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Fluctuation theorems, such as the Jarzynski equality and the Crooks relation, are effective tools connecting non-equilibrium work statistics and equilibrium free energy differences. However, detailed hands-on, reproducible protocols for…

We study Derrida's generalized random energy model in the presence of uniform external field. We compute the fluctuations of the ground state and of the partition function in the thermodynamic limit for all admissible values of parameters.…

Probability · Mathematics 2014-02-11 Anton Bovier , Anton Klimovsky

There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

Statistical Mechanics · Physics 2009-09-25 Gavin E. Crooks

Estimating free-energy differences using nonequilibrium work relations, such as the Jarzynski equality, is hindered by poor convergence when work fluctuations are large. For systems governed by overdamped Langevin dynamics, we propose the…

Statistical Mechanics · Physics 2025-08-14 Stephen Whitelam

We describe the relation between the isothermal atomic compressibility and density fluctuations in mixtures of two-component fermions with population or mass imbalance. We derive a generalized version of the fluctuation-dissipation theorem…

Quantum Gases · Physics 2011-10-19 Kangjun Seo , C. A. R. Sá de Melo

Understanding how systems respond to external perturbations is a fundamental challenge in physics, particularly for non-equilibrium and non-stationary processes. The fluctuation-dissipation theorem provides a complete framework for…

Statistical Mechanics · Physics 2026-05-06 Jiming Zheng , Zhiyue Lu

Diffusion maps approximate the generator of Langevin dynamics from simulation data. They afford a means of identifying the slowly-evolving principal modes of high-dimensional molecular systems. When combined with a biasing mechanism,…

Data Analysis, Statistics and Probability · Physics 2020-07-01 Zofia Trstanova , Ben Leimkuhler , Tony Lelièvre

The dissipation function for a system is defined as the natural logarithm of the ratio between probabilities of a trajectory and its time-reversed trajectory, and its probability distribution follows a well-known relation called the…

Statistical Mechanics · Physics 2023-01-16 Harsh Soni

The Helmholtz free energy density is parametrized as a function of temperature and baryon density near the chiral critical point of QCD. The parametrization incorporates the expected critical exponents and amplitudes. An expansion away from…

Nuclear Theory · Physics 2014-11-21 Joseph Kapusta

The asymptotic behaviour of the work probability distribution in driven non-equilibrium systems is determined using the method of optimal fluctuations. For systems described by Langevin dynamics the corresponding Euler-Lagrange equation…

Statistical Mechanics · Physics 2013-05-29 A. Engel

Using the Feynman-Kac formula, a work fluctuation theorem for a Brownian particle in a nonconfining potential, e.g., a potential well with finite depth, is derived. The theorem yields aninequality that puts a lower bound on the average work…

Statistical Mechanics · Physics 2021-02-12 Christoph Streißnig , Holger Kantz

We slightly extend the fluctuation theorem obtained in \cite{LS} for sums of generators, considering continuous-time Markov chains on a finite state space whose underlying graph has multiple edges and no loop. This extended frame is suited…

Mathematical Physics · Physics 2015-05-20 A. Faggionato , D. Di Pietro

We study work extraction processes mediated by finite-time interactions with an ambient bath -- \emph{partial thermalizations} -- as continuous time Markov processes for two-level systems. Such a stochastic process results in fluctuations…

Statistical Mechanics · Physics 2021-05-05 Maria Quadeer , Kamil Korzekwa , Marco Tomamichel

This article reports on an experimental study of the fluctuations of energy flux between a granular gas and a small driven harmonic oscillator. The DC-motor driving this system is used simultaneously as actuator and probe. The statistics of…

Statistical Mechanics · Physics 2011-12-12 Antoine Naert

We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs, we derive a hybrid result, similar in form to both…

Statistical Mechanics · Physics 2007-05-23 C. Jarzynski

We derive the bias function that minimizes the statistical error of free energy differences calculated in work-biased fast-switching simulations. The optimum bias function is compared to other bias functions using a particle pulled through…

Statistical Mechanics · Physics 2009-11-13 Harald Oberhofer , Christoph Dellago

We introduce a class of stochastic weakly coupled map lattices, as models for studying heat conduction in solids. Each particle on the lattice evolves according to an internal dynamics that depends on its energy, and exchanges energy with…

Statistical Mechanics · Physics 2013-02-18 François Huveneers

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

We compare the fluctuation relations for work and entropy in underdamped and overdamped systems, when the friction coefficient of the medium is space-dependent. We find that these relations remain unaffected in both cases. However, for the…

Statistical Mechanics · Physics 2015-06-15 Sourabh Lahiri , Shubhashis Rana , A. M. Jayannavar

Based on the observation that the thermodynamic equilibrium free energy of an open quantum system in contact with a thermal environment can be understood as the difference between the free energy of the total system and that of the bare…

Statistical Mechanics · Physics 2009-06-01 Michele Campisi , Peter Talkner , Peter Hänggi