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A theoretical study on the phase behaviors of a polymer solution confined between two coaxial cylindrical walls is presented. For the case of a neutral inner cylinder, the spinodal point derived through the Gaussian fluctuation theory is…

Soft Condensed Matter · Physics 2009-09-23 Tongchuan Suo , Dadong Yan

We study the dynamics of the phase behavior of a polymer blend in the presence of shear flow. By adopting a two fluid picture and using a generalization of the concept of material derivative, we construct kinetic equations that describe the…

Soft Condensed Matter · Physics 2009-10-30 Tao Sun , Anna C. Balazs , David Jasnow

We study dynamics of a Rouse polymer chain, which diffuses in a three-dimensional space under the constraint that one of its ends, referred to as the slip-link, may move only along a one-dimensional line containing randomly placed,…

Statistical Mechanics · Physics 2007-05-23 S. Nechaev , G. Oshanin , A. Blumen

The relaxation of a single knotted ring polymer is studied by Brownian dynamics simulations. The relaxation rate lambda_q for the wave number q is estimated by the least square fit of the equilibrium time-displaced correlation function to a…

Soft Condensed Matter · Physics 2008-06-11 Shinya Saka , Hiroshi Takano

Under an applied external load the global load-sharing fiber bundle model, with individual fiber strength thresholds sampled randomly from a probability distribution, will relax to an equilibrium state, or to complete bundle breakdown. The…

Statistical Mechanics · Physics 2010-09-20 Srutarshi Pradhan , Per C. Hemmer

We examine the ejection of an initially strongly confined flexible polymer from a spherical capsid through a nanoscale pore. We use molecular dynamics for unprecedentedly high initial monomer densities. We show that the time for an…

Biological Physics · Physics 2016-01-06 J. Piili , R. P. Linna

We explore the critical behaviour of two and three dimensional lattice models of polymers in dilute solution where the monomers carry a magnetic moment which interacts ferromagnetically with near-neighbour monomers. Specifically, the model…

Statistical Mechanics · Physics 2021-08-25 Damien Paul Foster , Debjyoti Majumdar

This report deals with phase transition in Bond Fluctuation Model (BFM) of a linear homo polymer on a two dimensional square lattice. Each monomer occupies a unit cell of four lattice sites. The condition that a lattice site can at best be…

Soft Condensed Matter · Physics 2012-04-16 Hima Bindu Kolli , K. P. N. Murthy

We construct a phenomenological theory of self-localization of directed polymers in d+1 dimensions. In d=1 we show that the polymer is always self-localized, whereas in d=2 there is a phase transition between localized and free states. We…

Statistical Mechanics · Physics 2007-05-23 T. J. Newman , Eugene B. Kolomeisky

By large-scale Monte Carlo simulations of semiflexible polymers in $d=2$ dimensions the applicability of the Kratky-Porod model is tested. This model is widely used as "standard model" for describing conformations and force versus extension…

Soft Condensed Matter · Physics 2011-11-15 Hsiao-Ping Hsu , Wolfgang Paul , Kurt Binder

We consider the properties of a self-avoiding polymer chain, adsorbed on a solid attractive substrate which is attached with one end to a pulling force. The conformational properties of such chain and its phase behavior are treated within a…

Soft Condensed Matter · Physics 2009-04-01 S. Bhattacharya , V. G. Rostiashvili , A. Milchev , T. A. Vilgis

We study the diffusion of a linear polymer in the presence of permeable membranes without excluded volume interactions, using scaling theory and Monte Carlo simulations. We find that the average time it takes for a chain with polymerization…

Condensed Matter · Physics 2016-08-31 Hyoungsoo Yoon , J. M. Deutsch

The dynamic behavior of semi-dilute polymer solutions is governed by an interplay between solvent quality, concentration, molecular weight, and flow type. Semi-dilute solutions are characterized by large fluctuations in concentration,…

Soft Condensed Matter · Physics 2020-07-03 Kai-Wen Hsiao , Chandi Samsal , J. Ravi Prakash , Charles M. Schroeder

We study the dynamics of a polymer when it is quenched from a $\theta$ solvent into a good or bad solvent by means of a Langevin equation. The variation of the radius of gyration is studied as a function of time. For the first stage of…

Soft Condensed Matter · Physics 2008-02-03 E. Pitard , H. Orland

Using Langevin dynamics complemented by Wang-Landau Monte Carlo simulations, we study the phase behavior of single and multiple semiflexible polymer chains in solution under poor-solvent conditions. In the case of a single chain, we obtain…

Velocity relaxation of a spherically symmetric polymer, immersed in a viscous incompressible fluid, and after a sudden small impulse or a sudden twist from a state of rest, is studied on the basis of the linearized Navier-Stokes equations…

Fluid Dynamics · Physics 2015-06-17 B. U. Felderhof

We present an extensive set of simulation results for the stress relaxation in equilibrium and step-strained bead-spring polymer melts. The data allow us to explore the chain dynamics and the shear relaxation modulus, $G(t)$, into the…

Soft Condensed Matter · Physics 2015-05-18 Ji Xuan Hou , Carsten Svaneborg , Ralf Everaers , Gary S. Grest

The mechanical properties of molecules are today captured by single molecule manipulation experiments, so that polymer features are tested at a nanometric scale. Yet devising mathematical models to get further insight beyond the commonly…

Polymer melts represent the flow-history-dependent behavior. To clearly show this behavior, we have investigated flow behavior of an entangled polymer melt around two cylinders placed in tandem along the flow direction in a two dimensional…

Soft Condensed Matter · Physics 2015-05-30 Takahiro Murashima , Takashi Taniguchi

We introduce a self-avoiding walk model for which end-effects are completely eliminated. We enumerate the number of these walks for various lattices in dimensions two and three, and use these enumerations to study the properties of this…

Statistical Mechanics · Physics 2015-04-09 Nathan Clisby
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