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In the present work we theoretically analyze electroluminescence occurring in a biased single-molecule junction with a chiral bridge imitated by a helical chain. We show that optical transitions between electron states of the chiral linker…

Mesoscale and Nanoscale Physics · Physics 2025-07-22 Natalya A Zimbovskaya

Chiral induced spin selectivity is a phenomenon that has been attributed to chirality, spin-orbit interactions, and non-equilibrium conditions, while the role of electron exchange and correlations have been investigated only marginally…

Mesoscale and Nanoscale Physics · Physics 2021-04-28 J. Fransson

Due to the mirror symmetry breaking, chiral structures show fantastic electromagnetic (EM) properties involving negative refraction, giant optical activity, and asymmetric transmission. Aligned electric and magnetic dipoles excited in…

Classical Physics · Physics 2019-08-26 Menglin L. N. Chen , Li Jun Jiang , Wei E. I. Sha , Wallace C. H. Choy , Tatsuo Itoh

We report that normal incidence reflection and transmission of circularly polarized electromagnetic waves from and through planar split-ring metamaterials with chiral symmetry breaking depends on the incidence direction and handedness of…

Optics · Physics 2009-03-31 E. Plum , V. A. Fedotov , N. I. Zheludev

We show that asymmetric transmission for linear polarizations can be easily achieved by a monolayer of anisotropic chiral metamolecules through the constructive and destructive interferences between the contributions from anisotropy and…

Optics · Physics 2015-06-15 Shuang Zhang , Fu Liu , Thomas Zentgraf , Jensen Li

Chiral molecules can selectively transport electrons of a particular spin orientation, yet the underlying mechanism remain poorly understood. Here, we present theoretical evidence that electrons propagating through chiral materials with…

Materials Science · Physics 2024-03-01 Xiaoming Wang , Yeming Xian , Yanfa Yan

We experimentally demonstrate a three-dimensional chiral optical metamaterial that exhibits an asymmetric transmission for forwardly and backwardly propagating linearly polarized light. The observation of this novel effect requires a…

In chemistry and biochemistry, chirality represents the structural asymmetry characterized by non-superimposable mirror images for a material like DNA. In physics, however, chirality commonly refers to the spin-momentum locking of a…

Materials Science · Physics 2024-08-07 Binghai Yan

The functionality of many biological systems depends on reliable electron transfer with minimal heating. Unlike man-made electric circuits, nature realizes electron transport via insulating chiral molecules. Here we include spin into the…

Mesoscale and Nanoscale Physics · Physics 2016-01-18 Karen Michaeli , Ron Naaman

Photoelectron circular dichroism results from one-photon ionization of chiral molecules by circularly polarized light and manifests itself in forward-backward asymmetry of electron emission in the direction orthogonal to the light…

Atomic Physics · Physics 2019-04-24 Andres F. Ordonez , Olga Smirnova

Various device-based experiments have indicated that electron transfer in certain chiral molecules may be spin-dependent, a phenomenon known as the Chiral Induced Spin Selectivity (CISS) effect. However, due to the complexity of these…

Mesoscale and Nanoscale Physics · Physics 2019-01-23 Xu Yang , Caspar H. van der Wal , Bart J. van Wees

Photons experience mirror asymmetry of macroscopic chiral media, as in circular dichroism and polarization rotation, since left and right handed circular polarizations differently couple with matter handedness. Conversely, free relativistic…

Quantum Physics · Physics 2022-04-08 Alessandro Ciattoni

Here we propose a mechanism by which spin polarization can be generated dynamically in chiral molecular systems undergoing photo-induced electron transfer. The proposed mechanism explains how spin polarization emerges in systems where…

Mesoscale and Nanoscale Physics · Physics 2021-08-19 Thomas P. Fay , David T. Limmer

We show that the combination of molecular chirality and phase-controlled driving can lead to rectification of vibrational energy transfer. We demonstrate this effect using classical models of (1) a single helical chain and (2) a more…

Chemical Physics · Physics 2025-10-31 Jichen Feng , Ethan Abraham , Joseph E. Subotnik , Abraham Nitzan

Chirality causes symmetry breaks in a large variety of natural phenomena ranging from particle physics to biochemistry. We investigate one of the simplest conceivable chiral systems, a laser-excited, oriented, effective one-electron Li…

A light beam changes direction as it enters a liquid at an angle from another medium, such as air. Should the liquid contain molecules that lack mirror symmetry, then it has been predicted by Fresnel that the light beam will not only change…

Optics · Physics 2009-11-13 Ambarish Ghosh , Peer Fischer

Coupling between light and material excitations underlies a wide range of optical phenomena. Polaritons are eigenstates of a coupled system with hybridized wave function. Owing to their hybrid composition, polaritons exhibit at the same…

Optics · Physics 2022-12-27 Denis G. Baranov , Christian Schäfer , Maxim V. Gorkunov

Light is one of the most powerful and precise tools allowing us to control, shape and create new phases of matter. In this task, the magnetic component of a light wave has so far played a unique role in defining the wave's helicity, but its…

Chirality, or the breaking of mirror symmetry, appears across all scales in nature, from molecular conformations to the dynamics of bacterial collectives. Environments composed of such symmetry-breaking constituents can give rise to…

Chirality describes the asymmetry between an object and its mirror image and manifests itself in diverse functionalities across all scales of matter - from molecules and aggregates to thin films and bulk chiral materials. A particularly…

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