Related papers: Droplet evaporation in one-component fluids: Dynam…
Condensation is an important aspect of many flow applications due to the universal presence of humidity in the air at ambient conditions. For direct numerical simulations of such flows, simulating the gas phase as a mixture characterized by…
We show how dynamical equations for liquid films and drops on uneven surfaces, including contact line dynamics and evaporation/condensation effects, may be formulated as a variational dynamics, generated via Onsager's variational principle.…
he contact angle of a liquid droplet on a surface under partial wetting conditions differs for a nanoscopically rough or periodically corrugated surface from its value for a perfectly flat surface. Wenzel's relation attributes this…
Recent experimental studies of molten metal droplets wetting high temperature reactive substrates have established that the majority of triple-line motion occurs when inertial effects are dominant. In light of these studies, this paper…
The evaporation of a tiny amount of water on the solid surface with different wettability has been studied by molecular dynamics simulations. We found that, as the surface changed from hydrophobicity to hydrophility, the evaporation speed…
When a volatile drop impacts on a superheated solid, air drainage and vapor generation conspire to create an intermediate gas layer that delays or even prevents contact between the liquid and the solid. In this article, we use high-speed…
The interfacial resistance to evaporation, in particular for the case of water, is a longstanding issue. The previous data on its main characterizing parameter, the accommodation coefficient, manifest a dispersion over three orders of…
Everybody knows that when a liquid is heated, its temperature increases until the moment when it starts to boil. The increase in temperature then stops, all heat being used to transform the liquid into vapor. What is the microscopic origin…
The structure of liquid water at ambient conditions is studied in ab initio molecular dynamics simulations using van der Waals (vdW) density-functional theory, i.e. using the new exchange-correlation functionals optPBE-vdW and vdW-DF2.…
A dryout point is recognized as the position where the phase transition from liquid to vapor occurs. In the one-dimensional case, by solving the stationary incompressible Navier-Stokes-Fourier equations with phase transition, we derive a…
We look at the wetting of a pure fluid in contact with a charged flat surface. In the bulk, the fluid is a classical van der Waals fluid containing dissociated ions. The presence of wall and ions leads to strong dielectrophoretic and…
Droplet formation happens in finite time due to the surface tension force. The linear stability analysis is useful to estimate droplet size but fails to approximate droplet shape. This is due to a highly non-linear flow description near the…
Differential geometry is powerful tool to analyze the vapor-liquid critical point on the surface of the thermodynamic equation of state. The existence of usual condition of the critical point $\left( \partial p/\partial V\right) _{T}=0$…
Molecular dynamics simulations are used to study the behavior of closely-fitting spherical and ellipsoidal particles moving through a fluid-filled cylinder at nanometer scales. The particle, the cylinder wall and the fluid solvent are all…
Deformed droplets are ubiquitous in various industrial applications, such as inkjet printing, lab-on-a-chip devices, and spray cooling, and can fundamentally affect the involved applications both favorably and unfavorably. Here, we employ…
I employ the van der Waals theory of Baus and coworkers to analyze the fast, adiabatic decay of a supercooled liquid in a closed vessel with which the solidification process usually starts. By imposing a further constraint on either the…
Solvent loss due to evaporation in a drying drop can drive capillary flows and solute migration. The flow is controlled by the evaporation profile and the geometry of the drop. We predict the flow and solute migration near a sharp corner of…
It is well-known that liquid and saturated vapor, separated by a flat interface in an unbounded space, are in equilibrium. One would similarly expect a liquid drop, sitting on a flat substrate, to be in equilibrium with the vapor…
We suggest a simple model to describe polyamorphism in single-component fluids using a maximum-valence approach. The model contains three types of interactions: i) atoms attract each other by van der Waals forces that generate a liquid-gas…
Fluctuations of the thermal or classical component of the van der Waals force between two dielectric slabs, modelled as an ensemble of polarizable dipoles which interact via the usual electrostatic dipole-dipole interaction, are evaluated.…