Related papers: Born-Oppenheimer approximation for a harmonic mole…
We extend the Born-Oppenheimer type of approximation scheme for the Wheeler-DeWitt equation of canonical quantum gravity to arbitrary orders in the inverse Planck mass squared. We discuss in detail the origin of unitarity violation in this…
In this work, we illustrate the recently introduced concept of the cavity Born-Oppenheimer approximation for correlated electron-nuclear-photon problems in detail. We demonstrate how an expansion in terms of conditional electronic and…
We employ the Born-Oppenheimer approximation to find the effective potential in a three-body system consisting of a light particle and two heavy ones when the heavy-light short-range interaction potential has a resonance corresponding to a…
The one-dimensional harmonic oscillator in a box problem is possibly the simplest example of a two-mode system. This system has two exactly solvable limits, the harmonic oscillator and a particle in a (one-dimensional) box. Each of the two…
We address the question of the reliability of the Born-Oppenheimer (BO) approximation for a mass-imbalanced resonant three-body system embedded in noninteger dimensions. We address this question within the problem of a system of currently…
The method of many-body Green's functions is developed for arbitrary systems of electrons and nuclei starting from the full (beyond Born-Oppenheimer) Hamiltonian of Coulomb interactions and kinetic energies. The theory presented here…
Bohr's atomic model, its relationship to the radiation spectrum of the hydrogen atom and the inherent hypotheses are revisited. It is argued that Bohr could have adopted a different approach, focusing his analyzes on the stationary orbit of…
In this paper we study in details a system of two weakly coupled harmonic oscillators. This system may be viewed as a simple model for the interaction between a photon and a photodetector. We obtain exact solutions for the general case. We…
The main purpose of this paper is to demonstrate and illustrate, once again, the potency of the variational technique as an approximation procedure for the quantization of quantum mechanical systems. By choosing particle-in-a-box…
The efficient and accurate calculation of how ionic quantum and thermal fluctuations impact the free energy of a crystal, its atomic structure, and phonon spectrum is one of the main challenges of solid state physics, especially when strong…
We consider the vibrational energy levels of the first two electronic states of the molecule ion $H_2^+$. The Born-Oppenheimer method applied to the case of the Stark effect on a $H_2^+$-like molecule gives existence of sharp resonances…
The problem of calculating the electron-positively charged particle correlation energy poses a challenge in the field of quantum chemistry beyond the adiabatic approximation. In this study, a toy model called Exotic Harmonium is developed…
The transport of charged particles or photons in a scattering medium can be modelled with a Boltzmann equation. The mathematical treatment for scattering in such scenarios is often simplified if evaluated in a frame where the scattering…
Computationally tractable and reliable, albeit approximate, methods for studying exciton transport in molecular aggregates immersed in structured bosonic environments have been actively developed. Going beyond the lowest-order (Born)…
In this note we discuss the Efimov effect emerging in a three-particle quantum system with zero-range interactions. In particular, we consider two non-interacting identical bosons plus a different lighter particle such that the interaction…
We investigate the effects of the electromagnetic vacuum field on a harmonically bound electron. We show that in the electric-dipole approximation the model atom couples only to an effective one-dimensional electric field. In a simplified…
We apply the Anharmonic Oscillator Symmetry Model to the description of vibrational excitations in ${\cal D}_{3h}$ and ${\cal T}_d$ molecules. A systematic procedure can be used to establish the relation between the algebraic and…
We report on deviations beyond the Born-Oppenheimer approximation in the potassium inter-atomic potentials. Identifying three up-to-now unknown $d$-wave Feshbach resonances, we significantly improve the understanding of the $^{39}$K…
Formulae for the value of a harmonic function at the center of a rectangle are found that involve boundary integrals. The central value of a harmonic function is shown to be well approximated by the mean value of the function on the…
We develop a quantum embedding method that enables accurate and efficient treatment of interactions between molecules and an environment, while explicitly including many-body correlations. The molecule is composed of classical nuclei and…