Related papers: Equation of state for hard sphere fluids with and …
Using the first seven known virial coefficients and forcing it to possess two branch-point singularities, a new equation of state for the hard-sphere fluid is proposed. This equation of state predicts accurate values of the higher virial…
New proposals for the equation of state of four- and five-dimensional hard-hypersphere mixtures in terms of the equation of state of the corresponding monocomponent hard-hypersphere fluid are introduced. Such proposals (which are…
An equation of state for a multicomponent mixture of non-additive hard spheres in $d$ dimensions is proposed. It yields a rather simple density dependence and constitutes a natural extension of the equation of state for additive hard…
It is shown that almost all known solutions of the kind mentioned in the title are easily derived in a unified manner when a simple ansatz is imposed on the metric. The Whittaker solution is an exception, replaced by a new solution with the…
A new closed virial equation of state of hard-sphere fluids is proposed which reproduces the calculated or estimated values of the first sixteen virial coefficients at the same time as giving very good accuracy when compared with computer…
A simple equation of state for a lattice gas of hard squares of side length $\lambda$ is presented. Comparing to the Monte Carlo simulations, the new equation of state is found to be quite accurate for the disordered fluid phase.
The asymptotic expansion method is extended by using currently available accurate values for the first ten virial coefficients for hard sphere fluids. It is then used to yield an equation of state for hard sphere fluids, which accurately…
The energy route to the equation of state of hard-sphere fluids is ill-defined since the internal energy is just that of an ideal gas and thus it is independent of density. It is shown that this ambiguity can be avoided by considering a…
Based on the survey of the literatures on the new improvements on the equation of state (EOS) for the hard sphere fluids, we here compare lots of different EOSs and present a very accurate equation of state for this kind of fluids. The new…
The composition-independent virial coefficients of a $d$-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture [Santos, A., Yuste, S. B., and L\'opez de Haro,…
The Van der Waal's equation of state for a (slightly) non-ideal classical gas is usually derived in the context of classical statistical mechanics by using the canonical ensemble. We use the hard sphere potential with no short range…
An equation of state of the hard sphere fluid which is not analytical at the freezing density is proposed and tested. The nonanalytical term is based on the the classical nucleation theory and is able to capture the observed ``anomalous…
A new analytical approach to derive an approximate equation of state and the virial coefficients for simple fluids is presented. Starting from the usual expression of the partition function, we first perform a Fourier transformation, and…
A simple recipe to derive the compressibility factor of a multicomponent mixture of d-dimensional additive hard spheres in terms of that of the one-component system is proposed. The recipe is based (i) on an exact condition that has to be…
The equation of state for a two-dimensional hard-sphere gas is difficult to calculate by usual methods. In this paper we develop an approach for calculating the equation of state of hard-sphere gases, both for two- and three-dimensional…
We propose a new semi empirical expression of the virial coefficients for a hard sphere fluid which is valid in the disordered phase over the whole density range. The results are in good agreement with the numerical data and better than…
Virial coefficients for the two-dimensional hard-disk fluid, when expressed in powers of density relative to maximum close packing, lead to an accurate closed equation-of-state for the equilibrium fluid, analogous to that recently found for…
The equation of state for five-dimensional hard hyperspheres arising as a weighted average of the Percus-Yevick compressibility (3/5) and virial (2/5) equations of state is considered. This Carnahan-Starling-like equation turns out to be…
Following the work of Leutheusser [Physica A 127, 667 (1984)], the solution to the Percus-Yevick equation for a seven-dimensional hard-sphere fluid is explicitly found. This allows the derivation of the equation of state for the fluid…
A general equation of state for the hard-body reference system of real fluid has been developed from first principles, statistical mechanical arguments using metric differential geometry to describe the "available volume," V0, and its…