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In the pursuit of numerically identifying the ground state of quantum many-body systems, approximate quantum wavefunction ansatzes are commonly employed. This study focuses on the spectral decomposition of these approximate quantum…

Quantum Physics · Physics 2025-08-29 Yu-Qin Chen , Shi-Xin Zhang

Kohn-Sham inversion, that is, the finding of the exact Kohn-Sham potential for a given density, is difficult in localized basis sets. We study the precision and reliability of several inversion schemes, finding estimates of density-driven…

Chemical Physics · Physics 2020-04-27 Seungsoo Nam , Suhwan Song , Eunji Sim , Kieron Burke

The most challenging scenario for Kohn-Sham density functional theory, that is when the electrons move relatively slowly trying to avoid each other as much as possible because of their repulsion (strong-interaction limit), is reformulated…

Strongly Correlated Electrons · Physics 2015-06-05 Giuseppe Buttazzo , Luigi De Pascale , Paola Gori-Giorgi

A single-term density functional model for nondynamic and strong correlation is presented, based on single-determinant Kohn-Sham density functional theory. It is derived from modeling the adiabatic connection and contains only two nonlinear…

Chemical Physics · Physics 2015-12-21 Jing Kong , Emil Proynov

How does charge density constrain many-body wavefunctions in nature? The Hohenberg-Kohn theorem for non-relativistic, interacting many-body Schr\"odinger systems is well-known and was proved using \emph{reductio-ad-absurdum}; however, the…

Computational Physics · Physics 2022-04-28 Purnima Ghale

The advent of the Hohenberg-Kohn theorem in 1964, its extension to finite-T, Kohn-Sham theory, and relativistic extensions provide the well-established formalism of density-functional theory (DFT). This theory enables the calculation of all…

Quantum Physics · Physics 2013-07-18 M. W. C. Dharma-wardana

We are concerned with few-particle correlations in a fermionic system at finite temperature and density. Within the many-body Green functions formalism the description of correlations is provided by the Dyson equation approach that leads to…

Nuclear Theory · Physics 2007-05-23 S. A. Sofianos , M. Beyer

The Hohenberg-Kohn (HK) theorem is one of the most fundamental theorems of quantum mechanics, and constitutes the basis for the very successful density-functional approach to inhomogeneous interacting many-particle systems. Here we show…

Materials Science · Physics 2009-11-11 K. Capelle , C. A. Ullrich , G. Vignale

We demonstrate the existence of different density-density functionals designed to retain selected properties of the many-body ground state in a non-interacting solution starting from the standard density functional theory ground state. We…

Other Condensed Matter · Physics 2009-11-13 F. A. Reboredo , P. R. C. Kent

Nonlocal effective interactions are inherent to non-relativistic quantum many-body systems, but their systematic resummation poses a significant challenge known as the ``vertex problem" in many-body perturbation theory. We introduce a…

Strongly Correlated Electrons · Physics 2024-07-23 Kun Chen

We propose a framework to construct the ground-state energy and density matrix of an N-electron system by solving selfconsistently a set of single-particle equations. The method can be viewed as a non-trivial extension of the Kohn-Sham…

Chemical Physics · Physics 2009-11-13 D. Van Neck , S. Verdonck , G. Bonny , P. W. Ayers , M. Waroquier

The theory of real-time quantum many-body dynamics as put forward in Ref. [arXiv:0710.4627] is evaluated in detail. The formulation is based on a generating functional of correlation functions where the Keldysh contour is closed at a given…

Quantum Gases · Physics 2011-02-09 Thomas Gasenzer , Stefan Kessler , Jan M. Pawlowski

The exact interaction energy of a many-electron system is determined by the electron pair density, which is not well-approximated in standard Kohn-Sham density functional models. Here we study the (complicated but well-defined) exact…

Chemical Physics · Physics 2015-08-07 Huajie Chen , Gero Friesecke

Density functional theory is currently the most widely applied method in electronic structure theory. The Kohn-Sham method, based on a fictitious system of non-interacting particles, is the work horse of the theory. The particular form of…

Chemical Physics · Physics 2016-06-01 Hubertus J J van Dam

Many-body quantum systems present a rich phenomenology which can be significantly altered when they are in contact with an environment. In order to study such setups, a number of approximations are usually performed, either concerning the…

Quantum Gases · Physics 2019-01-10 Xiansong Xu , Juzar Thingna , Chu Guo , Dario Poletti

The rapid development of quantum computers has enabled demonstrations of quantum advantages on various tasks. However, real quantum systems are always dissipative due to their inevitable interaction with the environment, and the resulting…

High throughput screening of materials for technologically relevant areas, like identification of better catalysts, electronic materials, ceramics for high temperature applications and drug discovery, is an emerging topic of research. To…

Chemical Physics · Physics 2020-05-04 Edgar Josué Landinez Borda , Amit Samanta

Recent breakthroughs in the creation of ultra-cold atomic gases in the laboratory have ushered in major changes in physical science. Many novel experiments are now possible, with an unprecedented control of interaction, geometry and purity.…

Quantum Gases · Physics 2014-11-13 Hui Hu

Restricted Boltzmann Machines (RBM) are simple statistical models defined on a bipartite graph which have been successfully used in studying more complicated many-body systems, both classical and quantum. In this work, we exploit the…

Nuclear Theory · Physics 2021-01-13 Ermal Rrapaj , Alessandro Roggero

Informed by an abstraction of Kohn-Sham computation called a KS machine, a functional analytic perspective is developed on mathematical aspects of density functional theory. A natural semantics for the machine is bivariate, consisting of a…

Other Condensed Matter · Physics 2023-09-25 Paul E. Lammert