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Density functional theory together with the Kohn-Sham scheme represent an efficient framework to recover the ground state density and energy of a many-body quantum system from an auxiliary ``non-interacting'' system (one-body with a local…

Quantum Physics · Physics 2021-05-18 Jérémie Messud

In this work we give a comprehensive derivation of an exact and numerically feasible method to perform ab-initio calculations of quantum particles interacting with a quantized electromagnetic field. We present a hierachy of…

The density functional theory is extended to account for self-bound systems. To this end the Hohenberg-Kohn theorem is formulated for the intrinsic density and a Kohn-Sham like procedure for an $N$--body system is derived using the…

Nuclear Theory · Physics 2008-11-26 Nir Barnea

Many-body perturbation theory is often formulated in terms of an expansion in the dressed instead of the bare Green's function, and in the screened instead of the bare Coulomb interaction. However, screening can be calculated on different…

Strongly Correlated Electrons · Physics 2021-09-15 Walter Tarantino , Bernardo S. Mendoza , Pina Romaniello , J. A. Berger , Lucia Reining

In the framework of quantum thermodynamics, we propose a method to quantitatively describe thermodynamic quantities for out-of-equilibrium interacting many-body systems. The method is articulated in various approximation protocols which…

Quantum Physics · Physics 2018-02-22 Marcela Herrera , Roberto M. Serra , Irene D'Amico

For properties of interacting electron systems, Kohn-Sham (KS) theory is often favored over many-body perturbation theory (MBPT) owing to its low computational cost. However, the exact KS potential can be challenging to approximate, for…

Materials Science · Physics 2021-01-15 Jack Wetherell , Matthew Hodgson , Leopold Talirz , Rex Godby

The exact reduced density-matrix functional is derived from the Luttinger-Ward functional of the single-particle Green's function. Thereby, a formal link is provided between diagrammatic many-body approaches using Green's functions on the…

Strongly Correlated Electrons · Physics 2013-12-11 Peter E. Blöchl , Thomas Pruschke , Michael Potthoff

The multi-component density functional theory is faced with the challenge of capturing various types of inter- and intra-particle exchange-correlation effects beyond those introduced by the conventional electronic exchange-correlation…

Atomic and Molecular Clusters · Physics 2023-12-27 Nahid Sadat Riyahi , Mohammad Goli , Shant Shahbazian

While in principle exact, Kohn-Sham density functional theory -- the workhorse of computational chemistry -- must rely on approximations for the exchange-correlation functional. Despite staggering successes, present-day approximations still…

The Kohn-Sham scheme of density functional theory is one of the most widely used methods to solve electronic structure problems for a vast variety of atomistic systems across different scientific fields. While the method is fast relative to…

Time-dependent density functional theory (TDDFT) is rapidly emerging as a premier method for solving dynamical many-body problems in physics and chemistry. The mathematical foundations of TDDFT are established through the formal existence…

Quantum Physics · Physics 2014-08-22 J. D. Whitfield , M. -H. Yung , D. G. Tempel , S. Boixo , A. Aspuru-Guzik

We extend the concept of the functional renormalization for quantum many-body problems to non-equilibrium situations. Using a suitable generating functional based on the Keldysh approach, we derive a system of coupled differential equations…

Strongly Correlated Electrons · Physics 2013-05-29 R. Gezzi , Th. Pruschke , V. Meden

Irreversibility, despite being a necessary condition for thermalization, still lacks a sound understanding in the context of isolated quantum many-body systems. In this work we approach this question by studying the behavior of generic…

Statistical Mechanics · Physics 2018-11-14 Markus Schmitt , Stefan Kehrein

The inverse problem is studied in multi-body systems with nonlinear dynamics representing, e.g., phase-locked wave systems, standard multimode and random lasers. Using a general model for four-body interacting complex-valued variables we…

Disordered Systems and Neural Networks · Physics 2017-08-01 Alessia Marruzzo , Payal Tyagi , Fabrizio Antenucci , Andrea Pagnani , Luca Leuzzi

In this paper, we investigate the energy minimization model of the ensemble Kohn-Sham density functional theory for metallic systems, in which a pseudo-eigenvalue matrix and a general smearing approach are involved. We study the invariance…

Numerical Analysis · Mathematics 2022-01-19 Xiaoying Dai , Stefano de Gironcoli , Bin Yang , Aihui Zhou

Recent developments of experimental techniques in the field of ultra-cold gases open a path to study the crossover from 'few' to 'many' on the quantum level. In this case, accurate description of inter-particle correlations is very…

Quantum Gases · Physics 2018-03-23 Marcin Płodzień , Dariusz Wiater , Andrzej Chrostowski , Tomasz Sowiński

Many-body theory is largely based on self-consistent equations that are constructed in terms of the physical quantity of interest itself, for example the density. Therefore, the calculation of important properties such as total energies or…

Materials Science · Physics 2015-10-28 Adrian Stan , Pina Romaniello , Santiago Rigamonti , Lucia Reining , J. A. Berger

Quantum simulation provides a powerful route for exploring many-body phenomena beyond the capabilities of classical computation. Existing approaches typically proceed in the forward direction: a model Hamiltonian is specified, implemented…

Time reversal in a macroscopic system is contradicting daily experience. It is practically impossible to restore a shattered cup to its original state by just time reversing the microscopic dynamics that led to its breakage. Yet, with the…

A Kohn-Sham (KS) inversion determines a KS potential and orbitals corresponding to a given electron density, a procedure that has applications in developing and evaluating functionals used in density functional theory. Despite the utility…

Computational Physics · Physics 2021-04-07 Seungsoo Nam , Ryan J. McCarty , Hansol Park , Eunji Sim