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The aromatic molecule benzene is considered the essential building block for larger polycyclic aromatic hydrocarbons (PAHs) in space. Despite benzene's importance in the formation of PAHs, the formation mechanisms of interstellar benzene…

Astrophysics of Galaxies · Physics 2025-02-26 G. S. Kocheril , C. Zagorec-Marks , H. J. Lewandowski

We present a new method to decompose the emission features of polycyclic aromatic hydrocarbons (PAHs) from mid-infrared spectra using theoretical PAH templates in conjunction with modified blackbody components for the dust continuum and an…

Astrophysics of Galaxies · Physics 2018-06-26 Yanxia Xie , Luis C. Ho , Aigen Li , Jinyi Shangguan

Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by modeling the physical conditions…

Astrophysics of Galaxies · Physics 2025-12-10 Guillermo M. Muñoz Caro , Héctor Carrascosa de Lucas , Rafael Martín-Doménech

We present a new model of interstellar dust in which large grains are a single composite material, ``astrodust,'' and nanoparticle-sized grains come in distinct varieties including polycyclic aromatic hydrocarbons (PAHs). We argue that a…

Astrophysics of Galaxies · Physics 2023-06-07 Brandon S. Hensley , B. T. Draine

This study theoretically predicts the specific Polycyclic Aromatic Hydrocarbon (PAH) molecules to reproduce both astronomically observed Infrared Bands (IR) and Diffuse Interstellar Bands (DIB). In our recent paper, we could reproduce IR by…

Astrophysics of Galaxies · Physics 2023-11-23 Norio Ota

Polycyclic Aromatic Hydrocarbon (PAH) emission features dominate the mid-infrared spectra of star-forming galaxies and can be useful to calibrate star formation rates and diagnose ionized states of grains. However, the PAH 3.3 micron…

A novel theoretical method is developed to study the polycyclic aromatic hydrocarbon - diffuse interstellar band (PAH-DIB) hypothesis. In this method, a computer program is used to enumerate all PAH molecules with up to a specific number of…

Astrophysics · Physics 2007-05-23 Xiaofeng Tan

Based on theoretical spectra computed using Density Functional Theory we study the properties of Polycyclic Aromatic Hydrocarbons (PAH). In particular using bin-average spectra of PAH molecules with varying number of carbons we investigate…

Deuterium (D) is one of the light elements created in the big bang. As the Galaxy evolves, the D/H abundance in the interstellar medium (ISM) decreases from its primordial value due to "astration". However, the observed gas-phase D/H…

Astrophysics of Galaxies · Physics 2020-11-18 X. J. Yang , Aigen Li , R. Glaser

Superhydrogenated polycyclic aromatic hydrocarbons (PAHs) may be present in H-rich and ultraviolet-poor benign regions. The addition of excess H atoms to PAHs converts the aromatic bonds into aliphatic bonds, the strongest of which falls…

Astrophysics of Galaxies · Physics 2020-03-04 X. J. Yang , Aigen Li , R. Glaser

We study the polarized infrared emission by Polycyclic Aromatic Hydrocarbons (PAHs), when anisotropically illuminated by UV photons. PAH molecules are modeled as planar disks with in-plane and out-of-plane vibrational dipoles. As first…

Astrophysics of Galaxies · Physics 2011-02-11 Lorenzo Sironi , Bruce T. Draine

Observationally, the interstellar gas-phase abundance of deuterium (D) is considerably depleted and the missing D atoms are often postulated to have been locked up into carbonaceous solids and polycyclic aromatic hydrocarbon (PAH)…

Astrophysics of Galaxies · Physics 2021-08-04 X. J. Yang , Aigen Li , C. Y. He , R. Glaser

Infrared (IR) emission spectra are calculated for dust composed of mixtures of amorphous silicate and graphitic grains, including varying amounts of polycyclic aromatic hydrocarbon (PAH) particles. The models are constrained to reproduce…

Astrophysics · Physics 2008-11-26 B. T. Draine , Aigen Li

Contrary to popular belief, the interstellar medium (ISM) is not empty; it is filled with atoms, dust particles, and molecules. Some of these molecules may have been the very building blocks of life that, delivered to Earth via comets and…

Using a large collection of near-infrared spectra (2.5-5.4 um) of Galactic HII regions and HII region-like objects, we perform a systematic investigation of the astronomical polycyclic aromatic hydrocarbon (PAH) features. 36 objects were…

Astrophysics of Galaxies · Physics 2015-06-18 Tamami I. Mori , Takashi Onaka , Itsuki Sakon , Daisuke Ishihara , Takashi Shimonishi , Ryou Ohsawa , Aaron C. Bell

We present the spatial distributions of dust and polycyclic aromatic hydrocarbons (PAHs) in the elliptical galaxy NGC4125, revealed by AKARI and Spitzer. NGC4125 is relatively bright in the dust and the PAH emision for elliptical galaxies,…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-27 Hidehiro Kaneda , Daisuke Ishihara , Takashi Onaka , Toyoaki Suzuki , Tatsuya Mori , Shinki Oyabu , Mitsuyoshi Yamagishi

Polycyclic aromatic hydrocarbon (PAH) ions are crucial intermediates in interstellar chemistry and may play a key role in the infrared emission features observed in space. Here, we investigate the infrared spectra of the indenyl…

Methylated polycyclic aromatic hydrocarbons (PAHs) have been hypothesised to be present in the interstellar medium (ISM) through their 3.4 and 6.9 $\mu$m absorption bands. To investigate the hydrogenation of these methylated PAHs, the…

Astrophysics of Galaxies · Physics 2026-02-11 A. T. Hopkinson , F. G. Doktor , J. Pitfield , M. Moll , J. D. Thrower , L. Hornekær