computational Physics · Physics 2025-02-05 Muhamed Amin , Jean-Michel Hartmann , Amit K. Samanta , Jochen Küpper

The propensity of molecules to spatially align along the polarization vector of intense, pulsed light fields is related to readily-accessible parameters (molecular polarizabilities, moment of inertia, peak intensity of the light and its…

Atomic Physics · Physics 2009-11-06 S. Banerjee , D. Mathur , G. Ravindra Kumar

A theoretical study of the rotational dynamics of a linear polar molecule in a two-color non-resonant cw laser field is presented. By systematically considering the interactions of this field with the electric dipole moment, polarizability…

Quantum Physics · Physics 2020-08-26 David Mellado-Alcedo , Niurka R. Quintero , Rosario González-Férez

Coherent control of chaotic molecular systems, using laser-assisted alignment of sulphur dioxide (SO$_2$) molecules in the presence of a static electric field as an example, is considered. Conditions for which the classical version of this…

Chemical Physics · Physics 2017-04-26 Johannes Floß , Paul Brumer

Present photoionization experiments cannot measure molecular frame photoelectron angular distributions (MFPAD) from the outermost valence electrons of molecules. We show that details of the MFPAD can be retrieved with high-order harmonics…

Atomic Physics · Physics 2009-05-24 Anh-Thu Le , R. R. Lucchese , M. T. Lee , C. D. Lin

While many-particle entanglement can be found in natural solids and strongly interacting atomic and molecular gases, generating highly entangled states between weakly interacting particles in a controlled and scalable way presents a…

Atomic Physics · Physics 2013-02-27 Felipe Herrera , Sabre Kais , K. Birgitta Whaley

Molecules have vibrational, rotational, spin-orbit and hyperfine degrees of freedom or quantum states, each of which responds in a unique fashion to external electromagnetic radiation. The control over superpositions of these quantum states…

Quantum Physics · Physics 2024-04-29 Svetlana Kotochigova , Qingze Guan , Eite Tiesinga , Vito Scarola , Brian DeMarco , Bryce Gadway

The local interaction of charges and light in organic solids is the basis of distinct and fundamental effects. We here observe, at the single molecule scale, how a focused laser beam can locally shift by hundreds-time their natural…

We have experimentally and theoretically investigated the mixed-field orientation of rotational-state-selected OCS molecules and we achieve strong degrees of alignment and orientation. The applied moderately intense nanosecond laser pulses…

An array of radiatively coupled emitters is an exciting new platform for generating, storing, and manipulating quantum light. However, the simultaneous positioning and tuning of multiple lifetime-limited emitters into resonance remains a…

Quantum Physics · Physics 2024-02-23 Christian Lange , Emma Daggett , Valentin Walther , Libai Huang , Jonathan D. Hood

We provide a theory of the deflection of polar and non-polar rotating molecules by inhomogeneous static electric field. Rainbow-like features in the angular distribution of the scattered molecules are analyzed in detail. Furthermore, we…

Chemical Physics · Physics 2015-05-20 E. Gershnabel , I. Sh. Averbukh