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The role of exchange-correlation effects in non-equilibrium quantum transport through molecular junctions is assessed by analyzing the IV curve of a generic two-level model using self-consistent many-body perturbation theory (second Born…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Kristian S. Thygesen

We have developed a theoretical formalism to investigate the contribution of fluctuation of Coulomb interaction to the shot noise based on Keldysh non-equilibrium Green's function method. We have applied our theory to study the behavior of…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 Duo Li , Lei Zhang , Fuming Xu , Jian Wang

A quantum transport model incorporating spin scattering processes is presented using the non-equilibrium Green's function (NEGF) formalism within the self-consistent Born approximation. This model offers a unified approach by capturing the…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Ahmet Ali Yanik , Gerhard Klimeck , Supriyo Datta

We calculate the finite temperature and non-equilibrium electric current through systems described generically at low energy by a singlet and \emph{two} spin doublets for $N$ and $N \pm 1$ electrons respectively, coupled asymmetrically to…

Strongly Correlated Electrons · Physics 2011-08-24 P. Roura-Bas , L. Tosi , A. A. Aligia , K. Hallberg

The structural, cohesive, electronic and optical properties of mixed SiGe:H quantum dots are studied by Density Functional Theory (DFT) calculations on a representative ensemble of medium size nanoparticles of the form…

Materials Science · Physics 2007-10-02 C. S. Garoufalis

We investigate the spectral and transport properties of parallel double-quantum-dot (DQD) system with interdot tunneling coupling in both the equilibrium and nonequilibrium cases. The special geometry of DQD system is considered, in which…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Rong Lu , Zhi-Rong Liu , Guang-Ming Zhang

We report theoretical investigations on the role of interfacial bonding mechanism and its resulting structures to quantum transport in molecular wires. Two bonding mechanisms for the Au-S bond in an Au(111)/1,4-benzenedithiol(BDT)/Au(111)…

Mesoscale and Nanoscale Physics · Physics 2014-12-01 Zhanyu Ning , Jingsi Qiao , Wei Ji , Hong Guo

We show theoretically and experimentally the existence of a new quantum interference(QI) effect between the electron-hole interactions and the scattering by a single Mn impurity. Theoretical model, including electron-valence hole…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 A. Trojnar , M. Korkusinski , E. Kadantsev , P. Hawrylak , M. Goryca , T. Kazimierczuk , P. Kossacki , P. Wojnar , M. Potemski

We investigate electron transport through single conjugated molecules - including benzenedithiol, oligo-phenylene-ethynylenes of different lengths, and a ferrocene-containing molecule sandwiched between two gold electrodes with different…

Mesoscale and Nanoscale Physics · Physics 2009-08-12 San-Huang Ke , Harold U. Baranger , Weitao Yang

The transmission of electrons through a non-interacting tight-binding chain with an interacting side quantum dot (QD) is analized. When the Kondo effect develops at the dot the conductance presents a wide minimum, reaching zero at the…

Strongly Correlated Electrons · Physics 2009-11-07 M. E. Torio , K. Hallberg , A. H. Ceccatto , C. R. Proetto

We discuss the effect of quantum interference on transport through a quantum dot system. We introduce an indirect coherent coupling parameter alpha, which provides constructive/destructive interference in the transport current depending on…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Y. Tokura , H. Nakano , T. Kubo

We study computationally the electron transport properties of dithiocarboxylate terminated molecular junctions. Transport properties are computed self-consistently within density functional theory and nonequilibrium Green's functions…

Materials Science · Physics 2007-05-23 Zhenyu Li , D. S. Kosov

We apply Density Functional Theory (DFT) and the DFT+U technique to study the adsorption of transition metal porphine molecules on atomistically flat Au(111) surfaces. DFT calculations using the Perdew-Burke-Ernzerhof (PBE) exchange…

We study the optical properties of hydrogen passivated silicon, germanium and mixed Ge/Si core/shell quantum dots (QDs) using high accuracy Density Functional Theory (DFT) and time-dependent DFT (TDFT). We employ the hybrid DFT functional…

Mesoscale and Nanoscale Physics · Physics 2016-04-19 Shanawer Niaz , Aristides D. Zdetsis , Manzoor Ahmad Badar , Safdar Hussain , Imran Sadiq , Muhammad Aslam Khan

Inspired by the formulation of quantum-electrodynamical time-dependent density functional theory (QED-TDDFT) by Rubio and coworkers, we propose an implementation that uses dimensionless amplitudes for describing the photonic contributions…

Materials Science · Physics 2021-08-20 Junjie Yang , Qi Ou , Zheng Pei , Hua Wang , Binbin Weng , Kieran Mullen , Yihan Shao

Embedded density functional theory (e-DFT) is used to describe the electronic structure of strongly interacting molecular subsystems. We present a general implementation of the Exact Embedding (EE) method [J. Chem. Phys. 133, 084103 (2010)]…

Other Condensed Matter · Physics 2011-07-27 Jason D. Goodpaster , Taylor A. Barnes , Thomas F. Miller

Quantum mechanical methods based on the density functional theory (DFT) offer a realistic possibility of first-principles design of organic donor-acceptor systems and engineered band-gap materials. This promise is contingent upon the…

Chemical Physics · Physics 2013-12-03 Marcin Modrzejewski , Grzegorz Chałasiński , Małgorzata M. Szczęśniak

The key features of density-functional theory (DFT) within a minimalistic implementation of quantum electrodynamics are demonstrated, thus allowing to study elementary properties of quantum-electrodynamical density-functional theory…

We study electron transport through a quantum interferometer with side-coupled quantum dots. The interferometer, threaded by a magnetic flux $\phi$, is attached symmetrically to two semi-infinite one-dimensional metallic electrodes. The…

Mesoscale and Nanoscale Physics · Physics 2010-12-17 Santanu K. Maiti

Optical properties of symmetry-forbidden pi-pi transitions in benzene are calculated with the time-dependent density functional theory (TDDFT), using an adiabatic LDA functional. Quantities calculated are the envelopes of the Franck-Condon…

Chemical Physics · Physics 2007-05-23 A. Schnell , G. F. Bertsch , K. Yabana