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A computational model for the simulation of a double band collector-generator experiment is applied to the situation where two electrochemical reactions occur concurrently. It is shown that chronoamperometric measurements can be used to…

Chemical Physics · Physics 2013-10-28 Edward O. Barnes , Grace E. M. Lewis , Sara E. C. Dale , Frank Marken , Richard G. Compton

This mini-review synthesizes our understanding of the equilibrium behavior of particle models with short-range attractive and long-range repulsive (SALR) interactions. These models, which can form stable periodic microphases, aim to…

Soft Condensed Matter · Physics 2022-05-03 Yuan Zhuang , Patrick Charbonneau

We calculate the ion and composition distributions around colloid particles in an aqueous mixture, accounting for preferential adsorption, electrostatic interaction, selective solvation among ions and polar molecules, and…

Soft Condensed Matter · Physics 2011-11-04 Ryuichi Okamoto , Akira Onuki

Solid solutions, structurally ordered but compositionally disordered mixtures, can form for salts, metals, and even organic compounds. The NaCl-KCl system forms a solid solution at all compositions between 657{\deg}C and 505{\deg}C. Below a…

Statistical Mechanics · Physics 2020-04-16 Jamshed Anwar , Christian Leitold , Baron Peters

We propose a new model for treating solid-phase photoprocesses in interstellar ice analogues. In this approach, photoionization and photoexcitation are included in more detail, and the production of electronically-excited (suprathermal)…

We propose a realistic model of the optical properties of silver, in which inter-band transition with a threshold energy of ~ 4 eV is described phenomenologically by an ensemble of oscillators with same damping constant and a certain…

Materials Science · Physics 2013-12-12 Armen Melikyan , Boris Kryzhanovsky

The phase behavior of a single type of colloid C suspended in near-critical solvents is known to be very rich. Motivated in part by recent experiments we consider a mixture of two colloidal types C1 and C2 in a binary solvent close to its…

Soft Condensed Matter · Physics 2026-03-23 Nima Farahmand Bafi , Robert Evans , Anna Maciolek

In this paper the normal collision of spherical particles is investigated. The particle interaction is modelled in a macroscopic way using the Hertzian contact force with additional linear damping. The goal of the work is to develop an…

Fluid Dynamics · Physics 2016-03-02 Shouryya Ray , Tobias Kempe , Jochen Fröhlich

An appropriate model Hamiltonian based formalism is proposed for a random adsorbate layer with arbitrary coverage and the ensuing two-dimensional band formation by metallic adsorbates in the monolayer regime. The coherent potential…

Chemical Physics · Physics 2007-05-23 A. K. Mishra

We computed the self-organisation process of a monodisperse collection of spherical micrometric particles trapped in a two-dimensional (2D) thin liquid film isothermally dried on a chemically inert substrate. The substrate is either flat or…

Soft Condensed Matter · Physics 2009-11-11 F. Lallet , N. Olivi-Tran

Solid-state dewetting phenomenon in silver thin films offers a straightforward method to obtain structures having controlled shape or size -this latter in principle spanning several orders of magnitudes -- with potentially strong interest…

Materials Science · Physics 2020-07-10 M. Berni , I. Carrano , A. Kovtun , A. Russo , A. Visani , C. Dionigi , A. Liscio , F. Valle , A. Gambardella

In this paper we present a modeling approach to bridge the atomistic with macroscopic scales in crystalline materials. The methodology combines identification and modeling of the controlling unit processes at microscopic level with the…

Materials Science · Physics 2009-11-07 A. M. Cuitino , L. Stainier , G. Wang , A. Strachan , T. Cagin , W. A. Goddard , M. Ortiz

Using the stabilized jellium model with self-compression, we have calculated the dissociation energies and the barrier heights for the binary fragmentation of charged silver clusters. At each step of calculations, we have used the…

Atomic and Molecular Clusters · Physics 2007-05-23 M. Payami

The thermodynamics and kinetics of crystallization of nanoparticles, as opposed to bulk phases, may be influenced by surface and size effects. We investigate the importance of such factors in the crystallization process of gold, silver, and…

Statistical Mechanics · Physics 2024-07-09 Arthur France-Lanord , Sarath Menon , Julien Lam

Microelectronic-grade copper foils were immersion silver plated in a home-made non-cyanide alkaline silver nitrate - thiosulfate solution and in two commercially available industrial baths via contact reductive precipitation. The…

Materials Science · Physics 2015-02-06 T. I. Török , A. Csik , J. Hakl , K. Vad , L. Kövér , J. Tóth , S. Mészáros , É. Kun , D. Sós

The assembly of colloidal cubic diamond is a challenging process since the shape and interaction parameters and the thermodynamic conditions where this structure is stable are elusive. The simultaneous use of shape-anisotropic particles and…

Soft Condensed Matter · Physics 2024-06-12 Susana Marín-Aguilar , Fabrizio Camerin , Marjolein Dijkstra

A simple three-dimensional model of a fluid whose constituent particles interact via a short range attractive and long range repulsive potential is used to model the aggregation into large spherical-like clusters made up of hundreds of…

Soft Condensed Matter · Physics 2025-02-11 Antonio Díaz-Pozuelo , Diego González-Salgado , Enrique Lomba

By means of multicanonical computer simulations, we investigate thermodynamic properties of the aggregation of interacting semiflexible polymers. We analyze a mesoscopic bead-stick model, where nonbonded monomers interact via Lennard-Jones…

Soft Condensed Matter · Physics 2015-05-28 Christoph Junghans , Michael Bachmann , Wolfhard Janke

Gold-silica hybrids are appealing in different fields of applications like catalysis, sensors, drug delivery, and biotechnology. In most cases, the morphology and distribution of the hetero-units play significant roles in their functional…

Materials Science · Physics 2015-03-04 Paromita Kundu , Hamed Heidari , Sara Bals , N. Ravishankar , Gustaaf Van Tendeloo

Different methods for creating Olympic gels are analyzed using computer simulations. First ideal reference samples are obtained from freely interpenetrating semi-dilute solutions and melts of cyclic polymers. The distribution of pairwise…

Soft Condensed Matter · Physics 2021-05-26 Jakob Fischer , Michael Lang , Jens-Uwe Sommer