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A most basic and puzzling enigma in surface science is the description of the dissociative adsorption of O2 at the (111) surface of Al. Already for the sticking curve alone, the disagreement between experiment and results of…

Materials Science · Physics 2009-11-10 Joerg Behler , Bernard Delley , Soenke Lorenz , Karsten Reuter , Matthias Scheffler

In this paper, we discuss the dissociative electron attachment process in Ammonia. Kinetic energy and angular distributions of H^{-} and NH_{2}^{-} fragment anions across the two well known resonances at 5.5 eV and 10.5 eV are reported. The…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

In all theoretical treatments of electron transport through single molecules between two metal electrodes, a clear distinction has to be made between a coherent transport regime with a strong coupling throughout the junction and a Coulomb…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Robert Stadler , Jerome Cornil , Victor Geskin

We present the results of calculations defining global, three-dimensional representations of the complex-valued potential-energy surfaces of the doublet B1, doublet A1, and doublet B2 metastable states of the water anion that underlie the…

Chemical Physics · Physics 2009-11-13 Daniel J. Haxton , C. W. McCurdy , T. N. Rescigno

Electronic excitations near the surface of water ice lead to the desorption of adsorbed molecules, through a so far debated mechanism. A systematic study of photon-induced indirect desorption, revealed by the spectral dependence of the…

Using first-principles calculations, we systematically study the adsorption behavior of a single molecular H$_{2}$O on the Be(0001) surface. We find that the favored molecular adsorption site is the top site with an adsorption energy of…

Materials Science · Physics 2015-05-27 Shuang-Xi Wang , Peng Zhang , Jian Zhao , Shu-Shen Li , Ping Zhang

Nitrogen-doped graphene was recently synthesized and was reported to be a catalyst for hydrogen dissociative adsorption under a perpendicular applied electric field (F). In this work, the diffusion of H atoms on N-doped graphene, in the…

Materials Science · Physics 2012-02-15 Z. M. Ao , A. D. Hernández-Nieves , F. M. Peeters , S. Li

When hydrogen molecules collide with a surface, they can either scatter away from the surface or stick to the surface through a dissociation reaction which leaves two H atoms adsorbed on the surface. The relative probabilities of these two…

Chemical Physics · Physics 2024-10-03 H. Chadwick , G. Zhang , C. J. Baker , P. L. Smith , G. Alexandrowicz

In the present paper, we report the details of the kinetic energy and angular distributions of the H^{-}, S^{-}/SH^{-} fragment ions produced due to dissociative electron attachment in H_{2}S molecules at resonances peaking at 2.2 eV, 5.2…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

Kinetic energy and angular distributions of O$^-$ ions formed by dissociative electron attachment to CO molecule have been studied for 9, 9.5, 10, 10.5, 11, 11.5 eV incident electron energies around the resonance using time sliced velocity…

Atomic and Molecular Clusters · Physics 2015-02-10 Pamir Nag , Dhananjay Nandi

We show that the radiative heat transfer between two solid surfaces at short separation may increase by many order of magnitude when the surfaces are covered by adsorbates. In this case the heat transfer is determined by resonant photon…

Materials Science · Physics 2009-11-11 A. I. Volokitin , B. N. J. Persson

Understanding the microscopic spatio-temporal dynamics of nonequilibrium charge carriers in heterosystems promises optimization of process and device design towards desired energy transfer. Hot electron transport is governed by scattering…

The dynamics following the photoexcitation of Na and Li atoms located on the surface of helium nanodroplets has been investigated in a joint experimental and theoretical study. Photoelectron spectroscopy has revealed that excitation of the…

Atomic and Molecular Clusters · Physics 2017-08-23 Alberto Hernando , Manuel Barranco , Martí Pi , Evgeniy Loginov , Marina Langlet , Marcel Drabbels

NO scattering from metallic and insulating surfaces represent contrasting benchmark systems for understanding energy transfer at gas-surface interface. Strikingly different behaviors of highly vibrationally excited NO scattered from Au(111)…

Materials Science · Physics 2021-04-21 Rongrong Yin , Bin Jiang

An ultra-strong photovoltaic effect has recently been reported for electrons trapped on a liquid Helium surface under a microwave excitation tuned at intersubband resonance [D. Konstantinov et. al. : J. Phys. Soc. Jpn. 81, 093601 (2012) ].…

Mesoscale and Nanoscale Physics · Physics 2013-07-24 F. Closa , E. Raphael , A. D. Chepelianskii

We report on an unconventional $macroscopic$ field effect transistor composed of electrons floating above the surface of superfluid helium. With this device unique transport regimes are realized in which the charge density of the electron…

Mesoscale and Nanoscale Physics · Physics 2018-10-26 K. Nasyedkin , H. Byeon , L. Zhang , N. R. Beysengulov , J. Milem , S. Hemmerle , R. Loloee , J. Pollanen

Combined first-principles and experimental investigations reveal the underlying mechanism responsible for a drastic change of the conductivity (by 10 orders of magnitude) following hydrogen annealing and UV-irradiation in a transparent…

Materials Science · Physics 2009-11-10 J. E. Medvedeva , A. J. Freeman , M. I. Bertoni , T. O. Mason

The adsorption and dissociation of isolated water molecule on Zr(0001) surface are theoretically investigated for the first time by using density-functional theory calculations. Two kinds of adsorption configurations with almost the same…

Materials Science · Physics 2015-05-27 Shuang-Xi Wang , Ping Zhang , Peng Zhang , Jian Zhao , Shu-Shen Li

The electronic structure of a monolayer of single-molecule magnets Mn$_{12}$ on a Au(111) surface is studied using spin-polarized density-functional theory. The Mn$_{12}$ molecules are oriented such that the magnetic easy axis is normal to…

Materials Science · Physics 2010-01-28 Salvador Barraza-Lopez , Michael C. Avery , Kyungwha Park

We present a molecular dynamics simulation of shock waves propagating in dense deuterium with the electron force field method [J. T. Su and W. A. Goddard, Phys. Rev. Lett. 99, 185003 (2007)], which explicitly takes the excitation of…

Plasma Physics · Physics 2017-03-08 Hao Liu , Yin Zhang , Wei Kang , Ping Zhang , Huiling Duan , X. T. He
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