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A quantum-mechanical (QM) method rooted on density functional theory (DFT) has been employed to determine conformations of the methane-thiosulfonate spin label (MTSL) attached to a fragment extracted from the activation loop of Aurora-A…

Chemical Physics · Physics 2016-03-25 Maria Grazia Concilio , Alistair J. Fielding , Richard Bayliss , Selena G. Burgess

The combination of isochoric heating of solids by free electron lasers (FEL) and in situ diagnostics by X-ray Thomson scattering (XRTS) allows for measurements of material properties at warm dense matter (WDM) conditions relevant for…

Slow dynamics of difluorotetrachloroethane in both supercooled plastic crystal and supercooled liquid states have been investigated from Molecular Dynamics simulations. The temperature and wave-vector dependence of collective dynamics in…

Soft Condensed Matter · Physics 2009-11-11 F. Affouard , M. Descamps

The article presents results of discrete thermodynamics (DTD) basic application to electrochemical systems. Consistent treatment of the electrochemical system as comprising two interacting subsystems - the chemical and the electrical…

Chemical Physics · Physics 2009-07-28 B. Zilbergleyt

In recent years, a method for computing spin dynamics at infinite temperature (spinDMFT) was developed. It utilizes the ideas of dynamical mean-field theory for fermions: single-site approximation and a self-consistency condition to…

Strongly Correlated Electrons · Physics 2026-04-24 Przemysław Bieniek , Timo Gräßer , Götz S. Uhrig

We present the theoretical analysis of the steady state currents and density distributions of particles moving with Langevin dynamics, under the effects of an external potential displaced at constant rate. The Dynamic Density Functional…

Soft Condensed Matter · Physics 2009-11-10 F. Penna , P. Tarazona

Static electric response properties of atoms and molecules are reported within the real-space Cartesian grid implementation of pseudopotential Kohn-Sham (KS) density functional theory (DFT). A detailed systematic investigation is made for a…

Chemical Physics · Physics 2019-04-26 Tanmay Mandal , Abhisek Ghosal , Amlan K. Roy

We have performed first-principles molecular-dynamics simulations based on density-functional theory to study the thermophysical properties of ethane under extreme conditions. We present new results for the equation of state of fluid ethane…

Materials Science · Physics 2012-12-12 Yujuan Zhang , Cong Wang , Fawei Zheng , Ping Zhang

Orbital-free density functional theory promises to deliver linear-scaling electronic structure calculations. This requires the knowledge of the non-interacting kinetic-energy density functional (KEDF), which should be accurate and must…

Materials Science · Physics 2024-12-12 Michael A. J. Mitchell , Teresa Del Aguila Ferrandis , Stefano Sanvito

We present a construction of a mean-field theory for thermodynamic and spectral properties of correlated electrons reliable in the strong-coupling limit. We introduce an effective interaction determined self-consistently from the reduced…

Strongly Correlated Electrons · Physics 2017-04-19 Václav Janiš , Vladislav Pokorný , Anna Kauch

Time-dependent density-functional theory (TDDFT) is a powerful tool to study the non-equilibrium dynamics of inhomogeneous interacting many-body systems. Here we show that the simple adiabatic local-spin-density approximation for the…

Strongly Correlated Electrons · Physics 2008-11-11 Wei Li , Gao Xianlong , Corinna Kollath , Marco Polini

Perdew et al. [Phys. Rev. Lett 49, 1691 (1982)] discovered and proved two different properties of exact Kohn-Sham density functional theory (DFT): (i) The exact total energy versus particle number is a series of linear segments between…

Other Condensed Matter · Physics 2015-03-13 Tamar Stein , Jochen Autschbach , Niranjan Govind , Leeor Kronik , Roi Baer

This thesis is devoted to ab initio calculations of ground and excited state properties of different systems within density functional theory and time dependent density functional theory. From the numerical point of view we implemented an…

Materials Science · Physics 2012-11-28 Lucia Caramella

The development of analytic-gradient methodology for excited states within conventional time-dependent density-functional theory (TDDFT) would seem to offer a relatively inexpensive alternative to better established quantum-chemical…

Other Condensed Matter · Physics 2010-08-11 Felipe Cordova , L. Joubert Doriol , Andrei Ipatov , Mark E. Casida , Claudia Filippi , Alberto Vela

We study the dynamical response of the half-filled one-dimensional(1d) Hubbard model for a range of interaction strengths $U$ and temperatures $T$ by a combination of numerical and analytical techniques. Using time-dependent density matrix…

Strongly Correlated Electrons · Physics 2018-02-07 Alberto Nocera , Fabian H. L. Essler , Adrian E. Feiguin

Thermodynamic properties of the electron-positron plasma (or gas) at high and very high temperatures are investigated. To achieve this goal we have derived a number of analytical formulas for the Fermi-Dirac distribution functions (or…

Plasma Physics · Physics 2023-01-16 Alexei M. Frolov

In one-dimensional (1D) non-perturbative many-electron problems such as the 1D Hubbard model the electronic charge and spin degrees of freedom separate into exotic quantum objects. However, there are two different representations for such…

Strongly Correlated Electrons · Physics 2007-05-23 J. M. P. Carmelo , K. E. Hibberd , N. Andrei

Theoretical studies of photochemical processes require a description of the energy surfaces of excited electronic states, especially near degeneracies, where transitions between states are most likely. Systems relevant to photochemical…

The time-dependent density functional theory (TDDFT) is the leading computationally feasible theory to treat excitations by strong electromagnetic fields. Here the theory is applied to coherent optical phonon generation produced by intense…

Materials Science · Physics 2015-06-05 Y. Shinohara , S. A. Sato , K. Yabana , J. -I. Iwata , T. Otobe , G. F. Bertsch

We have calculated high temperature expansions for the momentum distribution function $n_{\scriptscriptstyle\bf k}$ and the equal time spin and density correlation functions $S({\bf q})$ and $N({\bf q})$ of the two-dimensional $t$-$J$…

Condensed Matter · Physics 2009-10-22 W. O. Putikka , R. L. Glenister , R. R. P. Singh , H. Tsunetsugu