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12\% (wt.) silver containing catalysts were prepared by aqueous ion-exchange of Ag$^+$ against Na$^+$ in NaA zeolite. Hydrogen reduction leads to the formation of silver clusters. The results of X-ray absorption spectroscopy experiments at…

Materials Science · Physics 2015-04-06 Amgalanbaatar Baldansuren

Gold nanoclusters have been the focus of numerous computational studies but an atomistic understanding of their structural and dynamical properties at finite temperature is far from satisfactory. To address this deficiency, we investigate…

Mesoscale and Nanoscale Physics · Physics 2018-11-13 Diego Guedes-Sobrinho , Weiqi Wang , Ian Hamilton , Juarez L. F. Da Silva , Luca M. Ghiringhelli

A unique property of metal nanoclusters is the "superatom" shell structure of their delocalized electrons. The electronic shell levels are highly degenerate and therefore represent sharp peaks in the density of states. This can enable…

Superconductivity · Physics 2015-12-17 Avik Halder , Vitaly V. Kresin

We demonstrate that it is possible to distinguish two conductance switching mechanisms in silver sulfide devices at room temperature. Experiments were performed using a Ag$_2$S thin film deposited on a wide Ag bottom electrode, which was…

Mesoscale and Nanoscale Physics · Physics 2017-12-11 J. J. T. Wagenaar , M. Morales-Masis , J. M. van Ruitenbeek

The structural evolution of suspensions upon freezing is studied with optical microscopy in a suspended droplet configuration. Droplets have millimeter size and consist in an aqueous mixture of silica particles while the surroundings phase…

Soft Condensed Matter · Physics 2018-05-10 Mathieu Nespoulous , Renaud Denoyel , Mickaël Antoni

Manipulation of metal nanoparticles using atomic force microscope is a promising new technique for probing tribological properties at the nanoscale. In spite of some advancements in experimental investigations, there is no unambiguous…

Mesoscale and Nanoscale Physics · Physics 2010-11-25 Alexei V. Khomenko , Nikolay V. Prodanov

Combined gold and silicon nano-system has spurred tremendous interest in the scientific community due to its application in different metal-semiconductor electronic devices and solar driven water splitting cells. Silicon, fabricated on gold…

Materials Science · Physics 2024-06-19 Shahriar Nahian , Shahriar Muhammad Nahid , Mohammad Motalab , Pritom Bose

Transmission electron microscopy (TEM) study on morphological changes in gold nanostructures deposited on Si (100) upon annealing under different vacuum conditions has been reported. Au thin films of thickness ~2.0 nm were deposited under…

Mesoscale and Nanoscale Physics · Physics 2017-12-06 Ashutosh Rath , R. R. Juluri , P. V. Satyam

Density functional methods have been used to calculate the electronic properties of aligned smalldiameter single-walled carbon nanotubes under hydrostatic pressures. Abrupt pressure induced semiconductor-metal and metal-semiconductor…

Materials Science · Physics 2008-08-27 Sumit Saxena , Trevor A. Tyson

Atomic models of zigzag (n, 0)- and armchair (n,n)-like NiCl2 nanotubes (n = 4 - 29) formed by rolling (100) single layers of the bulk NiCl2 which crystallizes in the CdCl2-type structure, are constructed and their electronic properties and…

Materials Science · Physics 2007-05-23 V. V. Ivanovskaya , A. N. Enyashin , N. I. Medvedeva , A. L. Ivanovskii

Solid-state dewetting phenomenon in silver thin films offers a straightforward method to obtain structures having controlled shape or size -this latter in principle spanning several orders of magnitudes -- with potentially strong interest…

Materials Science · Physics 2020-07-10 M. Berni , I. Carrano , A. Kovtun , A. Russo , A. Visani , C. Dionigi , A. Liscio , F. Valle , A. Gambardella

The NaNO$_{2}$ nanocomposite ferroelectric material in porous glass was studied by neutron diffraction. For the first time the details of the crystal structure including positions and anisotropic thermal parameters were determined for the…

Electronic and optical properties of silver clusters were calculated using two different \textit{ab initio} approaches: 1) based on all-electron full-potential linearized-augmented plane-wave method and 2) local basis function…

Mesoscale and Nanoscale Physics · Physics 2016-11-28 John T. Titantah , Mikko Karttunen

Structural, magnetic and electronic structural properties of Ni0.2Cd0.3Fe2.5-xAlxO4 ferrites nanoparticles have been studied x-ray diffraction (XRD), transmission electron microscopy (TEM), dc magnetization, and near edge x-ray absorption…

Materials Science · Physics 2011-01-31 Shalendra Kumar , Khalid Mujasam Batoo , S. Gautam , B. H. Koo , Alimuddin , K. H. Chae , Chan Gyu Lee

Sn-Ag-Cu (SAC) alloys are commonly recognized as lead-free solders employed in the electronics industry. However, some disadvantages in mechanical properties and their higher melting temperatures compared to Pb-Sn solders prompt new…

Applied Physics · Physics 2018-06-20 Andriy Yakymovych , Stepan Mudry , Ihor Shtablavyi , Herbert Ipser

The "metallic" temperature variation of the electrical resistivity of chemical nano gold-silver coatings with a silver content of 6.6 % at. up to 13.1 % at. determined in the temperature range 4.2-300 K. Features of low-temperature…

High resolution photoelectron spectra of cold mass selected Cu_n-, Ag_n- and Au_n- with n =53-58 have been measured at a photon energy of 6.42 eV. The observed electron density of states is not the expected simple electron shell structure,…

Other Condensed Matter · Physics 2015-06-24 H. Hakkinen , M. Moseler , O. Kostko , N. Morgner , M. Astruc Hoffmann , B. v. Issendorff

Nanoparticles have become increasingly interesting for a wide range of applications, because in principle it is possible to tailor their properties by controlling size, shape and composition. One of these applications is heterogeneous…

Materials Science · Physics 2021-06-22 Jan Weinreich , Martín Leandro Paleico , Jörg Behler

The noble elements constitute the simplest group of atoms. At low temperatures or high pressures they freeze into the face-centered cubic (fcc) crystal structure (except helium). We perform molecular dynamics using the recently proposed…

Materials Science · Physics 2024-01-05 Aditya N. Singh , Jeppe C. Dyre , Ulf R. Pedersen

Individual highly pure single crystalline silver nanowires (Ag NWs) were investigated with regard to the electrical conductivity $\sigma$, the thermal conductivity $\lambda$ and the Seebeck coefficient $S$ as function of the temperature $T$…